WO2017119728A1 - Cosmetic composition having shape memory ability - Google Patents

Abstract

The present invention relates to a cosmetic composition having shape memory ability. More specifically, the present invention relates to a cosmetic composition provided with shape memory ability by containing siloxane and silicone quaternium in a water-in-oil type and to a cosmetic composition provided with natural association force and pickup force while maintaining shape memory ability by containing an amine-based or sulfone acid-based compound in a shape memory polymer that is conventionally used. A water-in-oil type cosmetic composition in the cosmetic composition of the present invention is a water-in-oil type formulation containing siloxane and silicone quaternium, and can be provided with an immediate skin wrinkle-improving effect or an immediate skin elasticity-improving effect through shape memory ability and can be provided with a skin gloss-improving effect or a skin moisturizing ability-enhancing effect. In addition, an oil-in-water type cosmetic composition in the composition of the present invention is an oil-in-water type formulation containing a shape memory polymer and an amine-based compound or a sulfone-based compound, and can provide effects of excellent pickup force and natural association force while having excellent shape memory ability.

Description

Cosmetic composition having shape memory ability

The present invention relates to a cosmetic composition having a shape memory capability. More specifically, in the water-in-oil type, by containing siloxane and silicon quaternium, the cosmetic composition given the shape memory capability and the conventional shape memory polymer include the amine or sulfonic acid compound in the shape memory polymer, thereby maintaining the natural shape memory capability. It relates to a cosmetic composition imparted with force and pickup force.

Cosmetic companies have made great efforts to prevent and improve symptoms that hinder people's pursuit of extroverted beauty, such as dryness, loss of elasticity, wrinkles, blemishes and freckles. Among the symptoms that disturb the external beauty of the people is representative of wrinkles, the causes of wrinkles are classified into three categories. The first cause is a genetic factor that is affected by genes inherited from parents. The second cause is the movement of muscles according to the expression. This occurs naturally when a person laughs or grimacs, and may cause wrinkles to be generated by applying a certain force continuously for a long time. The third cause is a decrease in collagen and elastin, which accounts for most of the dermis, and an increase in matrix metalloproteinase (MMP), which breaks it down.

UV is the main reason for the increase in the amount of MMP, which is the main cause of wrinkle formation and skin elasticity. Ironically, in the global atmosphere, consumers are always exposed to UV. Therefore, consumers' demand for functional cosmetics to prevent wrinkles and improve skin elasticity is increasing, and a large market is formed worldwide. However, in order to improve wrinkles and skin elasticity by using existing functional cosmetics, it is only visible when the product is used for at least 3 months. But consumers increasingly want products that will work in the short term. Therefore, consumers' preferences for cosmetics that show immediate skin wrinkle improvement and elasticity are increasing.

As cosmetics showing immediate wrinkle improvement and elasticity, cosmetics using shape-memory polymers have been developed into various categories of products. In general, the cosmetic composition having a shape memory capacity is given to the shape memory capacity depending on the properties of the shape memory polymer which is a water-soluble thickener in the oil-in-water type.

However, in the case of a cosmetic composition applying a polymer having a shape memory capability, there is a problem with low moisturizing power because it can be applied only to the oil-in-water type, and the water-in-oil type cosmetic composition has not yet given shape memory capability. . In addition, the formulation using the shape memory polymer has a disadvantage in that it is not easy to pick up and use a tool, and there is a limitation of the formulation in that the cracking and tearing occur in the process of association, which impairs aesthetics for the consumer.

Therefore, there has been a need for a cosmetic composition which has a shape memory ability in the water-in-oil type and a cosmetic composition that has excellent pick-up power and aesthetics through natural associative force to consumers while having immediate elasticity which is an advantage of the shape memory polymer.

Therefore, the present inventors confirmed that the present invention can prepare a cosmetic composition having a shape memory ability by simultaneously including siloxane and silicon quaternium as a water-in-oil type formulation, and use an amine or sulfonic acid compound as an oil-in-water type formulation containing a shape memory polymer. At the same time, the present invention was completed by confirming that the resilience of the shape was similar to that of the general shape restoration formulation, but a cosmetic composition having natural associative force and excellent pickup force could be prepared.

Therefore, the problem to be solved by the present invention is to provide a cosmetic composition having a shape memory capability.

 In addition, the present invention is to provide an immediate skin wrinkle improvement method, the instant skin elasticity improvement method comprising the step of applying the cosmetic composition to the skin.

To solve the above problems, the problem to be solved by the present invention provides a cosmetic composition having a shape memory capability.

As used herein, the term "shape memory capacity" is generally fixed in a temporary or idle shape under a specific temperature and external physical force (stress), and then the original stress is removed by thermal, electrical or environmental changes. Refers to the ability to relax to a state. Specifically, the shape memory capability of the present invention refers to the ability to restore to its original state after time elapses after its shape is changed by an external stimulus as shown in FIG. When a compound having a "shaping memory" is applied to the skin, skin pulling occurs as it is restored to its original state before the cosmetic is applied, thereby immediately improving skin wrinkles and skin elasticity.

In addition, the present invention provides an instant skin wrinkle improvement method, an instant skin elasticity improvement method or an instant skin gloss improvement method comprising applying the cosmetic composition to the skin.

As used herein, the term "immediate skin wrinkle improvement" means that the skin wrinkle improvement effect is visible in a short time after cosmetic skin application.

As used herein, the term "immediately improve skin elasticity" means that the skin elasticity improving effect is visible in a short time after the cosmetic skin application.

Hereinafter, the present invention will be described in more detail.

The cosmetic composition includes (a) siloxane; And (b) may be a water-in-oil cosmetic composition comprising a silicon quaternium compound.

In addition, the water-in-oil cosmetic composition of the present invention may be a cosmetic composition, characterized in that it does not contain a shape memory polymer.

In addition, the present invention provides the use of the water-in-oil cosmetic composition for immediate skin wrinkle improvement, immediate skin elasticity improvement or immediate skin gloss improvement.

In addition, the present invention provides a use of the water-in-oil cosmetic composition to improve skin gloss or enhance skin moisturizing power.

In addition, the present invention provides an instant skin wrinkle improvement method, an instant skin elasticity improvement method or an instant skin gloss improvement method comprising applying the water-in-oil cosmetic composition to the skin.

In addition, the present invention provides a method for improving skin luster or enhancing skin moisturizing power, comprising applying the water-in-oil cosmetic composition to the skin.

As used herein, the term "immediately improve skin luster" means that the skin luster improvement effect is visible in a short time after cosmetic skin application.

As used herein, the term "improvement of skin radiance" refers to the improvement of the skin feel and smoothness. Gloss is also referred to as gloss. After applying cosmetics, the skin looks smooth and shiny, and can be expressed as healthy skin.

The term "enhancement of skin moisturizing power" used in the present invention is to reduce moisture discomfort such as heat, dryness, and itching by preserving moisture on the skin for a long time, and may be evaluated by measuring the amount of water loss of the skin.

In one embodiment of the present invention, the shape memory polymer is polyurethane-59 (Polyurethane-59), Fiji-150 / stearyl alcohol / SM Diacopolymer (PEG-150 / Stearyl Alcohol / SMDIcopolymer) and Fiji-240 It may be one or more selected from the group consisting of / H-diadiapolymer / bis-decyl tetradeces-20 ether (PEG-240 / HDIcopolymer / Bis-decyltetradeceth-20ether), but is not limited thereto.

In one embodiment of the present invention, the siloxane is cyclotrisiloxane (Cyclotrisiloxane), cyclotetrasiloxane (Cyclotetrasiloxane), cyclopentasiloxane (Cyclopentasiloxane), cyclohexasiloxane (Cyclohexasiloxane), cycloheptasiloxane (Cycloheptasiloxane), phenyltrimethicone (Phenyl Trimethicone), Diphenylsiloxy Phenyl Trimethicone, Cetyl PEG / Fiji-10 / 1 Dimethicone and Lauryl Fiji-9 Poly Dimethylsiloxyethyldimethicone (Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone) may be one or more selected from the group consisting of, but is not limited thereto.

In one embodiment of the present invention, the silicon quaternium is silicon quaternium-1 (Silicone Quaternium-1), silicon quaternium-3 (Silicone Quaternium-3), silicon quaternium-8 (Silicone Quaternium-8), silicon Silicon Quaternium-15, Silicon Quaternium-16. It may be at least one selected from the group consisting of silicon quaternium-18, silicon quaternium-20, silicon quaternium-22, and the like. It is not.

The silicon quaternium-22 may use silicon quaternium-22 itself, but a commercialized formulation including the same may be used. Commercialized formulations containing silicon quaternium-22 usable in the present invention include ABIL ME 45 (containing 30% silicon quaternium-22, manufactured by Evonik). It is not limited to this.

In one embodiment of the invention, the siloxane may comprise 1 to 50% by weight relative to the total composition weight. In one example, the siloxane is 2 to 50% by weight, 3 to 50% by weight relative to the total composition weight. 4 to 50 weight percent, 5 to 50 weight percent, 6 to 50 weight percent, 7 to 50 weight percent. 8 to 50 weight percent, 9 to 50 weight percent, 10 to 50 weight percent, 1 to 49 weight percent, 1 to 48 weight percent, 1 to 47 weight percent. 1 to 46 weight percent, 1 to 45 weight percent, 1 to 44 weight percent, 1 to 43 weight percent. 1 to 42 weight percent, 1 to 41 weight percent, 1 to 40 weight percent, 1 to 39 weight percent, 1 to 38 weight percent, 1 to 37 weight percent. 1 to 36 weight percent, 1 to 35 weight percent, 1 to 34 weight percent, 1 to 33 weight percent. 1 to 32 weight percent, 1 to 31 weight percent, 1 to 30 weight percent, 2 to 48 weight percent, 2 to 46 weight percent, 2 to 45 weight percent. 2 to 44 weight percent, 2 to 42 weight percent, 2 to 40 weight percent, 2 to 38 weight percent, 2 to 36 weight percent, 2 to 35 weight percent. 2 to 34 weight percent, 2 to 32 weight percent, 2 to 30 weight percent, 4 to 38 weight percent, 4 to 36 weight percent, 4 to 35 weight percent. 4 to 34%, 4 to 32%, 4 to 30%, 5 to 45%, 5 to 40%, 5 to 35%, 5 to 30%, 10 to 45%, 10 to 40 weight percent, 10 to 35 weight percent, or 10 to 30 weight percent. If the siloxane is less than 1% by weight, the shape memory capacity is not exhibited. If the siloxane is more than 50% by weight, the water-in-oil type formulation stability and the shape memory capacity are poor.

In one embodiment of the invention, the silicon quaternium may comprise 1 to 20% by weight relative to the total composition weight. For example, the silicon quaternium may be 2 to 20% by weight, 3 to 20% by weight, 4 to 20% by weight, 5 to 20% by weight, 1 to 19% by weight, 1 to 18% by weight, and 1 to 20% by weight of the total composition. 17 wt%, 1-16 wt%, 1-15 wt%, 1-14.0 wt%, 1-13 wt%, 1-12 wt%, 1-11 wt%, 1-10 wt%, 1.5-20 wt% %, 1.5 to 15%, 1.5 to 10%, 1.8 to 18%, 1.8 to 15%, 1.8 to 12%, 2 to 18%, 2 to 16%, 2 to 15%, 2 to 14%, 2 to 12%, 2 to 10%, 4 to 18%, 4 to 16%, 4 to 15%, 4 to 14%, 4 to 12% or 4 to 10 weight percent. If the silicon quaternium is less than 1% by weight, the shape memory capacity is not exhibited. If the silicon quaterium is more than 20% by weight, the water-in-oil type formulation stability and the shape memory capacity are lowered.

In one embodiment of the invention, the siloxane is from 1 to 50% by weight, the silicon quaternium is from 2 to 20% by weight or the siloxane is from 5 to 40% by weight relative to the total composition weight of the composition, the silicone Quaternium may comprise 1.8 to 15 weight percent.

In one embodiment of the present invention, the composition may include siloxane and silicon quaternium in a composition ratio of 1: 0.02 to 1:20. For example, the composition may include siloxane and silicon quaternium in a composition ratio of 1: 0.06 to 1:20, 1: 0.1 to 1:20, 1: 0.5 to 1:20, 1: 1 to 1:20, and 1: 3 to 1:20, 1: 5 to 1:20, 1: 0.02 to 1:18, 1: 0.02 to 1:15, 1: 0.02 to 1:12, 1: 0.02 to 1:10, 1: 0.02 to 1: 5, 1: 0.02 to 1: 1, 1: 0.02 to 1: 0.5, 1: 0.02 to 1: 0.1, 1: 0.06 to 1:18, 1: 0.06 to 1:15, 1: 0.06 to 1:12, 1: 0.06 to 1:10, 1: 0.06 to 1: 5, 1: 0.06 to 1: 1, 1: 0.06 to 1: 0.5, 1: 0.06 to 1: 0.1, 1: 0.1 to 1:18, 1: 0.1 to 1:15, 1: 0.1 to 1:12, 1: 0.1 to 1:10, 1: 0.1 to 1: 5, 1: 0.1 to 1: 1, 1: 0.1 to 1: 0.5, 1: 0.1 to 1: 0.1, 1: 3 to 1:18, 1: 3 to 1:15, 1: 3 to 1:12, 1: 3 to 1:10, 1: 3 to 1: 5, 1: 3 to 1: 1, 1: 3 to 1: 0.5, or 1: 3 to 1: 0.1. Compositions comprising siloxanes and silicon quaternium outside the above ratios have poor shape memory capabilities.

In one embodiment of the present invention, the composition may include siloxane and silicon quaternium in a composition ratio of 1: 0.02 to 1:20, 1: 0.45 to 1: 3, or 1: 0.06 to 1: 0.5.

The cosmetic composition is (a) a shape memory polymer; And (b) may be an oil-in-water cosmetic composition comprising at least one compound of the amine compound and sulfonic acid compound.

In one embodiment of the present invention, the shape memory polymer is polyurethane-59 (Polyurethane-59), Fiji-150 / stearyl alcohol / SM Diacopolymer (PEG-150 / Stearyl Alcohol / SMDIcopolymer) and Fiji-240 It may be one or more selected from the group consisting of / H-diadiapolymer / bis-decyl tetradeces-20 ether (PEG-240 / HDIcopolymer / Bis-decyltetradeceth-20ether), but is not limited thereto.

In an embodiment of the present invention, the amine-based compound is triethanolamine (Triethanolamine), tromethamine (Tromethamine), ethanolamine (Ethanolamine), stearimidopropyl Dimethylamine (Stearamidopropyl Dimethylamine), tetrahydroxypropyl ethylene diamine ( Tetrahydroxypropyl Ethylenediamine), acetyl glucosamine (Acetyl Glucosamine) and stearimidopropyl dimethylamine (Stearamidopropyl Dimethylamine) may be one or more selected from the group consisting of, but is not limited thereto.

In one embodiment of the present invention, the sulfonic acid compound is sodium c8-16 isoalkyl succinyl lactoglobulin sulfonate, sodium xylenesulfonate, phenylbenzimidazole sulfonic Phenylbenzimidazole Sulfonicacid, Disodium Phenyldibenzimidazole Tetrasulfonate, Disodium Laureth Sulfosuccinate, Disodium Lauryl Sulfosuccinate TEA-dodecyl Benzenesulfonate, Sodium c14-16 Olefin Sulfonate, Sodium Hexanesulfonate, Sodium Benzotriazolyl Butylphenol Sulfonate Butylphenol Sulfonate) and Polydodecaneamideaminium triazadiphenyl ethenesulfonate (Polydodecanamideaminium) Triazadiphenyl Ethenesulfonate) may be one or more selected from the group consisting of, but is not limited thereto.

In one embodiment of the present invention, the hardness value of the oil-in-water cosmetic composition may be 7.0 g to 10.0 g.

As used herein, the term "hardness (hardness)" is a test of the softness or hardness of a material (object) in a defined (promise) method, and the result is expressed numerically, and generally a hardness value (load weight) The larger the unit (g), the harder the physical properties of the material.

In one embodiment of the present invention, at least one compound of the (b) amine compound and sulfonic acid compound may be a mixture of an amine compound and a sulfonic acid compound.

In one embodiment of the present invention, when (b) at least one compound of the amine compound and sulfonic acid compound is a mixture, the mixing ratio of the amine compound: sulfonic acid compound may be 3: 1 to 1: 3.

In one embodiment of the present invention, the oil-in-water cosmetic composition is to comprise at least one compound of the (a) shape memory polymer and (b) amine compound and sulfonic acid compound in a composition ratio of 1: 0.2 to 1: 200.0. Can be. For example, (a) the shape memory polymer, and (b) at least one compound of the amine compound and the sulfonic acid compound may have a composition ratio of 1: 0.5 to 1: 200.0, 1: 0.8 to 1: 200.0, and 1: 1 to 1: 200.0. , 1: 0.2 to 1: 150.0, 1: 0.2 to 1: 100.0, 1: 0.2 to 1: 80.0, 1: 0.2 to 1: 50.0, 1: 0.2 to 1: 30.0, 1: 0.2 to 1: 10.0, 1 : 0.2 to 1: 6.7, 1: 0.2 to 1: 3.3, 1: 0.2 to 1: 1, 1: 0.5 to 1: 150.0, 1: 0.5 to 1: 100.0, 1: 0.5 to 1: 80.0, 1: 0.5 To 1: 50.0, 1: 0.5 to 1: 30.0, 1: 0.5 to 1: 10.0, 1: 0.5 to 1: 6.7, 1: 0.5 to 1: 3.3, 1: 0.5 to 1: 1, 1: 0.8 to 1 : 150.0, 1: 0.8-1: 100.0, 1: 0.8-1: 80.0, 1: 0.8-1: 50.0, 1: 0.8-1: 30.0, 1: 0.8-1: 10.0, 1: 0.8-1: 6.7 , 1: 0.8 to 1: 3.3, 1: 0.8 to 1: 1, 1: 1 to 1: 150.0, 1: 1 to 1: 100.0, 1: 1 to 1: 80.0, 1: 1 to 1: 50.0, 1 1: 1 to 1: 30.0, 1: 1 to 1: 10.0, 1: 1 to 1: 6.7, and 1: 1 to 1: 3.3. If the composition ratio is other than the above, there is a problem that the pickup force is significantly reduced.

In one embodiment of the present invention, the oil-in-water cosmetic composition is a composition ratio of 1: 0.2 to 1: 200.0, 1: at least one compound of the (a) shape memory polymer and (b) amine compound and sulfonic acid compound. 0.5 to 1: 30.0, 1: 1 to 1: 6.7.

In one embodiment of the present invention, the oil-in-water cosmetic composition may comprise (a) the shape memory polymer 0.1% to 5.0% by weight relative to the total composition weight. For example, the (a) shape memory polymer may be 0.2 wt% to 5.0 wt%, 0.3 wt% to 5.0 wt%, 0.4 wt% to 5.0 wt%, 0.5 wt% to 5.0 wt%, and 0.6 wt% to the total composition weight. 5.0 wt%, 0.7 wt% to 5.0 wt%, 0.8 wt% to 5.0 wt%, 0.9 wt% to 5.0 wt%, 1.0 wt% to 5.0 wt%, 1.1 wt% to 5.0 wt%, 1.2 wt% to 5.0 wt% %, 1.3 wt% to 5.0 wt%, 1.4 wt% to 5.0 wt%, 1.5 wt% to 5.0 wt%, 1.6 wt% to 5.0 wt%, 1.7 wt% to 5.0 wt%, 1.8 wt% to 5.0 wt%, 1.9% to 5.0%, 2.0% to 5.0%, 0.1% to 4.0%, 0.2% to 4.0%, 0.3% to 4.0%, 0.4% to 4.0%, 0.5% % To 4.0 wt%, 0.6 wt% to 4.0 wt%, 0.7 wt% to 4.0 wt%, 0.8 wt% to 4.0 wt%, 0.9 wt% to 4.0 wt%, 1.0 wt% to 4.0 %, 1.1 wt% to 4.0 wt%, 1.2 wt% to 4.0 wt%, 1.3 wt% to 4.0 wt%, 1.4 wt% to 4.0 wt%, 1.5 wt% to 4.0 wt%, 1.6 wt% to 4.0 wt%, 1.7 wt% to 4.0 wt%, 1.8 wt% to 4.0 wt%, 1.9 wt% to 4.0 wt%, 2.0 wt% to 4.0 wt%, 0.1 wt% to 3.0 wt%, 0.2 wt% to 3.0 wt%, 0.3 wt% % To 3.0%, 0.4% to 3.0%, 0.5% to 3.0%, 0.6% to 3.0%, 0.7% to 3.0%, 0.8% to 3.0%, 0.9% to 3.0 wt%, 1.0 wt% to 3.0 wt%, 1.1 wt% to 3.0 wt%, 1.2 wt% to 3.0 wt%, 1.3 wt% to 3.0 wt%, 1.4 wt% to 3.0 wt%, 1.5 wt% to 3.0 wt% %, 1.6 wt% to 3.0 wt%, 1.7 wt% to 3.0 wt%, 1.8 wt% to 3.0 wt%, 1.9 wt% to 3.0 wt%, 2.0 wt% to 3.0 wt%. If less than 0.1% by weight shows a low viscosity flowing like water, the thickening effect is insignificant, if the amount exceeds 5.0% by weight, the thickening effect is too large, there is a problem in that the applicability is heavy.

In one embodiment of the present invention, the oil-in-water cosmetic composition comprises (a) the shape memory polymer 0.1% to 5.0% by weight, 0.5% to 4.0% by weight, 1.5% to 3.0% by weight relative to the total composition weight can do.

In one embodiment of the present invention, the oil-in-water cosmetic composition may include 1.0% to 20.0% by weight of one or more compounds of the (b) amine compound and sulfonic acid compound based on the total weight of the composition. For example, (b) 1.0% to 20.0% by weight, 2.0% to 20.0% by weight, 3.0% to 20.0% by weight, and 4.0% by weight of the at least one compound of the amine compound and the sulfonic acid compound, based on the total composition weight 20.0 wt%, 5.0 wt% to 20.0 wt%, 1.0 wt% to 18.0 wt%, 2.0 wt% to 18.0 wt%, 3.0 wt% to 18.0 wt%, 4.0 wt% to 18.0 wt%, 5.0 wt% to 18.0 wt% %, 1.0 wt% to 15.0 wt%, 2.0 wt% to 15.0 wt%, 3.0 wt% to 15.0 wt%, 4.0 wt% to 15.0 wt%, 5.0 wt% to 15.0 wt%, 1.0 wt% to 12.0 wt%, 2.0 wt% to 12.0 wt%, 3.0 wt% to 12.0 wt%, 4.0 wt% to 12.0 wt%, 5.0 wt% to 12.0 wt%, 1.0 wt% to 10.0 wt%, 2.0 wt% to 10.0 wt%, 3.0 wt% % To 10.0 wt%, 4.0 wt% to 10.0 wt%, 5.0 wt% to 10.0 wt%. If the content is less than 1.0% by weight, the amine compound or sulfonic acid compound is ineffective due to the low content, and when it is more than 20.0% by weight, the pH is higher or lower than the general cosmetic composition to reduce the stability of the formulation. There is this.

In one embodiment of the present invention, the oil-in-water cosmetic composition is (b) 1.0% to 20.0% by weight, 2.0% to 15.0% by weight of the at least one compound of the amine compound and sulfonic acid-based compound, 3.0% by weight, 3.0 It may include 1% by weight to 10.0% by weight.

In one embodiment of the present invention, the oil-in-water cosmetic composition may be for skin defect correction.

The term "skin flaw correction" as used herein means to cover and compensate for irregularities, blemishes, pores or wrinkles that are perceived by the consumer as skin flaws. The irregularities, blemishes, pores or wrinkles of the skin, which are the skin defects, serve to create curvature of the skin surface, thereby inhibiting the appearance of the skin.

In one embodiment of the present invention, the oil-in-water cosmetic composition may be for skin defect correction.

The term "easy to apply" as used in the present invention means the degree to which the consumer feels easy to apply the cosmetic composition thinly on the outer surface of the desired skin area.

As used herein, the term "easy to hand" or "pickup force" means the degree to which the consumer feels easy to pick-up the cosmetic composition by a finger or a spatula or the like. Preferably, it refers to the case of using a finger without a tool such as a spatula.

As used herein, the term "association aesthetic" or "natural associative force" refers to the extent to which the consumer feels beautiful when the cosmetic composition is reunited after deforming its shape by contact with a finger or a spatula or the like. do.

In one embodiment of the present invention, the cosmetic composition may further include an aqueous phase component and an oil phase component.

The water phase component is purified water as a solvent, propanediol (Propanediol), glycerin (Glycerine), butylene glycol (Buthyleneglycol), propylene glycol (Dipropyleneglycol), pentylene glycol (Penthleneglycol), hex Hexyleneglycol, polyethyleneglycol, sorbitol, and the like may contain one or more polyols selected from the group consisting of, but is not limited thereto.

The oil phase component is a volatile oil and phytosqualane of cyclic silicone oils such as Decamethyl Cyclopentasiloxane and Octamethyl Cyclopentasiloxane, and hydrocarbons having 8 to 20 carbon atoms. Ethylhexyl Palmitate, Butylene Glycol Dicaprylate / Dicaprate, Caprylic / Capric Triglyceride, Triethylhexanoin Esters such as diisostearyl malate, polyglyceryl-2 triisostearate, dicaprylyl carbonate, isononyl isononanoate, and the like Oils and Phenyl Trimethicone, Methyl Trimethicone, Dimethic one), silicone oils such as Caprylyl Methicone, Dipheynylsiloxy Phenyl Trimethicone and Ozokerite, Ceresin, Carnauba Wax, Candelilla Wax, Paraffin Wax, Behenyl Alcohol, Lecithin, Polyhydroxystearic Acid, Isopropyl Myristate, Isopropyl Isostearic Acid, Stearoyl Inulin, Dextrin Palmitate, Glyceryl Behenate / Eicosadioate, Disteardimonium Hectorite , Thickeners such as stearalkonium hectorite, bentonite, silica dimethylsilylate, and acrylates / ethylhexyl acrylates / Dispersants such as Acrylates / Ethylhexyl Acrylate / Dimethicone Methacrylate Copolymer, Fatty Alcohol, Fatty Acid or Higher Alcohol may be used, but are not limited thereto. .

In addition, it may include components commonly used in the cosmetic composition of the present invention, for example, surfactants, pH adjusting agents, pigments, flavors, pigments, preservatives, fungicides, thickeners, antioxidants, stabilizers, solubilizers, metals Various additives such as ion blockers, refreshing agents, deodorants, emulsifiers, solubilizers and moisturizers, ultraviolet absorbers, ultraviolet scatterers, vitamins, plant extracts, skin astringents, anti-inflammatory agents, cell activators, vasodilators, blood stimulators, skin functions Adjuvants, such as anti-inflammatory agents, and carriers, and the like, and the formulations and additives thereof are not limited thereto. The ingredients may also be introduced in amounts generally used in the field of dermatology.

The cosmetic composition of the present invention is not particularly limited in its formulation, and may include a cosmetic composition blending component commonly used in the art to which the invention pertains, depending on the formulation to be prepared. The cosmetic composition of the present invention may be formulated, for example, as a liquid product, lotion, essence, cream, sun lotion, sun cream, makeup base, foundation, BB cream, stick-like product or balm type product, It is not limited to this. In addition, depending on the formulation to be prepared, oil, water, surfactants, moisturizers, lower alcohols, thickeners, chelating agents, preservatives, fragrances and the like may be selected and added. In addition, it may include a sunscreen, a light scattering agent and the like, the formulation and additives are not limited to the above. The ingredients may also be introduced in amounts generally used in the field of dermatology.

The cosmetic composition of the present invention may include, but is not limited to, wrinkle improvement cosmetics, cosmetics for whitening, sunscreens, light scattering agents, and the like, to add or enhance functionality. The water-in-oil cosmetic composition of the present invention can be used directly by spraying or spraying on the skin according to its form.

The cosmetic composition of the present invention can be applied directly to the skin or sprayed according to its form. The amount of use of the composition and the number of times of use per day are appropriately set according to the user's age, sex, use, degree of symptoms, and the like, but for example, an appropriate amount of the composition is 5 or 6 times / day from 1 / day. Can be applied to the skin at frequent frequencies.

The water-in-oil cosmetic composition of the cosmetic composition of the present invention is a water-in-oil formulation containing siloxane and silicone quaternium, and gives an immediate skin wrinkle improvement or immediate skin elasticity improvement effect through shape memory ability, and improves skin radiance or skin moisturizing ability. Enhancement effect can be given. In addition, the oil-in-water cosmetic composition of the composition of the present invention is an oil-in-water formulation containing a shape memory polymer and an amine compound or a sulfonic acid compound, and has excellent shape memory capability and can provide excellent pick-up force and natural associative effect. have.

1 shows the shapes of Formulation Example 1 and Comparative Formulation Example 1. FIG.

Figure 2 shows the shapes of Formulation Example 2 and Comparative Formulation Example 2.

Hereinafter, the present invention will be described in more detail with reference to Examples. However, the examples are only to aid the understanding of the present invention, and the scope of the present invention is not limited by these examples in any sense.

Example  1 to 13 and Comparative example  Preparation of 1-3

The water-in-oil cosmetic compositions of Examples 1 to 13 and Comparative Examples 1 to 3 were prepared using the compositions shown in Table 1 below (unit: wt%). As the siloxane compound, cyclopentasiloxane or cyclohexasiloxane was used, and as the silicon quaternium compound, ABIL ME 45 (containing 30% silicon quaternium-22, manufactured by Evonik) was used.

		Example 1	Example 2	Example 3	Example 4	Example 5	Example 6	Example 7	Example 8	Example 9	Example 10	Example 11	Example 12	Example 13	Comparative Example 1	Comparative Example 2	Comparative Example 3
(a) siloxane compound	Cyclopentasiloxane	30.00	30.00	30.00	30.00	-	-	-	-	15.00	30.00	-	30.00	-	30.00	-	-
	Cyclohexasiloxane	-	-	-	-	30.00	30.00	30.00	30.00	15.00	-	30.00	-	30.00	-	30.00	-
(b) silicon quaternium compounds	ABIL ME 45 (silicone quaternium-22 equivalent)	40.00 (12.00)	30.00 (9.00)	15.00 (4.50)	6.00 (1.80)	40.00 (12.00)	30.00 (9.00)	15.00 (4.50)	6.00 (1.80)	15.00 (4.50)	50.00 (15.00)	50.00 (15.00)	20.00 (6.00)	20.00 (6.00)	-	-	30.00 (9.00)
(a) :( b) Composition ratio		1: 0.4	1: 0.3	1: 0.15	1: 0.06	1: 0.4	1: 0.3	1: 0.15	1: 0.06	1: 0.15	1: 0.5	1: 0.5	1: 0.2	1: 0.2	-	-	-
(c) other	Disodium ID	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity
	1.3-butylene glycol	8.00	8.00	8.00	8.00	8.00	8.00	8.00	8.00	8.00	8.00	8.00	8.00	8.00	8.00	8.00	8.00
	ABIL EM 90	2.00	2.00	2.00	2.00	2.00	2.00	2.00	2.00	2.00	2.00	2.00	2.00	2.00	2.00	2.00	2.00
	Purified water	To 100	To 100	To 100	To 100	To 100	To 100	To 100	To 100	To 100	To 100	To 100	To 100	To 100	To 100	To 100	To 100

In Table 1, Examples 1 to 4 contain 30.00% by weight of cyclopentasiloxane as the siloxane compound, ABIL ME 45 as the silicon quaternium compound in Example 1 is 40.00% by weight, Example 2 is 30.00% by weight, and Example 3 Silver 15.00 wt%, Example 4 includes 6.00 wt%. Examples 5 to 8 contain 30.00% by weight of cyclohexasiloxane with the siloxane compound, 40.00% by weight for Example 1, 30.00% for Example 2, and 15.00 for Example 3 for ABIL ME 45 with a silicon quaternium compound %, Example 4 comprises 6.00% by weight. Example 9 comprises a mixture comprising cyclopentasiloxane and cyclohexasiloxane at 15.00 wt% each as a siloxane compound, and 15.00 wt% ABIL ME 45 as a silicon quaternium compound. Examples 10 and 12 contain 30.00 weight percent cyclopentasiloxane, ABIL ME 45 with a silicon quaternium compound Example 10 50.00 weight percent Example 12 contains 20.00 weight percent. Examples 11 and 13 contain 30.00 weight percent cyclohexasiloxane, ABIL ME 45 with a silicon quaternium compound Example 10 50.00 weight percent Example 12 contains 20.00 weight percent. Comparative Examples 1 and 2 did not add ABIL ME 45 in Examples 1 and 2, and Comparative Example 3 did not add cyclopentasiloxane or cyclohexasiloxane in Example 1.

Test Example  One: Example  1 to 13 and Comparative example  Sensory evaluation results of 1 to 3

The sensory evaluation was carried out for the shape memory ability of the Examples 1 to 13 and Comparative Examples 1 to 3 and the immediate gloss improvement upon application.

For the sensory evaluation, Examples 1 to 13 and Comparative Examples 1 to 3 were to compare the effect of the product to 20 consumers in women in their 20s and 30s, was evaluated as bad, normal, good, very good. The evaluation results for each item are shown in Table 2 below.

Test Items

Example 1

Example 2

Example 3

Example 4

Example 5

Example 6

Example 7

Example 8

Example 9

Example 10

Example 11

Example 12

Example 13

Comparative Example 1

Comparative Example 2

Comparative Example 3

Shape memory

good

Very good

good

usually

good

Very good

good

usually

good

usually

usually

Very good

Very good

Bad

Bad

Bad

Immediate gloss improvement when applying

Very good

Very good

Very good

usually

Very good

Very good

Very good

usually

Very good

usually

usually

Very good

Very good

Bad

Bad

Bad

As shown in Table 2, prepared Examples 1 to 13 containing both a siloxane compound and a silicon quaternium compound according to the present invention are different from those of Examples 1 to 3, which include the respective compounds. It is confirmed that the immediate gloss improvement of. In addition, through the excellent shape memory capacity, it was confirmed that the immediate wrinkle improvement and immediate elasticity improvement effect will be given.

Example  14 to 19 and Comparative example  4, Manufacture

As a result of sensory evaluation of Table 2, it was confirmed that the shape memory capacity is exhibited when the ratio of siloxane compound: silicon quaternium compound is 1: 0.06 to 1: 0.5. Among them, it was confirmed that the ratio of siloxane compound: silicon quaternium compound showed the best effect at 1: 0.3.

To determine the content range of the siloxane compound based on this, the silicon quaternium compound was added so that the capacity of the siloxane compound was 40% by weight, 15% by weight, 5% by weight and the ratio of siloxane compound: silicon quaternium compound was 1: 0.3. Including Examples 14 to 16 were prepared. In addition, Examples 17-19 were manufactured using silicon quaternium-20 in order to confirm that silicon quaternium compounds other than ABIL ME 45 also show the same effect. Finally, Comparative Example 4 including only silicon quaternium-20 was prepared in order to confirm whether silicon quaternium-20 had its own shape memory effect.

To prepare the water-in-oil cosmetic composition of Examples 14 to 19 with the composition of Table 3 (unit: wt%). The siloxane compound used cyclopentasiloxane or cyclohexasiloxane, and the silicon quaternium compound used ABIL ME 45 or silicon quaternium-20.

		Example 14	Example 15	Example 16	Example 17	Example 18	Example 19	Comparative Example 4
(a) siloxane compounds	Cyclopentasiloxane	40.00	15.00	5.00	30.00	-	30.00	-
	Cyclohexasiloxane	-	-	-	-	30.00	-	-
(b) silicon quaternium compounds	ABIL ME 45 (silicone quaternium-22 equivalent)	40.00 (12.00)	15.00 (4.50)	5.00 (1.50)	-	-	15.00	-
	Silicon Quaternium-20	-	-	-	9.00	9.00	4.50	9.00
(a): (b) Composition ratio		1: 0.3	1: 0.3	1: 0.3	1: 0.3	1: 0.3	1: 0.3	-
(c) other	Disodium ID	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity
	1.3-butylene glycol	8.00	8.00	8.00	8.00	8.00	8.00	8.00
	ABIL EM 90	2.00	2.00	2.00	2.00	2.00	2.00	2.00
	Purified water	To 100	To 100	To 100	To 100	To 100	To 100	To 100

In Table 3, Examples 14 to 17 include cyclopentasiloxane as the siloxane compound, Example 14 includes 40.00 wt%, Example 15 includes 15.00 wt%, Example 16 includes 5.00 wt%, Example 17 contains 30.00 wt%, Examples of silicon quaternium compounds include Examples 14-16 comprising 40.00 weight percent ABIL ME 45 and Example 17 9.00 weight percent silicone quaternium-22. Example 18 contains 30.00 weight percent cyclohexasiloxane as the siloxane compound and 9.00 weight percent silicon quaternium-22 as the silicon quaternium compound. Example 19 comprises a mixture of 30.00 wt% cyclopentasiloxane as the siloxane compound and 15.00 wt% ABIL ME 45 and 4.50 wt% silicon quaternium-22 as the silicon quaternium compound. Comparative Example 4 did not add cyclopentasiloxane in Example 17.

Test Example  2: Example  14 to Example  19 and Comparative example  4 sensory evaluation results

Sensory evaluation was carried out for the shape memory ability of the Examples 14 to 19 and the immediate gloss improvement upon application.

For the sensory evaluation, Examples 14 to 19 were to compare the effect of the product to 20 consumers in women in their 20s and 30s, was evaluated as bad, normal, good, very good. The evaluation results for each item are shown in Table 4 below.

Test Items	Example 14	Example 15	Example 16	Example 17	Example 18	Example 19	Comparative Example 4
Shape memory	usually	Very good	usually	Very good	Very good	Very good	Bad
Immediate gloss improvement when applying	usually	Very good	usually	Very good	Very good	Very good	Bad

As shown in Table 4, when the amount of the siloxane compound is 40% by weight (Example 14) or 5% by weight (Example 16), unlike the 15% by weight (Example 15), the shape memory capacity and instant gloss It was confirmed that all the improvement effects were reduced.

In addition, through Examples 17 to 19 using silicon quaternium-20, which is a silicon quaternium compound other than ABIL ME 45, it is possible to obtain the same excellent shape memory ability and immediate gloss improvement even when using other silicon quaternium compounds. It was confirmed.

Formulation example  1 and Comparative formulation example  1, manufacture

To Comparative Formulation Example 1, which is the makeup formulation of Example 2 and Comparative Example 1 was prepared in the composition of Table 5 below.

No	division	Raw material	Formulation Example 1	Comparative Formulation Example 1
One	Paid	ABIL EM 90	2.00	2.50
2		Cyclopentasiloxane	30.00	30.00
3		Phenyltrimethicone	5.00	5.00
4		Bentonite	0.30	0.30
5	Pigment	Titanium dioxide	Quantity	Quantity
6		Yellow iron oxide	Quantity	Quantity
7		Red iron oxide	Quantity	Quantity
8		Black iron oxide	Quantity	Quantity
9	Awards	Purified water	To 100	To 100
10		Disodium ID	Quantity	Quantity
11		1.3-butylene glycol	8.00	8.00
12		ABIL ME 45	30.00	-
13	additive	Spices	Quantity	Quantity

Test Example  3: shape memory Cosmetics  Of composition formulation Coronary  Shape comparison

Using Formulation Example 1 and Comparative Formulation Example 1, the following test was performed to visually confirm the shape memory ability.

For the comparison of the coronal shape, the shape of the formulation is shown in FIG. 1 after 5 minutes of physical impact using a spatula commonly used for cosmetic pickup in Formulation Example 1 and Comparative Formulation Example 1.

As shown in FIG. 1, in Comparative Formulation Example 1 (FIG. 1A), Formulation Example 1 (FIG. It was confirmed that it was made. This result confirmed that Formulation Example 1 has a shape memory capability.

Test Example  4: shape memory Cosmetics  Skin of the composition formulation Moisturizing  Confirmation of Enhancement Effect

In order to confirm the skin moisturizing effect of Formulation Example 1, a clinical trial was conducted in 22 women aged 19-55 years. In order to confirm the improvement of skin moisturizing power, the change of the epidermal moisture loss was confirmed. Trans Epidermal Water Loss (TEWL) is the amount of water delivered from the body through the epidermal layer of the skin to the atmosphere through the diffusion and evaporation of the skin. Expressed as the g / m ² h value, the amount of water (g) to evaporate. In order to confirm the change in the amount of epidermal moisture loss, before and after use of the cosmetic composition of Formulation Example 1 and two weeks after daily application of the cosmetic composition of Formulation Example 1 to the facial cheek area, The amount of transdermal moisture loss in the cheek area was measured.

Transdermal moisture loss of Formulation Example 1 decreased by 6.24% from 17.02 ± 3.91 g / m ² h before use to 16.02 ± 3.86 g / m ² h after 2 weeks of use. According to the normality test, P-value of the value was less than 0.05 after 2 weeks of use when tested by the parametric paired samples t-test. If the P-value is less than 0.05, it means that there is less than 5% probability that the shine will naturally decrease by 6% in the unapplied experimental group.

Therefore, the results of the experiments confirmed that Formulation Example 1 lowered the moisture loss rate of the skin to promote skin moisturizing power.

Test Example  5: shape memory Cosmetics  Confirmation of improvement of skin luster of composition formulation

In order to confirm the skin gloss improvement effect of Formulation Example 1, a clinical trial was conducted on 22 19-55 year old women. Skin Gloss Meter (SGU) is used to determine the skin gloss unit (SGU) value before and after the use of the cosmetic composition of Formulation Example 1 and daily application of the cosmetic composition of Formulation Example 1 to the facial cheek area for the purpose of checking the shine improvement effect. , Delfin Technologies Ltd, Finland).

The skin gloss value of Formulation Example 1 increased 2.24% from 63.03 ± 6.20 before use to 64.44 ± 6.06 after 2 weeks, and after 2 weeks of use when tested by the paired samples t-test according to the normality test. The P-value of the value was less than 0.05. A P-value of less than 0.05 means less than 5% chance of a natural 2% increase in shine in the unapplied experimental group.

 Therefore, it was confirmed through the statistical results that the formulation example 1 to improve the skin shine through the experimental results.

Example  20 to 28 and Comparative example  Preparation of 5 to 14

To prepare the oil-in-water cosmetic composition of Examples 20 to 28 and Comparative Examples 5 to 14 with the composition of Table 6 and Table 7 (unit: wt%). Examples 20 to 28 and Comparative Example 1 of the present invention were used as the shape memory polymer, ADEKANOL GT-700 (ADEKA, Japan) as a PG-240 / H. copolymer copolymer bis-decyl tetradeces-20 ether.

Raw material name	Example 20	Example 21	Example 22	Example 23	Example 24	Example 25	Example 26	Example 27	Example 28
Purified water	To 100	To 100	To 100	To 100	To 100	To 100	To 100	To 100	To 100
Disodium ID	0.02	0.02	0.02	0.02	0.02	0.02	0.02	0.02	0.02
1.3-butylene glycol	5.0	5.0	5.0	5.0	5.0	5.0	5.0	5.0	5.0
Fiji-240 / HTdiai copolymer bis-decyltetradeces-20 ether	2.0	2.0	2.0	2.0	2.0	2.0	2.0	2.0	2.0
Triethanolamine	8.0	-	-	-	-	-	3.0	-	-
Tromethamine	-	6.0	-	-	-	-	-	-	1.5
Acetyl glucosamine	-	-	5.0	-	-	-	3.0	-	-
Sodium xylenesulfonate	-	-	-	5.0	-	-	-	3.0	-
Sodium hexanesulfonate	-	-	-	-	8.0	-	-	3.0	-
Phenylbenzimidazole sulfonic acid						5.0			3.0
Fiji-26-Bootes-26 / PG-40 Hydrogenated Castor Oil	0.2	0.2	0.2	0.2	0.2	0.2	0.2	0.2	0.2
Spices	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity
antiseptic	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity

Raw material name	Comparative Example 5	Comparative Example 6	Comparative Example 7	Comparative Example 8	Comparative Example 9	Comparative Example 10	Comparative Example 11	Comparative Example 12	Comparative Example 13	Comparative Example 14
Purified water	To 100	To 100	To 100	To 100	To 100	To 100	To 100	To 100	To 100	To 100
Disodium ID	0.02	0.02	0.02	0.02	0.02	0.02	0.02	0.02	0.02	0.02
1.3-butylene glycol	5.0	5.0	5.0	5.0	5.0	5.0	5.0	5.0	5.0	5.0
Fiji-240 / HTdiai copolymer bis-decyltetradeces-20 ether	2.0	-	-	-	-	-	-	-	-	-
Triethanolamine	-	8.0	-	-	-	-	-	3.0	-	-
Tromethamine	-	-	6.0	-	-	-	-	-	-	1.5
Acetyl glucosamine	-	-	-	5.0	-	-	-	3.0	-	-
Sodium xylenesulfonate	-	-	-	-	5.0	-	-	-	3.0	-
Sodium hexanesulfonate	-	-	-	-	-	8.0	-	-	3.0	-
Phenylbenzimidazole sulfonic acid	-	-	-	-	-	-	5.0	-	-	3.0
Fiji-26-Bootes-26 / PG-40 Hydrogenated Castor Oil	0.2	0.2	0.2	0.2	0.2	0.2	0.2	0.2	0.2	0.2
Spices	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity
antiseptic	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity

In Table 6, Examples 20 to 22 are 8.0% by weight of triethanolamine, 6.0% by weight of tromethamine, and 5.0% by weight of acetyl glucosamine as the amine compound, and Examples 23 to 25 are sodium xylene as the sulfonic acid compound. 5.0 wt% sulfonate, 8.0 wt% sodium hexanesulfonate and 5.0 wt% phenylbenzimidazole sulfonic acid. Example 26 includes a mixture of 3.0 wt% of two amine compounds, triethanolamine and acetyl glucosamine, respectively, and Example 27 contains 3.0 wt% of two sulfonic acid compounds, sodium xylenesulfonate and sodium hexanesulfonate, respectively. It contains the mixed mixture. Example 28 includes a mixture of 1.5 wt% of amine-based tromethamine and 3.0 wt% of sulfonic acid-based phenylbenzimidazole sulfonic acid.

In Examples 20 to 28, the content of the shape memory polymer, PIG-240 / H DY Copolymer bis-decyl tetradeces-20 ether, was 2.0% by weight. The components other than the shape memory polymer and the added amine compound, the mixture consisting of the amine compound, the sulfonic acid compound or the mixture of the amine compound and the sulfonic acid compound are the same.

In Table 7, Comparative Example 5 does not add the amine compound and sulfonic acid compound in Example 20, Comparative Examples 6 to 14 do not add the shape memory polymer in Examples 20 to 28.

Test Example  6: Example  20 to 28 and Comparative example  Sensory evaluation of 5 to 14

The sensory evaluations were carried out for the shape memory ability, easy to apply, easy to pick up (pick up force), and aesthetic properties (natural associative force) of the associating shapes of Examples 20 to 28 and Comparative Examples 5 to 14.

For the sensory evaluation, Examples 20 to 28 and Comparative Examples 5 to 14 were used to compare the effect of the product to 20 consumers in their 20s and 30s. Granted. Score average values for each item are shown in Tables 8 and 9 below.

<Evaluation Criteria for Sensory Evaluation>

0: no effect at all, 1: very bad, 2: bad, 3: moderate, 4: good, 5: very good

Test Items	Example 20	Example 21	Example 22	Example 23	Example 24	Example 25	Example 26	Example 27	Example 28
Shape memory	4.8	4.5	4.7	4.8	4.5	4.8	4.7	4.5	4.7
Easy to apply	4.3	4.7	4.4	4.5	4.7	4.5	4.3	4.3	4.8
Easy to get drunk (pick-up power)	4.7	4.6	4.7	4.6	4.5	4.6	4.7	4.5	4.6
Associative aesthetics (natural associative force)	4.5	4.8	4.7	4.6	4.7	4.7	4.5	4.5	4.8

Test Items	Comparative Example 5	Comparative Example 6	Comparative Example 7	Comparative Example 8	Comparative Example 9	Comparative Example 10	Comparative Example 11	Comparative Example 12	Comparative Example 13	Comparative Example 14
Shape memory	4.5	0.8	0.7	0.6	0.7	0.5	0.6	0.7	0.8	0.8
Easy to apply	2.7	4.5	4.7	4.5	4.7	4.6	4.5	4.2	4.4	4.6
Easy to get drunk (pick-up power)	1.8	4.7	4.2	4.5	4.5	4.7	4.8	4.7	4.4	4.5
Associative aesthetics (natural associative force)	1.9	1.2	1.5	1.4	1.5	1.2	1.3	1.2	1.4	1.6

As shown in Table 8 and Table 9, Examples 20 to 28 prepared according to the present invention was confirmed that the same or superior shape memory capacity than the composition of Comparative Examples 5 to 14. In addition, it was confirmed that Examples 20 to 28 showed excellent applicationability, pick-up force, and natural associative force compared to Comparative Example 1, and that the shape memory ability was not shown in Comparative Examples 6 to 14 that do not include the shape memory polymer. It was.

Test Example  7: Example  20 to 28 and Comparative Example  Hardness measurement

The hardness evaluation was carried out to confirm the pickup force and the natural associative force of Examples 20 to 28 and Comparative Example 5 showing the shape memory capacity in Test Example 6.

Hardness was measured using Sun Rheo Meter Compac-100 (Sun Scientific, Japan), the adapter was 10 mm in diameter, the entry distance was 15 m, the maximum stress was measured under 2 kg conditions. The cosmetic compositions of Examples 20 to 28 and Comparative Example 5 were measured to be constantly contained in a cylindrical container 45 mm in diameter, 35 mm in height. The results are shown in Table 10 below (load weight (unit: g)).

	Comparative Example 5	Example 20	Example 21	Example 22	Example 23	Example 24	Example 25	Example 26	Example 27	Example 28
Hardness (g)	31.0	8.0	10.0	9.0	7.0	8.0	10.0	7.0	9.0	9.0

As shown in Table 10, the compositions of Examples 20 to 28 exhibited a hardness value of 7.0 g to 10.0 g, whereas the cosmetic composition of Comparative Example 5 exhibited a high hardness value of 31.0 g. Comparative Example 5 having a high hardness value was very hard to take the hand, Examples 20 to 28 having a low hardness value compared to Comparative Example 5 is not hard and easy to take (excellent pickup force), picked up After confirming that the shape of the cosmetic remaining in the container is associated naturally. These results confirmed that Examples 20 to 28 had a pickup force and a natural associating force compared to Comparative Example 5.

Formulation example  2 and Comparative formulation example  2, manufacturing

Formulation Example 2 and Comparative Formulation Example 2, which are makeup formulations, were prepared using the compositions of Example 23 and Comparative Example 5 in the compositions shown in Table 11 below (unit: wt%).

No.	division	Raw material name	Formulation Example 1	Comparative Formulation Example 1
One	Awards	Purified water	To 100	To 100
2		1,3-butylene glycol	10.0	10.0
3		glycerin	5.0	5.0
4		Disodium ID	0.2	0.2
5		Fiji-240 / HTdiai copolymer bis-decyltetradeces-20 ether	2.0	2.0
6		Sodium xylenesulfonate	5.0	-
7	coloring agent	Titanium dioxide	8.0	8.0
8		Yellow Iron Oxide, Red Iron Oxide, Black Iron Oxide	2.0	2.0
9	Paid	Dimethicone	4.0	4.0
10		Cyclopentasiloxane	7.0	7.0
11		Emulsifier	2.0	2.0
12		antiseptic	Quantity	Quantity
13		Spices	Quantity	Quantity

Test Example  8: Formulation example  2 lesson Comparative formulation example  Visual shape comparison of the makeup formulation of Formula 2

Using the Formulation Example 2 and Comparative Formulation Example 2 was tested as follows to visually determine the shape memory capacity.

For visual comparison, the physical shock was applied using a spatula commonly used for cosmetic pickup in Formulation Example 2 and Comparative Formulation Example 2, and then 5 minutes later, the shape of the formulation and a finger were picked up. One state is shown in FIG.

As shown in the results of Figure 2, Comparative Formulation Example 2 (Fig. 2 (a)) is very hard and dripping tearing and cracking phenomenon and difficult to get in hand (poor pick-up), whereas Formulation Example 2 (Fig. 2 (B)) confirmed that it was easy to get in the hand (excellent pick-up power) while showing the shape to be associated naturally. This confirmed that Formulation Example 2 is excellent in pick-up power to consumers, can provide aesthetic cosmetic formulation.

Test Example  9: according to the invention Cosmetics  Shape memory of composition Polymer  Content range confirmation test

To determine the effect of the content of the shape memory polymer was tested as follows (unit: wt%). As the shape memory polymer, Fiji-240 / H-Didia copolymer bis-decyl tetradeces-20 ether was used, the amine compound was used triethanolamine of Example 20, and the sulfonic acid compound was sodium xyl of Example 23. Rensulfonate was used.

Raw material name	Example 20	Example 23	Example 29	Example 30	Example 31	Example 32	Example 33	Example 34	Example 35	Example 36
Purified water	To 100	To 100	To 100	To 100	To 100	To 100	To 100	To 100	To 100	To 100
Disodium ID	0.02	0.02	0.02	0.02	0.02	0.02	0.02	0.02	0.02	0.02
1.3-butylene glycol	5.0	5.0	5.0	5.0	5.0	5.0	5.0	5.0	5.0	5.0
Fiji-240 / HTdiai copolymer bis-decyltetradeces-20 ether	2.0	2.0	0.5	1.5	3.0	4.0	0.5	1.5	3.0	4.0
Triethanolamine	8.0	-	8.0	8.0	8.0	8.0	-	-	-	-
Sodium xylenesulfonate	-	5.0	-	-	-	-	5.0	5.0	5.0	5.0
Fiji-26-Bootes-26 / PG-40 Hydrogenated Castor Oil	0.2	0.2	0.2	0.2	0.2	0.2	0.2	0.2	0.2	0.2
Spices	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity
antiseptic	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity

In Table 12, Examples 29 to 32 included 8.0% by weight of triethanolamine, which is an amine compound, and Example 29, 0.5% by weight of the content of Fiji-240 / H-DiDi copolymer bis-decyl tetradeces-20 ether Example 30 is 1.5 weight percent, Example 31 is 3.0 weight percent and Example 32 is 4.0 weight percent. Examples 33-36 comprise 5.0 wt% of sodium xylenesulfonate, a sulfonic acid compound, and Example 33, 0.5 wt% of a Fiji-240 / H dii copolymer copolymer bis-decyltetradeces-20 ether , Example 34 is 1.5% by weight, Example 35 is 3.0% by weight, and Example 36 is 4.0% by weight.

<Evaluation Criteria for Sensory Evaluation>

0: no effect at all, 1: very bad, 2: bad, 3: moderate, 4: good, 5: very good

Test Items	Example 20	Example 23	Example 29	Example 30	Example 31	Example 32	Example 33	Example 34	Example 35	Example 36
Shape memory	4.8	4.8	2.8	4.5	4.9	4.9	2.4	4.6	4.9	5.0
Easy to apply	4.3	4.5	4.8	4.7	4.0	1.3	4.9	4.5	3.9	1.5
Easy to get drunk (pick-up power)	4.7	4.6	4.7	4.4	4.1	1.8	4.8	4.6	4.0	1.4
Associative aesthetics (natural associative force)	4.5	4.6	4.1	4.5	4.1	3.5	3.9	4.7	4.0	2.8

Table 13 shows the results of sensory evaluation on the shape memory ability, easy to apply, easy to pick up (pickup force), and the aesthetic effect (natural associative force) of the associative shape of Examples 20 and 23 and Examples 29 to 36. Score result for the item. The sensory evaluation was made to compare the effect of the product on 20 consumers in their 20s and 30s, and they were given a six-stage score of 0-5 points for each item.

As a result of Table 13, 0.5 wt% and 4.0 wt% of Fiji-240 / H-Didia copolymer bis-decyltetradeces-20 ether had a shape memory ability, easy to apply, and easy to get hand (pickup force) ) And the aesthetic properties (natural associative force) of the association shape were confirmed. Especially, it is easy to apply and easy to apply while maintaining the existing shape memory ability at 1.5 wt% and 3.0 wt% of PHY-240 / H diady copolymer bis-decyl tetradeces-20 ether ) And the aesthetics of the associative shape (natural associative force) were improved.

Test Example  10: according to the invention Cosmetics  Of composition Amine  Compound or sulfonic acid compound content range identification test

To determine the effect according to the content of the amine compound or sulfonic acid compound was tested as follows (unit: wt%). As the amine compound and the sulfonic acid compound, triethanolamine and sodium xylenesulfonate used in Test Example 9 were used.

Raw material name	Example 20	Example 23	Example 37	Example 38	Example 39	Example 40	Example 41	Example 42	Example 43	Example 44
Purified water	To 100	To 100	To 100	To 100	To 100	To 100	To 100	To 100	To 100	To 100
Disodium ID	0.02	0.02	0.02	0.02	0.02	0.02	0.02	0.02	0.02	0.02
1.3-butylene glycol	5.0	5.0	5.0	5.0	5.0	5.0	5.0	5.0	5.0	5.0
Fiji-240 / HTdiai copolymer bis-decyltetradeces-20 ether	2.0	2.0	2.0	2.0	2.0	2.0	2.0	2.0	2.0	2.0
Triethanolamine	8.0	-	2.0	3.0	10.0	15.0	-	-	-	-
Sodium xylenesulfonate	-	5.0	-	-	-	-	2.0	3.0	10.0	15.0
Fiji-26-Bootes-26 / PG-40 Hydrogenated Castor Oil	0.2	0.2	0.2	0.2	0.2	0.2	0.2	0.2	0.2	0.2
Spices	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity
antiseptic	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity	Quantity

In Table 14, Examples 37 to 40 include triethanolamine as the amine compound, Example 37 has a 2.0% by weight triethanolamine content, Example 38 is 3.0% by weight, Example 39 is 10.0% by weight, Example 40 is 15.0 weight percent. Examples 41 to 44 include sodium xylenesulfonate as the sulfonic acid compound, Example 41 has a sodium xylenesulfonate content of 2.0 wt%, Example 42 is 3.0 wt%, and Example 43 is 10.0 wt% Example 44 is 15.0 wt.%.

<Evaluation Criteria for Sensory Evaluation>

0: no effect at all, 1: very bad, 2: bad, 3: moderate, 4: good, 5: very good

Test Items	Example 20	Example 23	Example 37	Example 38	Example 39	Example 40	Example 41	Example 42	Example 43	Example 44
Shape memory	4.8	4.8	4.7	4.5	3.7	3.2	4.8	4.8	3.8	3.2
Easy to apply	4.3	4.5	3.3	3.7	4.5	4.8	3.2	3.4	4.5	4.7
Easy to get drunk (pick-up power)	4.7	4.6	3.5	3.7	4.0	4.5	3.8	3.9	4.5	4.8
Associative aesthetics (natural associative force)	4.5	4.6	3.3	3.4	3.5	3.2	3.4	3.8	3.7	3.5

Table 15 shows the results of sensory evaluation on the shape memory ability, ease of application, ease of hand (pickup force), and aesthetic effect (natural association force) of the associative shape of Examples 20, 23 and 37 to 44, respectively. Score result for the item. The sensory evaluation was made to compare the effect of the product on 20 consumers in their 20s and 30s, and they were given a six-stage score of 0-5 points for each item.

As shown in the results of Table 15, for each of the amine compound and the sulfone compound, the content of 2.0% to 15.0% by weight is shape memory ability, easy to apply, easy to pick up (pickup force), and associative aesthetics (natural It was confirmed that there is an effect to impart an association force). Particularly, for each of the amine compound and the sulfone compound, the content of 3.0 wt% to 10.0 wt% is easy to apply, easy to pick up (pickup force), and associative aesthetic (natural associative force) while maintaining the existing shape memory ability. ) Has been improved.

Test Example  11: according to the invention Cosmetics  Of composition Amine  Content range identification test of compound and sulfonic acid compound mixture

When using a mixture of an amine compound and a sulfonic acid compound, the contents of the mixture of tromethamine and phenylbenzimidazole sulfonic acid were tested as follows (unit: wt%) to determine the content range of the mixture. The shape memory polymer used a PYG-240 / H DY Copolymer bis-decyl tetradeces-20 ether content range of 2.0% by weight.

Raw material name	Example 45	Example 46	Example 47	Example 48
Purified water	To 100	To 100	To 100	To 100
Disodium ID	0.02	0.02	0.02	0.02
Butylene glycol	5.0	5.0	5.0	5.0
Fiji-240 / HTdiai copolymer bis-decyltetradeces-20 ether	2.0	2.0	2.0	2.0
Tromethamine	1.5	3.0	5.0	10
Phenylbenzimidazole sulfonic acid	1.5	3.0	5.0	10
Fiji-26-Bootes-26 / PG-40 Hydrogenated Castor Oil	0.2	0.2	0.2	0.2
Spices	Quantity	Quantity	Quantity	Quantity
antiseptic	Quantity	Quantity	Quantity	Quantity

In Table 16, Example 45 is 1.5% by weight of each of the amine-based tromethamine and sulfonic acid-based compound phenylbenzimidazole sulfonic acid, Example 46 is 3.0% by weight, Example 47 is 5.0% by weight %, Example 48 is 10.0 wt.%.

<Evaluation Criteria for Sensory Evaluation>

0: no effect at all, 1: very bad, 2: bad, 3: moderate, 4: good, 5: very good

Test Items	Example 45	Example 46	Example 47	Example 48
Shape memory	4.5	4.7	4.0	3.4
Easy to apply	3.5	4.5	4.6	4.8
Easy to get drunk (pick-up power)	3.7	4.4	4.7	4.8
Associative aesthetics (natural associative force)	3.2	4.6	3.5	3.2

Table 17 shows the results of score average values for each item after performing the sensory evaluation on the shape memory ability, easy to apply, easy to pick up (pick up force), and the aesthetic properties of the association shape (natural associative force) of Examples 45 to 48. . The sensory evaluation was made to compare the effect of the product on 20 consumers in their 20s and 30s, and they were given a six-stage score of 0-5 points for each item.

As a result of Table 17, with respect to the mixture of the amine compound and the sulfone compound, the shape memory ability, easy to apply, and easy to get in the case where the content (wt%) is 3.0 wt% to 10.0 wt% It was confirmed that there is an effect of imparting the pickup force) and the aesthetic properties (natural association force) of the association shape. However, when the content of the mixture of the amine compound and the sulfone compound is 20% by weight. It was confirmed that shape memory ability and association shape aesthetics (natural association force) decreased.

Test Example  12: according to the invention Cosmetics  Of composition Amine  Mixing ratio confirmation test of compound and sulfonic acid compound mixture

When using a mixture of an amine compound and a sulfonic acid compound, to determine the mixing ratio of the amine compound and the sulfonic acid compound in the mixture, the amount of tromethamine and 6.0% by weight of Example 46, which was effective in Test Example 11, was used. Phenylbenzimidazole sulfonic acid mixing ratio was tested as follows (unit: wt%).

Raw material name	Example 46	Example 49	Example 50	Example 51	Example 52
Purified water	To 100	To 100	To 100	To 100	To 100
Disodium ID	0.02	0.02	0.02	0.02	0.02
Butylene glycol	5.0	5.0	5.0	5.0	5.0
Fiji-240 / HTdiai copolymer bis-decyltetradeces-20 ether	2.0	2.0	2.0	2.0	2.0
Tromethamine	3.0	4.0	4.5	2.0	1.5
Phenylbenzimidazole sulfonic acid	3.0	2.0	1.5	4.0	4.5
Fiji-26-Bootes-26 / PG-40 Hydrogenated Castor Oil	0.2	0.2	0.2	0.2	0.2
Spices	Quantity	Quantity	Quantity	Quantity	Quantity
antiseptic	Quantity	Quantity	Quantity	Quantity	Quantity

In Table 18, Example 46 has a mixing ratio of tromethamine as an amine compound and phenylbenzimidazole sulfonic acid as sulfonic acid compound as 1: 1, Example 49 is 2: 1, and Example 50 is 3: 1, Example 51 is 1: 2, and Example 52 is 1: 3.

<Evaluation Criteria for Sensory Evaluation>

0: no effect at all, 1: very bad, 2: bad, 3: moderate, 4: good, 5: very good

Test Items	Example 46	Example 49	Example 50	Example 51	Example 52
Shape memory	4.6	4.3	4.1	4.8	4.6
Easy to apply	4.4	4.6	4.4	4.7	4.4
Easy to get drunk (pick-up power)	4.5	4.5	4.5	4.5	4.5
Associative aesthetics (natural associative force)	4.4	4.2	3.8	4.8	4.3

Table 19 shows the scores for each item after performing the sensory evaluation on the shape memory capacity, easy to apply, easy to pick up (pick up force) and aesthetic effect (natural association force) of the association shape of Examples 46, 49 to 51. The mean value is the result. The sensory evaluation was made to compare the effect of the product on 20 consumers in their 20s and 30s, and they were given a six-stage score of 0-5 points for each item.

As shown in Table 19, with respect to the mixture of the amine compound and the sulfone compound, the shape-memory ability, ease of application, ease of handling (pick-up force) and the like in the examples in which the mixing ratio is 3: 1 to 1: 3 and It was confirmed that there was an effect of imparting the aesthetic properties (natural associative force) of the association shape.

Claims (18)

1. Cosmetic composition having shape memory ability
2. The method of claim 1,

   The cosmetic composition includes (a) siloxane; And (b) a water-in-oil cosmetic composition comprising silicon quaternium.
3. The method of claim 2,

   The (a) siloxane is characterized in that at least one selected from the group consisting of cyclotrisiloxane (Cyclotrisiloxane), cyclotetrasiloxane (Cyclotetrasiloxane), cyclopentasiloxane (Cyclopentasiloxane), cyclohexasiloxane (Cyclohexasiloxane) and cycloheptasiloxane (Cycloheptasiloxane) A water-in-oil cosmetic composition.
4. The method of claim 2,

   (B) the silicon quaternium is silicon quaternium-1, silicon quaternium-3, silicon quaternium-8, silicon quaternium-15 Silicone Quaternium-15), Silicon Quaternium-16. Water-in-oil cosmetics, characterized in that at least one selected from the group consisting of silicon quaternium-18, silicon quaternium-20 and silicon quaternium-22 Composition.
5. The method of claim 2,

   Water-in-oil cosmetic composition, characterized in that the (a) siloxane is 1 to 50% by weight, and (b) the silicon quaternium is 1 to 20% by weight based on the total composition weight of the water-in-oil cosmetic composition.
6. The method of claim 2,

   The water-in-oil cosmetic composition is a water-in-oil cosmetic composition characterized in that the composition ratio of (a) siloxane and (b) silicon quaternium is 1: 0.02 to 1:20.
7. The method according to any one of claims 2 to 6,

   The water-in-oil cosmetic composition is water-in-oil cosmetic composition characterized in that for immediate skin wrinkle improvement, immediate skin elasticity improvement or immediate skin gloss improvement.
8. The method according to any one of claims 2 to 6,

   The water-in-oil cosmetic composition is a water-in-oil cosmetic composition, characterized in that for improving skin luster or skin moisturizing.
9. The method of claim 1,

   The cosmetic composition is

   (a) shape memory polymer; And

   (b) at least one compound of the amine compound and the sulfonic acid compound

   Oil-in-water cosmetic composition comprising a.
10. The method of claim 9,

    The shape memory polymers include polyurethane-59 (POLYURETHANE-59), Fiji-150 / Stearyl Alcohol / SM Diacopolymer (PEG-150 / STEARYL ALCOHOL / SMDICOPOLYMER) and Fiji-240 / H-Diacicopolymer / Bis- Oil-in-water cosmetic composition characterized in that at least one member selected from the group consisting of decyl tetradeceth-20 ether (PEG-240 / HDICOPOLYMER / BIS-DECYLTETRADECETH-20ETHER).
11. The method of claim 9,

    The amine compound is triethanolamine (TRIETHANOLAMINE), tromethamine (TROMETHAMINE), ethanolamine (ETHANOLAMINE), stearimidopropyl dimethylamine (STEARAMIDOPROPYL DIMETHYLAMINE), tetrahydroxypropyl ethylene diamine (TETRAHYDROXYPROPYL ETHYLENEDIAMINE company, Oil-in-water cosmetic composition characterized in that at least one member selected from the group consisting of ACETYL GLUCOSAMINE) and stearamidopropyl dimethylamine (STEARAMIDOPROPYL DIMETHYLAMINE).
12. The method of claim 9,

    The sulfonic acid-based compound is sodium C8-16 isoalkyl succinyl lactoglobulin sulfonate (SODIUM C8-16 ISOALKYLSUCCINYL LACTOGLOBULIN SULFONATE), sodium xylene sulfonate (SODIUM XYLENESULFONATE), phenylbenzimidazole sulfonic acid (PHENYLBENZIDAZONIZON) Sodium Phenyldibenzimidazole Tetrasulfonate (DISODIUM PHENYLDIBENZIMIDAZOLE TETRASULFONATE) TEA-DODECYL BENZENESULFONATE, SODIUM C14-16OLEFIN SULFONATE, SODIUM HEXANESULFONATE, SODIUM Benzotriazolyl butylphenol sulfonate (SODIUM BENZOTRIAZOLYL BUTYLPHENOL SULDUMON SULDON) Amidealuminum triazadiphenyl ethenesulfonate (POLYDODECANAMIDEAMINIUM TRIAZADIPHENYL ETHENESULFONATE) In-water type cosmetic composition, characterized in that at least one member selected from the group consisting of.
13. The method of claim 9,

    Oil-in-water cosmetic composition characterized in that the hardness value of the oil-in-water cosmetic composition is 7.0 g to 10.0 g.
14. The method according to claim 9,

    (B) at least one compound of the amine compound and sulfonic acid compound is an oil-in-water cosmetic composition, characterized in that the mixture of the amine compound and sulfonic acid compound.
15. The method of claim 9,

    The mixture is an oil-in-water cosmetic composition, characterized in that the mixing ratio of the amine compound: sulfonic acid compound is 3: 1 to 1: 3.
16. The method of claim 9,

    The oil-in-water cosmetic composition is an oil-in-water cosmetic composition comprising (a) a shape memory polymer in an amount of 0.1% to 5.0% by weight relative to the total weight of the composition.
17. The method of claim 9,

    The oil-in-water cosmetic composition is an oil-in-water cosmetic composition comprising (b) at least one compound of the amine compound and sulfonic acid compound in an amount of 1.0% to 20.0% by weight of the total composition.
18. The method according to any one of claims 9 to 17,

    The oil-in-water cosmetic composition is an oil-in-water cosmetic composition, characterized in that for correcting skin defects.

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