WO2003083181A3 - Process and device for forming ceramic coatings on metals and alloys, and coatings produced by this process - Google Patents

Process and device for forming ceramic coatings on metals and alloys, and coatings produced by this process Download PDF

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Publication number
WO2003083181A3
WO2003083181A3 PCT/GB2002/004305 GB0204305W WO03083181A3 WO 2003083181 A3 WO2003083181 A3 WO 2003083181A3 GB 0204305 W GB0204305 W GB 0204305W WO 03083181 A3 WO03083181 A3 WO 03083181A3
Authority
WO
WIPO (PCT)
Prior art keywords
coatings
microns
acoustic vibrations
alloys
metals
Prior art date
Application number
PCT/GB2002/004305
Other languages
French (fr)
Other versions
WO2003083181A2 (en
Inventor
Alexander Sergeevich Shatrov
Victor Iosifovich Samsonov
Original Assignee
Isle Coat Ltd
Alexander Sergeevich Shatrov
Victor Iosifovich Samsonov
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB0207193A external-priority patent/GB2386907B/en
Application filed by Isle Coat Ltd, Alexander Sergeevich Shatrov, Victor Iosifovich Samsonov filed Critical Isle Coat Ltd
Priority to AU2002329410A priority Critical patent/AU2002329410A1/en
Priority to JP2003580609A priority patent/JP4182002B2/en
Priority to KR1020047014364A priority patent/KR100871332B1/en
Priority to EP02765036.5A priority patent/EP1488024B1/en
Publication of WO2003083181A2 publication Critical patent/WO2003083181A2/en
Priority to NO20034936A priority patent/NO20034936L/en
Publication of WO2003083181A3 publication Critical patent/WO2003083181A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/60—Electroplating characterised by the structure or texture of the layers
    • C25D5/615—Microstructure of the layers, e.g. mixed structure
    • C25D5/617—Crystalline layers
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/18—Electroplating using modulated, pulsed or reversing current
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/005—Apparatus specially adapted for electrolytic conversion coating
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02—Anodisation
    • C25D11/024—Anodisation under pulsed or modulated current or potential
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02—Anodisation
    • C25D11/026—Anodisation with spark discharge
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/20—Electroplating using ultrasonics, vibrations
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/60—Electroplating characterised by the structure or texture of the layers
    • C25D5/605—Surface topography of the layers, e.g. rough, dendritic or nodular layers
    • C25D5/611—Smooth layers
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/627—Electroplating characterised by the visual appearance of the layers, e.g. colour, brightness or mat appearance

Abstract

There is disclosed a process and apparatus for carrying out plasma electrolytic oxidation of metals and alloys, forming ceramic coatings on surfaces thereof at a rate of 2-10 microns per minute. The process comprises the use of high-frequency current pulses of a certain form and having a given frequency range, combined with the generation of acoustic vibrations in a sonic frequency range in the electrolyte, the frequency ranges of the current pulses and the acoustic vibrations being overlapping. The process makes it possible to introduce ultra-disperse powders into the electrolyte, with the acoustic vibrations helping to form a stable hydrosol, and to create coatings with set properties. The process makes it possible to produce dense hard microcrystalline ceramic coatings of thickness up to 150 microns. The coatings are characterised by reduced specific thickness of an external porous layer (less than 14% of the total coating thickness) and low roughness of the oxidised surface, Ra 0.6-2.1 microns.
PCT/GB2002/004305 2002-03-27 2002-09-23 Process and device for forming ceramic coatings on metals and alloys, and coatings produced by this process WO2003083181A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
AU2002329410A AU2002329410A1 (en) 2002-03-27 2002-09-23 Process and device for forming ceramic coatings on metals and alloys, and coatings produced by this process
JP2003580609A JP4182002B2 (en) 2002-03-27 2002-09-23 Process and apparatus for forming ceramic coatings on metals and alloys, and coatings produced by this process
KR1020047014364A KR100871332B1 (en) 2002-03-27 2002-09-23 Process and device for forming ceramic coatings on metals and alloys, and coatings produced by this process
EP02765036.5A EP1488024B1 (en) 2002-03-27 2002-09-23 Process and device for forming ceramic coatings on metals and alloys
NO20034936A NO20034936L (en) 2002-03-27 2003-11-06 Method and device for forming ceramic coatings on metals and alloys as well as coatings produced by this method

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB0207193.4 2002-03-27
GB0207193A GB2386907B (en) 2002-03-27 2002-03-27 Process and device for forming ceramic coatings on metals and alloys, and coatings produced by this process
US10/123,010 US6896785B2 (en) 2002-03-27 2002-04-15 Process and device for forming ceramic coatings on metals and alloys, and coatings produced by this process
US10/123,010 2002-04-15

Publications (2)

Publication Number Publication Date
WO2003083181A2 WO2003083181A2 (en) 2003-10-09
WO2003083181A3 true WO2003083181A3 (en) 2004-09-10

Family

ID=28676486

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2002/004305 WO2003083181A2 (en) 2002-03-27 2002-09-23 Process and device for forming ceramic coatings on metals and alloys, and coatings produced by this process

Country Status (7)

Country Link
EP (1) EP1488024B1 (en)
JP (2) JP4182002B2 (en)
CN (1) CN100503899C (en)
AU (1) AU2002329410A1 (en)
HK (1) HK1059804A1 (en)
NO (1) NO20034936L (en)
WO (1) WO2003083181A2 (en)

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US8900292B2 (en) 2007-08-03 2014-12-02 Boston Scientific Scimed, Inc. Coating for medical device having increased surface area
US8920491B2 (en) 2008-04-22 2014-12-30 Boston Scientific Scimed, Inc. Medical devices having a coating of inorganic material
US8932346B2 (en) 2008-04-24 2015-01-13 Boston Scientific Scimed, Inc. Medical devices having inorganic particle layers
US9284409B2 (en) 2007-07-19 2016-03-15 Boston Scientific Scimed, Inc. Endoprosthesis having a non-fouling surface
KR101701268B1 (en) 2015-04-09 2017-02-13 현대성우메탈 주식회사 Electrolyte solution for PEO on magnesium alloy and PEO method using the same

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WO2003083181A2 (en) * 2002-03-27 2003-10-09 Isle Coat Limited Process and device for forming ceramic coatings on metals and alloys, and coatings produced by this process
US7196459B2 (en) * 2003-12-05 2007-03-27 International Resistive Co. Of Texas, L.P. Light emitting assembly with heat dissipating support
CN100348780C (en) * 2004-03-16 2007-11-14 天津大学 Method of pulse plating nickel based nano composite plating layer and equipment
GB2422249A (en) * 2005-01-15 2006-07-19 Robert John Morse Power substrate
CN100420775C (en) * 2005-05-23 2008-09-24 狄士春 Microarc oxidation process method for surface of steel and ion
CN100396823C (en) * 2005-09-29 2008-06-25 陕西科技大学 Method and device for preparing coating or film using supersonic, water-heating and electrodeposition technology
CN100469946C (en) * 2005-12-19 2009-03-18 广东工业大学 Preparation method of TiC ceramic coating
JP4125765B2 (en) * 2006-09-28 2008-07-30 日本パーカライジング株式会社 Method of coating ceramic film of metal, electrolytic solution used therefor, ceramic film and metal material
WO2008045184A1 (en) * 2006-10-05 2008-04-17 Boston Scientific Limited Polymer-free coatings for medical devices formed by plasma electrolytic deposition
EP2112670B1 (en) 2007-02-15 2018-04-18 Kankyou Engineering Co., Ltd. Method for producing conductor fine particles
EP1967615A1 (en) * 2007-03-07 2008-09-10 Siemens Aktiengesellschaft Method for applying a heat insulation coating and turbine components with a heat insulation coating
EA012825B1 (en) * 2007-04-02 2009-12-30 Владимир Никандрович Кокарев Method of forming a protective ceramic coating on the surface of metal products
GB0720982D0 (en) 2007-10-25 2007-12-05 Plasma Coatings Ltd Method of forming a bioactive coating
CN101333673B (en) * 2008-07-29 2011-11-23 浙江工业大学 Electrolytic solution for preparing nano ceramic coatings by micro-arc oxidation
JP5394021B2 (en) * 2008-08-06 2014-01-22 アイシン精機株式会社 Aluminum alloy piston member and manufacturing method thereof
EP2179752B1 (en) * 2008-10-06 2014-08-13 Biotronik VI Patent AG Implant and method for manufacturing same
AT506583B9 (en) * 2008-10-23 2009-12-15 Happy Plating Gmbh ELECTROCHEMICAL COATING PROCESS
DE102008043970A1 (en) * 2008-11-21 2010-05-27 Biotronik Vi Patent Ag A method for producing a corrosion-inhibiting coating on an implant of a biocorrodible magnesium alloy and implant produced by the method
DE102009012945A1 (en) * 2009-03-12 2010-09-16 Mtu Aero Engines Gmbh Method for producing an abrasive coating and component for a turbomachine
GB2469115B (en) 2009-04-03 2013-08-21 Keronite Internat Ltd Process for the enhanced corrosion protection of valve metals
CN101892507B (en) * 2010-07-29 2012-02-22 南昌航空大学 Method for improving growth speed of titanium alloy microarc oxide film
ES2638666T3 (en) 2011-02-08 2017-10-23 Cambridge Nanolitic Limited Non-metallic coating and production method
KR101349076B1 (en) * 2011-07-20 2014-01-14 현대자동차주식회사 Apparatus and method for forming oxidation layer of manifold block for fuel cell stack
EP2919762A4 (en) * 2012-11-16 2016-07-20 Merck Sharp & Dohme Process for making agglomerates using acoustic mixing technology
KR101476235B1 (en) * 2012-12-11 2014-12-24 한국기계연구원 Method for surface treatment of magnesium material using plasma electrolytic oxidation, anodic films formed on magnesium thereby and solution for surface treatment of magnesium material used for plasma electrolytic oxidation
WO2014175653A1 (en) * 2013-04-23 2014-10-30 인제대학교 산학협력단 Method for preparing nanostructure by electrochemical deposition, and nanostructure prepared thereby
KR101572849B1 (en) * 2013-04-23 2015-12-01 인제대학교 산학협력단 Manufacturing method of nano structures by electrochemical deposition, and nano structures made by the same
GB2513575B (en) 2013-04-29 2017-05-31 Keronite Int Ltd Corrosion and erosion-resistant mixed oxide coatings for the protection of chemical and plasma process chamber components
KR101419273B1 (en) * 2013-08-27 2014-07-15 (주)엠에스티테크놀로지 Method for forming transparent layer on metal surface by plasma electrolytic oxidation
CN103567404A (en) * 2013-11-04 2014-02-12 虞雪君 Composite coating material used for crystallizer and preparation method
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CH708829A1 (en) 2013-11-11 2015-05-15 Panerai Ag Off An aluminum-lithium alloy component comprising a ceramic coating and a method for forming the coating.
CN103695985B (en) * 2013-12-16 2016-02-10 电子科技大学 The method of titania coating is prepared on a kind of nickel metal hydride battery nickel electrode surface
CN104562130B (en) * 2014-08-22 2017-06-16 东莞市武华新材料有限公司 The manufacture method of light metal or the titania based ceramic film of its alloy surface
US9506161B2 (en) * 2014-12-12 2016-11-29 Metal Industries Research & Development Centre Surface treatment of a magnesium alloy
JP2016156036A (en) * 2015-02-23 2016-09-01 株式会社栗本鐵工所 Coating formation method
CN108368632B (en) 2015-12-16 2020-09-25 汉高股份有限及两合公司 Method for depositing titanium-based protective coatings on aluminum
CN109385654A (en) * 2017-08-11 2019-02-26 昆山汉鼎精密金属有限公司 Automatic differential arc oxidation system and method
KR102205173B1 (en) 2019-06-19 2021-01-20 오엠피주식회사 Process for Forming an Oxidization layer on a Inner surface of Metal Products
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CN110257878B (en) * 2019-07-16 2021-06-08 广西大学 Method for preparing micro-arc oxidation film of aluminum-titanium composite plate
CN113943964A (en) * 2020-07-15 2022-01-18 中国科学院上海硅酸盐研究所 Titanium alloy surface thermal control wear-resistant coating and preparation method thereof
CN112708917A (en) * 2020-12-23 2021-04-27 西安工业大学 Preparation method of micro-arc oxidation layer on surface of titanium alloy turbine blade
CN113774459A (en) * 2021-09-29 2021-12-10 上海交通大学 Preparation method of compact high-corrosion-resistance micro-arc oxidation film layer on surface of zirconium alloy
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WO2003083181A2 (en) * 2002-03-27 2003-10-09 Isle Coat Limited Process and device for forming ceramic coatings on metals and alloys, and coatings produced by this process

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9284409B2 (en) 2007-07-19 2016-03-15 Boston Scientific Scimed, Inc. Endoprosthesis having a non-fouling surface
US8900292B2 (en) 2007-08-03 2014-12-02 Boston Scientific Scimed, Inc. Coating for medical device having increased surface area
US8920491B2 (en) 2008-04-22 2014-12-30 Boston Scientific Scimed, Inc. Medical devices having a coating of inorganic material
US8932346B2 (en) 2008-04-24 2015-01-13 Boston Scientific Scimed, Inc. Medical devices having inorganic particle layers
KR101701268B1 (en) 2015-04-09 2017-02-13 현대성우메탈 주식회사 Electrolyte solution for PEO on magnesium alloy and PEO method using the same

Also Published As

Publication number Publication date
CN1623013A (en) 2005-06-01
AU2002329410A8 (en) 2003-10-13
WO2003083181A2 (en) 2003-10-09
JP4722102B2 (en) 2011-07-13
CN100503899C (en) 2009-06-24
JP2005521794A (en) 2005-07-21
EP1488024B1 (en) 2017-05-03
NO20034936L (en) 2004-01-09
JP4182002B2 (en) 2008-11-19
HK1059804A1 (en) 2004-07-16
NO20034936D0 (en) 2003-11-06
EP1488024A2 (en) 2004-12-22
AU2002329410A1 (en) 2003-10-13
JP2008038256A (en) 2008-02-21

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