WO2001040850A1 - Liquid crystal elastomer films and method of production thereof - Google Patents
Liquid crystal elastomer films and method of production thereof Download PDFInfo
- Publication number
- WO2001040850A1 WO2001040850A1 PCT/GB2000/004381 GB0004381W WO0140850A1 WO 2001040850 A1 WO2001040850 A1 WO 2001040850A1 GB 0004381 W GB0004381 W GB 0004381W WO 0140850 A1 WO0140850 A1 WO 0140850A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- liquid crystal
- crystal elastomer
- elastomer film
- film
- film according
- Prior art date
Links
- 0 *c1ccc(*c(cc2)ccc2O)cc1F Chemical compound *c1ccc(*c(cc2)ccc2O)cc1F 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D7/00—Producing flat articles, e.g. films or sheets
- B29D7/01—Films or sheets
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/38—Polymers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N15/00—Thermoelectric devices without a junction of dissimilar materials; Thermomagnetic devices, e.g. using the Nernst-Ettingshausen effect
- H10N15/10—Thermoelectric devices using thermal change of the dielectric constant, e.g. working above and below the Curie point
- H10N15/15—Selection of materials
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N30/00—Piezoelectric or electrostrictive devices
- H10N30/80—Constructional details
- H10N30/85—Piezoelectric or electrostrictive active materials
- H10N30/857—Macromolecular compositions
Definitions
- This invention relates to methods for the fabrication of free standing liquid crystal elastomeric films and such films obtained therefrom. It also relates to free standing liquid crystal elastomeric films in general.
- this invention relates to the use of liquid crystal elastomer (LCE) films as transducers.
- LCE liquid crystal elastomer
- WO 97/25649 discloses the use of liquid crystal elastomer films.
- a method for the production of a free-standing liquid crystal elastomer film comprises the steps of:
- one of the plates is a silicon wafer and the other plate is sufficiently transparent to the incident radiation at an appropriate wavelength such that polymerisation will occur.
- the other plate is a quartz plate.
- the types of incident radiation include UV and thermal.
- the initiator includes thermal and photo initiators.
- the monomer is aligned after it is loaded between the plates. This may be done by using any of the conventional techniques. For example, poling may be used. If poling is used then one or both of the plates may have electrodes present eg an ellipsoidal electrode pattern. These electrodes have the additional advantage that they prevent voltage accumulation spikes that may occur with electrode patterns that have corners.
- the plates may be heated before the monomer is loaded, the temperature chosen is dependent upon in which particular phase it is desired to cure the film eg an isotropic or liquid crystal phase. It is preferred to heat to the isotropic phase and cool through the various liquid crystal phases (if present) to the desired liquid crystal phase - typically the Sc phase.
- the plates may be spaced by using a spacer such as a Mylar spacer.
- a spacer such as a Mylar spacer.
- Si may be highly polished resulting in a uniform surface which gives rise to a substantially defect free film.
- the silicon may be doped using conventional techniques allowing for poling of the material thus aiding alignment.
- a standard alignment layer used for liquid crystals can also be used on the silicon (doped or bulk) surface in order to further improve the alignment.
- Poling may be achieved by applying a DC and/or AC and/or thermal bias across the plates.
- the resulting film may be removed in any suitable way including peeling or so-called "float-off' wherein a fluid is used to separate the film from the wafer.
- a fluid is used to separate the film from the wafer.
- Acetone is an example of a suitable fluid.
- the cooling rate may be varied in the method - such a cooling rate lies in the range 0.01 °C - 10°C/minute.
- the cooling rate is of a value of about 0.1°C/minute.
- a cooling rate as described above may be applied in addition to applying a voltage.
- a triangular waveform is applied. Even more preferably the triangular waveform is in the region of 0.5Hz at 50V/micron.
- a high positive or negative bias may also be used.
- the mixture can be poured or placed onto the lower plate which has a spacer placed or fixed on it.
- the upper plate can then be placed on top to complete the cell.
- the plates can be clamped together if necessary.
- the plates can be fixed together, incorporating the spacer, and the material can be flowed into the cell.
- the lower plate is silicon.
- the mixture is cooled down from the isotropic phase into the desired final phase.
- the resulting elastomer material is an aligned chiral smectic C material.
- the resulting elastomer material is ferroelectric.
- a further aspect of this invention includes a free-standing liquid crystal elastomer film obtainable by the process of the current invention.
- a free-standing liquid crystal elastomeric film is provided.
- a free standing liquid crystal elastomer film is provided of area 10mm 2 -40, 000mm 2 .
- the area is 100mm 2 -20, 000mm 2 , even more preferably 500mm 2 - 20,000mm 2 .
- liquid crystal elastomer film suitable for use in transducer devices is provided.
- the area of the film is 10mm 2 -40, 000mm 2 , even more preferably 100mm 2 - 20,000mm 2 and even more preferably 500mm 2 -20,000mm 2 .
- Fig 1 illustrates a pyroelectric device
- a pyroelectric detector consists of electrode plates 1 ,2 at least one of which may be pixellated. In operation the detector is exposed to radiation R, for example infrared radiation, which is absorbed by the electrode 1. This results in a rise in temperature which is transmitted to a layer of pyroelectric material 3 (provided by the current invention) by conduction, The change in temperature results in a thermal expansion and a charge is generated. This change in charge is usually small when compared with the charge output due to the change in the spontaneous polarisation, Ps with a change in temperature; this constitutes the primary pyroelectric effect. A change in charge results in a change in potential difference between the electrodes. The charge on each pixel may be read out and the resulting signal is used to modulate scanning circuits in, for example, a video monitor and for a visual image of the infra red scans.
- R for example infrared radiation
- Example of pyroelectric devices include detectors, steering arrays and vidicon cameras.
- the films of the present invention may be used generally as transducers in piezo electric devices and in optical recording media.
- Any suitable monomer material may be used in order to form the polymer/elastomeric material of the present invention.
- Suitable materials are well known to those skilled in the art. They include and are hereby incorporated by reference, but are not limited to;
- n 0-12;
- R is a mesogenic group
- R is given by the general formula II;
- A, B, D are selected from the following rings:
- the above rings may be subst tuted with one or more of the following substituents in at least one of the available substitution positions: F, Cl, Br, CH 3 , CN, OR, R and NCS where R is given by C 1-5 branched or straight chain alkyl;
- Y O or single bond or COO or OCO
- Different monomer materials can be mixed together in the polymerisation process in any suitable ratio.
- the preferred ratio is one which gives the desired phase behaviour at the operating temperature of interest.
- the preferred ratio is in the region of 1 :1.
- cross-linkers examples include pentaerythritol tetra-acrylate and related cross-linkers and liquid crystal based cross-linkers including diacrylate based proprietary materials such as RM1 from Merck. Any suitable cross-linker may be used.
- the cross-linker is usually present in the range 1-10wt%; preferably 1-3wt%. Any suitable initiator may be used, and preferably is present in the range 1-10wt% preferably 1-5wt%.
- the ratio of initiator to cross-linker is in the region of 2:1 by weight.
- a mixture was formulated comprising monomer 145, monomer 138, a pentaerythritol tetra-acrylate cross-linker and a photo-initiator (eg Irgacure 184 available from CIBA GEIGY);
- the monomers are mixed in a 1 :1 weight ratio, the initiator to cross-linker ratio is 2:1 by weight, the overall weight % of initiator is 4wt% the overall weight % of cross-linker is 2wt%.
- a further monomer may be added (eg RM22) to aid in alignment - preferred is any monomer with the phase sequence of nematic/smectic A/smectic C.
- Clean eg acetone, IPA, water
- dry plates made of silicon and quartz are heated eg on hotplates - the temperature being determined by the temperature at which the isotropic phase is formed in the mixture to be used.
- the plates are heated until they are stable at the desired temperature eg in this case for about 30 minutes, and the mixture heated to a liquid - optionally can be mixed eg using a high speed vortex mixer.
- the mixture can be poured or placed onto the lower plate which has a spacer placed or fixed on it.
- the upper plate can then be placed on top to complete the cell.
- the plates can be clamped together if necessary.
- the plates can be fixed together, incorporating the spacer, and the material can be flowed into the cell.
- the plates may have electrodes on the surface (eg elliptical) these may be used to aid in poling - AC or DC.
- the use of elliptical electrodes helps prevent voltage accumulation spikes that can occur with patterns that have corners.
- the electrodes are patterned on the surface, for example on the surface of the doped silicon and for example on the surface of an Indium Tin Oxide (ITO) layer on the radiation transparent plate - eg a thin layer of transparent film on the quartz.
- ITO Indium Tin Oxide
- a cooling rate is applied, and/or
- a voltage is applied.
- the mixture is cured by exposing the quartz plate to UV radiation for about
- the plates are undipped and allowed to cool.
- the film may be removed either by the use of a knife-like tool eg a razor blade or the float-off method in a fluid, eg acetone or water, may be used.
- the shape of the film obtained is defined by the shape of the spacer.
- films of area 10mm 2 - 40,000mm 2 are obtained. It is particularly advantageous that larger high quality films may be obtained.
- the thickness of the film is also variable and preferably lies in the range 0.01 -0.5mm thick.
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020027006877A KR20020069198A (en) | 1999-11-29 | 2000-11-20 | Liquid crystal elastomer films and method of production thereof |
GB0210613A GB2372252B (en) | 1999-11-29 | 2000-11-20 | Liquid crystal elastomer films and method of production thereof |
JP2001542258A JP2003515478A (en) | 1999-11-29 | 2000-11-20 | Liquid crystal elastomer film and method for producing the same |
EP00976166A EP1244936A1 (en) | 1999-11-29 | 2000-11-20 | Liquid crystal elastomer films and method of production thereof |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9928062.0 | 1999-11-29 | ||
GB9928062A GB2356633A (en) | 1999-11-29 | 1999-11-29 | Free standing liquid crystal elastomer film fabrication |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2001040850A1 true WO2001040850A1 (en) | 2001-06-07 |
Family
ID=10865263
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB2000/004381 WO2001040850A1 (en) | 1999-11-29 | 2000-11-20 | Liquid crystal elastomer films and method of production thereof |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP1244936A1 (en) |
JP (1) | JP2003515478A (en) |
KR (1) | KR20020069198A (en) |
GB (2) | GB2356633A (en) |
WO (1) | WO2001040850A1 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7563388B2 (en) | 2004-08-27 | 2009-07-21 | The University Of Connecticut | Crosslinked liquid crystalline polymer, method for the preparation thereof, and articles derived therefrom |
US7601274B2 (en) | 2004-03-31 | 2009-10-13 | The University Of Connecticut | Shape memory main-chain smectic-C elastomers |
WO2014082662A1 (en) | 2012-11-27 | 2014-06-05 | Cnr - Consiglio Nazionale Delle Ricerche | Light driven liquid crystal elastomer actuator |
WO2016102015A1 (en) | 2014-12-23 | 2016-06-30 | Consiglio Nazionale Delle Ricerche - Cnr | Multiple alignment method in liquid crystalline medium |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997025649A1 (en) * | 1996-01-04 | 1997-07-17 | The Secretary Of State For Defence | Liquid crystal elastomers |
US5773179A (en) * | 1995-12-22 | 1998-06-30 | The Secretary Of State For Defence Defence Evaluation & Research Agency | Liquid crystal polymers |
-
1999
- 1999-11-29 GB GB9928062A patent/GB2356633A/en not_active Withdrawn
-
2000
- 2000-11-20 KR KR1020027006877A patent/KR20020069198A/en not_active Application Discontinuation
- 2000-11-20 JP JP2001542258A patent/JP2003515478A/en active Pending
- 2000-11-20 GB GB0210613A patent/GB2372252B/en not_active Expired - Fee Related
- 2000-11-20 WO PCT/GB2000/004381 patent/WO2001040850A1/en active Application Filing
- 2000-11-20 EP EP00976166A patent/EP1244936A1/en not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5773179A (en) * | 1995-12-22 | 1998-06-30 | The Secretary Of State For Defence Defence Evaluation & Research Agency | Liquid crystal polymers |
WO1997025649A1 (en) * | 1996-01-04 | 1997-07-17 | The Secretary Of State For Defence | Liquid crystal elastomers |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7601274B2 (en) | 2004-03-31 | 2009-10-13 | The University Of Connecticut | Shape memory main-chain smectic-C elastomers |
US7799243B2 (en) | 2004-03-31 | 2010-09-21 | University Of Connecticut | Shape memory main-chain smectic-C elastomers |
US7563388B2 (en) | 2004-08-27 | 2009-07-21 | The University Of Connecticut | Crosslinked liquid crystalline polymer, method for the preparation thereof, and articles derived therefrom |
WO2014082662A1 (en) | 2012-11-27 | 2014-06-05 | Cnr - Consiglio Nazionale Delle Ricerche | Light driven liquid crystal elastomer actuator |
WO2016102015A1 (en) | 2014-12-23 | 2016-06-30 | Consiglio Nazionale Delle Ricerche - Cnr | Multiple alignment method in liquid crystalline medium |
US10613392B2 (en) | 2014-12-23 | 2020-04-07 | Consiglio Nazionale Delle Ricerche—Cnr | Multiple alignment method in liquid crystalline medium |
Also Published As
Publication number | Publication date |
---|---|
GB0210613D0 (en) | 2002-06-19 |
GB2372252A (en) | 2002-08-21 |
EP1244936A1 (en) | 2002-10-02 |
JP2003515478A (en) | 2003-05-07 |
KR20020069198A (en) | 2002-08-29 |
GB2372252B (en) | 2003-09-03 |
GB9928062D0 (en) | 2000-01-26 |
GB2356633A (en) | 2001-05-30 |
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