US4256841A - Manufacture of light-stable polyurethane integral foams - Google Patents
Manufacture of light-stable polyurethane integral foams Download PDFInfo
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- US4256841A US4256841A US06/038,853 US3885379A US4256841A US 4256841 A US4256841 A US 4256841A US 3885379 A US3885379 A US 3885379A US 4256841 A US4256841 A US 4256841A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/161—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
- C08G18/163—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/7806—Nitrogen containing -N-C=0 groups
- C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
- C08G18/7831—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing biuret groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
- C08G18/8006—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32
- C08G18/8009—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203
- C08G18/8012—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203 with diols
- C08G18/8016—Masked aliphatic or cycloaliphatic polyisocyanates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0033—Foam properties having integral skins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2410/00—Soles
Definitions
- the present invention relates to a process for the manufacture of light-stable polyurethane integral skin foams, especially soft integral foams, by reacting an aliphatic and/or cycloaliphatic polyisocyanate, either of which may or may not contain urethane and/or biuret groups, with a polyol in the presence of a blowing agent and of a synergistic catalyst combination comprising an alkali metal hydroxide, alkali metal alcoholate, alkali metal phenolate, alkali metal salt of a weak acid and/or hexahydrotriazine derivative and an organic tin, zinc and/or iron(II) compound, in the presence or absence of assistants and adjuvants.
- a synergistic catalyst combination comprising an alkali metal hydroxide, alkali metal alcoholate, alkali metal phenolate, alkali metal salt of a weak acid and/or hexahydrotriazine derivative and an organic tin, zinc and/or iron
- Polyurethane foams have long been known. A review of the manufacture and properties of polyurethane foams is given, for example, in Kunststoff-Handbuch, volume VII, "Polyurethane” by R. Vieweg and A. Hochtlen, Verlag Carl Hanser, Kunststoff 1966, or in the monograph by J. H. Saunders and K. C. Frisch “High Polymers”, volume XVI, Polyurethanes, parts 1 and 2, Interscience Publishers 1962 and 1964.
- Polyurethane foams manufactured from aromatic polyisocyanates and polyols are usually not light-stable, ie. they yellow when exposed to light.
- the reason for the yellowing is the formation of quinonoid structures from aromatic polymer units. It has therefore been proposed to reduce the light-sensitivity of the polyurethane foams by adding stabilizers, as a rule compounds which have a reducing action. It is true that such stabilizers can delay the yellowing, but they cannot suppress it completely. Since, for many applications, a yellowing or color change of the polyurethane foams is undesirable soft integral skin foams employed, for example, as cushioning, seats, headrests, dashboards and fenders in the automotive industry, must be either laminated with polymer films, or be surface-coated. The same remarks apply to thermoset resin foams, which are used for sports goods, window frames and as a wood substitute.
- polyurethane foams or integral foams are manufactured using polyisocyanates whereof the NCO groups are not directly bonded to an aromatic radical, and catalyst combinations based on amines having a ##STR1## structure and alkaline earth metal salts of carboxylic acids having a dissociation constant K a ⁇ 10 -1 , alcoholates and phenolates and organic lead compounds, and compounds having primary or secondary amino groups.
- this object is achieved by a process for the manufacture of light-stable polyurethane integral skin foams by reacting a mixture of organic polyisocyanates, polyols, catalysts and blowing agents, with or without assistants and adjuvants, wherein the organic polyisocyanates used are aliphatic and/or cycloaliphatic polyisocyanates, of which both categories may or may not contain urethane and/or biuret groups, and the catalysts used are synergistic catalyst combinations consisting of
- Organic polyisocyanates which may be used according to the invention have the formula R(NCO) n , where R is a polyvalent aliphatic or cycloaliphatic radical or a mixed radical of this type, which radicals may or may not contain urethane and/or biuret groups, and n is an integer which corresponds to the valency of R and is at least 2, preferably 2 or 3. Specific examples are aliphatic diisocyanates, eg.
- ethylene diisocyanate 1,2-propylene diisocyanate, 1,4-butylene diisocyanate, 2,2,4-trimethyl-1,6-hexamethylene diisocyanate and preferably 1,6-hexamethylene diisocyanate
- cycloaliphatic diisocyanates such as 1,2-cyclohexane diisocyanate, 1,3-cyclohexane diisocyanate, 1,4-cyclohexane diisocyanate, 1-methyl-2,4-cyclohexane diisocyanate, 1-methyl-2,6-cyclohexane diisocyanate and the corresponding 1-methylcyclohexane diisocyanate isomer mixtures, 4,4'-, 2,4'- and 2,2'-dicyclohexylmethane diisocyanate and the corresponding isomer mixtures and, preferably, 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate and polyisocyanates
- polyisocyanates containing urethane groups or, in particular, containing biuret groups, and mixtures of such compounds, prepared from aliphatic or cycloaliphatic polyisocyanates are used.
- Polyisocyanates containing urethane groups may for example be obtained by reacting the above aliphatic or cycloaliphatic diisocyanates, preferably hexamethylene diisocyanate and isophorone diisocyanate, with alkanediols, which may or may not be substituted or modified, of 2 to 10, preferably 2 to 6, carbon atoms in the alkylene radical, eg.
- the polyisocyanates containing biuret groups have NCO contents of from 30 to 15, preferably from 25 to 20, % by weight and viscosities, at 20° C., of from 6,000 to 500, preferably from 1,000 to 4,000, m.Pas.
- Suitable polyols are preferably polyester-ols and especially polyether-ols.
- hydroxyl-containing polymers having molecular weights of from 500 to 8,000 and hydroxyl numbers of from 20 to 500, for example polycarbonates, especially those prepared by trans-esterifying diphenyl carbonate with hexane-1,6-diol, polyacetals, eg. polyoxymethylene, and polyester-amides.
- Suitable polyester-ols may for example be prepared from dicarboxylic acids, preferably from aliphatic dicarboxylic acids of 2 to 12 carbon atoms in the alkylene radical, and polyhydric alcohols, preferably diols.
- suitable acids are aliphatic dicarboxylic acids, eg. glutaric acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, undecanedicarboxylic acid, dodecanedicarboxylic acid and, preferably, succinic acid and adipic acid, and aromatic dicarboxylic acids, such as phthalic acid and terephthalic acid.
- dihydric and polyhydric, especially dihydric, alcohols are ethylene glycol, diethylene glycol, 1,2- and 1,3-propylene glycol, dipropylene glycol, decane-1,10-diol, glycerol, trimethylolpropane, pentaerythritol and, preferably, butane-1,4-diol, hexane-1,6-diol and neopentylglycol.
- the polyester-ols have molecular weights of from 500 to 8,000, preferably from 1,000 to 4,000, and hydroxyl numbers of from 20 to 500, preferably from 50 to 200.
- the polyester-ols may be employed singly or in the form of mixtures.
- polystyrene-ols having molecular weights of from 500 to 8,000, preferably from 1,000 to 4,000, and hydroxyl numbers of from 20 to 500, preferably from 50 to 200.
- the polyether-ols are prepared by conventional processes from one or more alkylene oxides of 2 to 4 carbon atoms in the alkylene radical and a starter molecule which contains from 2 to 8, preferably 2 or 3, active hydrogen atoms.
- suitable alkylene oxides are tetrahydrofuran, 1,3-propylene oxide, 1,2- and 1,3-butylene oxide, styrene oxide and, preferably, ethylene oxide and 1,2-propylene oxide.
- the alkylene oxides may be used singly, in alternation or as mixtures.
- starter molecules are water, dicarboxylic acids, eg. succinic acid, adipic acid, phthalic acid and terephthalic acid, N,N'-dialkyl-substituted diamines, where alkyl is of 1 to 4 carbon atoms, for example N,N'-dimethyl-ethylenediamine, N,N'-dimethyl-1,2- and -1,3-propylenediamine, N,N'-diethyl-1,4-butylenediamine and N,N'-dimethyl-1,6-hexamethylenediamine, as well as N-alkyl-dialkanolamines, where alkyl is of 1 to 4 carbon atoms, eg.
- dicarboxylic acids eg. succinic acid, adipic acid, phthalic acid and terephthalic acid
- N,N'-dialkyl-substituted diamines where alkyl is of 1 to 4 carbon atoms, for example
- alcohols eg. ethylene glycol, 1,2- and 1,3-propylene glycol, diethylene glycol, dipropylene glycol, 1,4-butylene glycol, 1,6-hexamethylene glycol, glycerol, trimethylolpropane, pentaerythritol, sorbitol and saccharose.
- the polyether-ols may be used singly or in the form of mixtures.
- polyester-ols or polyether-ols instead of the polyester-ols or polyether-ols, mixtures of polyester-ols and polyether-ols may also be employed, in which mixtures the weight ratio of polyester-ol to polyether-ol may be varied within wide limits, for example from 20:80 to 80:20, depending on the end use of the polyurethane integral foam to be manufactured.
- Suitable agents of this type are polyfunctional, especially difunctional and trifunctional, compounds with molecular weights of from 18 to 600, preferably from 60 to 300.
- dialkanolamines and trialkanolamines eg. diethanolamine and triethanolamine
- aliphatic diols and triols of 2 to 6 carbon atoms eg. ethylene glycol, 1,4-butylene glycol, 1,6-hexamethylene glycol, glycerol and trimethylolpropane
- An essential feature of the process according to the invention is the use of a synergistic catalyst combination consisting of
- the above catalyst combinations essentially comprise a strongly basic polyisocyanurate catalyst and an organo-metallic polyurethane catalyst.
- Suitable strongly basic polyisocyanurate catalysts include alkali metal hydroxides, especially sodium hydroxide and potassium hydroxide, alkali metal alcoholates, preferably sodium alcoholates and especially potassium alcoholates of alcohols of preferably 1 to 6 carbon atoms, eg.
- phenolates eg. sodium phenolate and potassium phenolate
- salts of weak organic and inorganic acids eg. sodium formate, potassium formate, sodium acetate, potassium acetate, sodium octoate, potassium octoate, sodium carbonate and potassium carbonate, and, preferably, hexahydrotriazine derivatives.
- Particularly suitable hexahydrotriazine derivatives are 1,3,5-tris-(N,N-dialkylaminoalkyl)-s-hexahydrotriazines, for example 1,3,5-tris-(N,N-dimethyl-2-aminoethyl)-s-hexahydrotriazine, 1,3,5-tris-(N,N-dimethyl-3-aminopropyl)-s-hexahydrotriazine, 1,3,5-tris-(N,N-diethyl-2-aminoethyl)-s-hexahydrotriazine, 1,3,5-(N,N-diethyl-3-aminopropyl)-s-hexahydrotriazine and 1,3,5-tris-(N,N-dipropyl-2-aminoethyl)-s-hexahydrotriazine.
- alkali metal hydroxide, alkali metal alcoholate, alkali metal phenolate, alkali metal salt of a weak acid and hexahydrotriazine derivative to be employed are from 0.01 to 5, preferably from 0.1 to 3, parts by weight per 100 parts by weight of polyol.
- the other component of the catalyst combination is a zinc compound, iron(II) compound or, preferably, tin compound.
- tin compound Specific examples are iron acetylacetonate, zinc 2-ethyl-hexoate, zinc naphthenate, dibutyl-tin versatate and dibutyl-tin diacetate and preferably tin dioctoate and especially dibutyl-tin dilaurate.
- the amount of organic zinc compound, iron(II) compound or tin compound employed is from 0.01 to 5 parts by weight, preferably from 0.1 to 3 parts by weight, per 100 parts by weight of polyol.
- a catalyst combination of tris-(N,N-dimethylaminopropyl)-s-hexahydrotriazine and dibutyl-tin dilaurate has proved particularly suitable and is therefore used preferentially.
- a suitable blowing agent is water, which reacts with the polyisocyanates and provides carbon dioxide.
- water Preferably, from 0.1 to 2% by weight, especially from 0.01 to 1% by weight, of water, based on the weight of polyol, is used.
- other, physically acting, blowing agents, or mixtures of water and physically acting blowing agents can be used.
- Physically acting blowing agents are usually chemically inert, low-boiling hydrocarbons or halohydrocarbons.
- hydrocarbons or halohydrocarbons with boiling points, at atmospheric pressure, of below 50° C., preferably of from -50° C. to 30° C. are employed. Specific examples are halohydrocarbons, eg.
- the amount of physically acting blowing agent which is required can readily be determined; it is a function of the desired foam density and is from about 2.5 to 20% by weight, preferably from 5 to 15% by weight, based on the weight of polyol.
- Suitable mixtures of water and hydrocarbons or halohydrocarbons in general comprise from 0.01 to 2% by weight, preferably from 0.1 to 1% by weight, of water and from 2.5 to 20% by weight, preferably from 5 to 10% by weight, of hydrocarbon or halohydrocarbon, the percentages being based on the weight of polyol.
- trichlorofluoromethane and methylene chloride, or a mixture of these blowing agents are used to manufacture the integral skin foams.
- the content of water, where any is added is usually less than 1 part by weight, preferably from 0.01 to 0.5 part by weight, per 100 parts by weight of polyol.
- assistants and adjuvants such as are conventionally used for the manufacture of polyurethane foams, may be incorporated into the foamable reaction mixtures.
- examples include surfactants, flameproofing agents, pore regulators, antioxidants, anti-hydrolysis agents, colorants, fillers and other additives.
- Suitable surfactants are, for example, compounds which serve to assist the homogenization of the starting materials and may also be able to regulate the cell structure of the polyurethane foams.
- Specific examples are siloxane-oxyalkylene copolymers and other organopolysiloxanes, oxyethylated alkylphenols, oxyethylated fatty alcohols, paraffin oils, castor oil, ricinoleic acid esters and turkey red oil; these are used in amounts of from 0.2 to 6 parts by weight per 100 parts by weight of polyisocyanate.
- Flameproofing agents may be incorporated into the light-stable polyurethane foams manufactured according to the invention, in order to improve their flame-retardant characteristics.
- Examples are compounds containing phosphorus and/or halogen which can additionally reduce the brittleness of the foams and act as plasticizers, eg. tricresyl phosphate, tris-2-chloroethyl phosphate, tris-chloropropyl phosphate and tris-2,3-dibromopropyl phosphate, and inorganic flameproofing agents, eg. antimony trioxide, arsenic oxide, ammonium phosphate and the like. In general, it has proved advantageous to use from 1 to 10 parts by weight of the said flameproofing agents per 100 parts by weight of polyisocyanate.
- the polyurethane integral skin foams are manufactured by conventional methods known for aromatic polyisocyanates, for example by the prepolymer process and preferably by the one-shot process.
- the conventional procedure is to react a mixture of polyol, catalyst and blowing agent, with or without chain extender, crosslinking agent, assistants and adjuvants, with the aliphatic and/or cycloaliphatic polyisocyanate at from 15° to 60° C., preferably from 20° to 50° C., the amounts used being such that the ratio of hydroxyl groups of the polyol, together with any NCO-active hydrogen atoms of the chain extender and/or crosslinking agent, to NCO groups of the polyisocyanate is from 0.8:1 to 1.2:1, preferably about 1:1.
- the liquid starting materials may be introduced individually or, where the components are solid, in the form of a solution or suspension, and be mixed thoroughly in the mixing chamber.
- a mixing chamber with several feed nozzles
- the liquid starting materials may be introduced individually or, where the components are solid, in the form of a solution or suspension, and be mixed thoroughly in the mixing chamber.
- the polyurethane integral skin foams manufactured according to the invention have densities of from about 60 to 600 g/l and are particularly distinguished by their light stability.
- the flexible products are particularly suitable for the manufacture of automotive components, eg. headrests, armrests, crash pads and fenders, shoe soles and sports mats.
- the rigid products are used in sports goods and window frames and as a wood substitute.
Abstract
To prepare light-stable polyurethane integral skin foams, especially soft integral foams, aliphatic and/or cycloaliphatic polyisocyanates, both categories preferably containing urethane groups and/or biuret groups, are reacted with polyols in the presence of blowing agents and of a synergistic catalyst combination comprising an alkali metal hydroxide, alkali metal alcoholate, alkali metal phenolate, alkali metal salt of a weak acid and/or hexahydrotriazine derivative and an organic tin, zinc and/or iron(II) compound, in the presence or absence of assistants and adjuvants.
The preferred catalyst combination is tri-(dimethylaminopropyl)-s-hexahydrotriazine and dibutyl-tin dilaurate.
Description
The present invention relates to a process for the manufacture of light-stable polyurethane integral skin foams, especially soft integral foams, by reacting an aliphatic and/or cycloaliphatic polyisocyanate, either of which may or may not contain urethane and/or biuret groups, with a polyol in the presence of a blowing agent and of a synergistic catalyst combination comprising an alkali metal hydroxide, alkali metal alcoholate, alkali metal phenolate, alkali metal salt of a weak acid and/or hexahydrotriazine derivative and an organic tin, zinc and/or iron(II) compound, in the presence or absence of assistants and adjuvants.
Polyurethane foams have long been known. A review of the manufacture and properties of polyurethane foams is given, for example, in Kunststoff-Handbuch, volume VII, "Polyurethane" by R. Vieweg and A. Hochtlen, Verlag Carl Hanser, Munich 1966, or in the monograph by J. H. Saunders and K. C. Frisch "High Polymers", volume XVI, Polyurethanes, parts 1 and 2, Interscience Publishers 1962 and 1964.
Polyurethane foams manufactured from aromatic polyisocyanates and polyols are usually not light-stable, ie. they yellow when exposed to light. The reason for the yellowing is the formation of quinonoid structures from aromatic polymer units. It has therefore been proposed to reduce the light-sensitivity of the polyurethane foams by adding stabilizers, as a rule compounds which have a reducing action. It is true that such stabilizers can delay the yellowing, but they cannot suppress it completely. Since, for many applications, a yellowing or color change of the polyurethane foams is undesirable soft integral skin foams employed, for example, as cushioning, seats, headrests, dashboards and fenders in the automotive industry, must be either laminated with polymer films, or be surface-coated. The same remarks apply to thermoset resin foams, which are used for sports goods, window frames and as a wood substitute.
In the case of polyurethane elastomers and coatings the difficulties are circumvented by using aliphatic and/or cycloaliphatic polyisocyanates, in place of aromatic polyisocyanates, for the manufacture of the polyurethane. However, these methods have hitherto been unsuccessful in the manufacture of polyurethane foams, since the reactivity of aliphatic polyisocyanates is substantially less than that of the aromatic polyisocyanates.
According to the disclosures of German Laid-Open Application DOS No. 2,710,901 and U.S. Pat. No. 4,025,466, polyurethane foams or integral foams are manufactured using polyisocyanates whereof the NCO groups are not directly bonded to an aromatic radical, and catalyst combinations based on amines having a ##STR1## structure and alkaline earth metal salts of carboxylic acids having a dissociation constant Ka <10-1, alcoholates and phenolates and organic lead compounds, and compounds having primary or secondary amino groups.
A disadvantage of the processes described is that the polyurethane foams thus obtained have a low heat distortion point and in some cases have inadequate mechanical properties.
It is an object of the present invention to manufacture light-fast polyurethane integral skin foams, especially soft integral foams, in such a way that the reaction conditions, and the mechanical properties of the polyurethane integral foams obtained, correspond to those when using aromatic polyisocyanates.
We have found that this object is achieved by a process for the manufacture of light-stable polyurethane integral skin foams by reacting a mixture of organic polyisocyanates, polyols, catalysts and blowing agents, with or without assistants and adjuvants, wherein the organic polyisocyanates used are aliphatic and/or cycloaliphatic polyisocyanates, of which both categories may or may not contain urethane and/or biuret groups, and the catalysts used are synergistic catalyst combinations consisting of
(A) one or more compounds from the group comprising the alkali metal hydroxides, alkali metal alcoholates, alkali metal phenolates, alkali metal salts of weak acids and/or hexahydrotriazine derivatives and
(B) one or more compounds from the group comprising organic tin, zinc and/or iron(II) compounds.
Surprisingly, we have found that by the specific selection, according to the invention, of a strongly basic polyisocyanurate catalyst and an organo-metallic polyurethane catalyst from the plurality of conventional and commercially available polyisocyanurate and polyurethane catalysts, a synergistic catalyst combination is obtained, which can adequately catalyze the reaction of polyols with aliphatic or cycloaliphatic polyisocyanates. It is particularly advantageous that the preferentially used polyisocyanates containing urethane groups and/or biuret groups are non-toxic and that the ratio in which the polyol and polyisocyanate compounds are mixed can be varied within wide limits without causing collapse of the polyurethane integral skin foams obtained.
The following may, for example, be used as starting components for the manufacture, according to the invention, of the light-stable rigid and soft polyurethane integral skin foams:
Organic polyisocyanates which may be used according to the invention have the formula R(NCO)n, where R is a polyvalent aliphatic or cycloaliphatic radical or a mixed radical of this type, which radicals may or may not contain urethane and/or biuret groups, and n is an integer which corresponds to the valency of R and is at least 2, preferably 2 or 3. Specific examples are aliphatic diisocyanates, eg. ethylene diisocyanate, 1,2-propylene diisocyanate, 1,4-butylene diisocyanate, 2,2,4-trimethyl-1,6-hexamethylene diisocyanate and preferably 1,6-hexamethylene diisocyanate, cycloaliphatic diisocyanates, such as 1,2-cyclohexane diisocyanate, 1,3-cyclohexane diisocyanate, 1,4-cyclohexane diisocyanate, 1-methyl-2,4-cyclohexane diisocyanate, 1-methyl-2,6-cyclohexane diisocyanate and the corresponding 1-methylcyclohexane diisocyanate isomer mixtures, 4,4'-, 2,4'- and 2,2'-dicyclohexylmethane diisocyanate and the corresponding isomer mixtures and, preferably, 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate and polyisocyanates, such as polycyclohexyl-polymethylene polyisocyanates with from 2 to 6, preferably with 3, cyclohexylene radicals in the molecule.
Preferably, however, polyisocyanates containing urethane groups or, in particular, containing biuret groups, and mixtures of such compounds, prepared from aliphatic or cycloaliphatic polyisocyanates, are used. Polyisocyanates containing urethane groups may for example be obtained by reacting the above aliphatic or cycloaliphatic diisocyanates, preferably hexamethylene diisocyanate and isophorone diisocyanate, with alkanediols, which may or may not be substituted or modified, of 2 to 10, preferably 2 to 6, carbon atoms in the alkylene radical, eg. ethylene glycol, butane-1,4-diol, dipropylene glycol, hexane-1,6-diol and neopentylglycol, as well as neopentylglycol mono-hydroxypivalate or mixtures of these, in the molar ratio of about 2:1. The preparation of polyisocyanates containing biuret groups is described, for example, in U.S. Pat. Nos. 3,124,605 and 3,903,126, which are incorporated by reference. The polyisocyanates containing biuret groups have NCO contents of from 30 to 15, preferably from 25 to 20, % by weight and viscosities, at 20° C., of from 6,000 to 500, preferably from 1,000 to 4,000, m.Pas.
Suitable polyols are preferably polyester-ols and especially polyether-ols. However, it is also possible to use other hydroxyl-containing polymers having molecular weights of from 500 to 8,000 and hydroxyl numbers of from 20 to 500, for example polycarbonates, especially those prepared by trans-esterifying diphenyl carbonate with hexane-1,6-diol, polyacetals, eg. polyoxymethylene, and polyester-amides.
Suitable polyester-ols may for example be prepared from dicarboxylic acids, preferably from aliphatic dicarboxylic acids of 2 to 12 carbon atoms in the alkylene radical, and polyhydric alcohols, preferably diols. Examples of suitable acids are aliphatic dicarboxylic acids, eg. glutaric acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, undecanedicarboxylic acid, dodecanedicarboxylic acid and, preferably, succinic acid and adipic acid, and aromatic dicarboxylic acids, such as phthalic acid and terephthalic acid. Examples of dihydric and polyhydric, especially dihydric, alcohols are ethylene glycol, diethylene glycol, 1,2- and 1,3-propylene glycol, dipropylene glycol, decane-1,10-diol, glycerol, trimethylolpropane, pentaerythritol and, preferably, butane-1,4-diol, hexane-1,6-diol and neopentylglycol. The polyester-ols have molecular weights of from 500 to 8,000, preferably from 1,000 to 4,000, and hydroxyl numbers of from 20 to 500, preferably from 50 to 200. The polyester-ols may be employed singly or in the form of mixtures.
However, particularly suitable polyols are polyether-ols having molecular weights of from 500 to 8,000, preferably from 1,000 to 4,000, and hydroxyl numbers of from 20 to 500, preferably from 50 to 200. The polyether-ols are prepared by conventional processes from one or more alkylene oxides of 2 to 4 carbon atoms in the alkylene radical and a starter molecule which contains from 2 to 8, preferably 2 or 3, active hydrogen atoms. Examples of suitable alkylene oxides are tetrahydrofuran, 1,3-propylene oxide, 1,2- and 1,3-butylene oxide, styrene oxide and, preferably, ethylene oxide and 1,2-propylene oxide. The alkylene oxides may be used singly, in alternation or as mixtures. Examples of suitable starter molecules are water, dicarboxylic acids, eg. succinic acid, adipic acid, phthalic acid and terephthalic acid, N,N'-dialkyl-substituted diamines, where alkyl is of 1 to 4 carbon atoms, for example N,N'-dimethyl-ethylenediamine, N,N'-dimethyl-1,2- and -1,3-propylenediamine, N,N'-diethyl-1,4-butylenediamine and N,N'-dimethyl-1,6-hexamethylenediamine, as well as N-alkyl-dialkanolamines, where alkyl is of 1 to 4 carbon atoms, eg. N-methyldiethanolamine, N-ethyl-diethanolamine and N-butyl-diethanolamine, and preferably dihydric to octahydric, especially dihydric or trihydric, alcohols, eg. ethylene glycol, 1,2- and 1,3-propylene glycol, diethylene glycol, dipropylene glycol, 1,4-butylene glycol, 1,6-hexamethylene glycol, glycerol, trimethylolpropane, pentaerythritol, sorbitol and saccharose.
The polyether-ols may be used singly or in the form of mixtures.
Instead of the polyester-ols or polyether-ols, mixtures of polyester-ols and polyether-ols may also be employed, in which mixtures the weight ratio of polyester-ol to polyether-ol may be varied within wide limits, for example from 20:80 to 80:20, depending on the end use of the polyurethane integral foam to be manufactured.
It may at times be advantageous to employ chain extenders or crosslinking agents, in addition to the above polyols, when manufacturing the polyurethane integral skin foams. Suitable agents of this type are polyfunctional, especially difunctional and trifunctional, compounds with molecular weights of from 18 to 600, preferably from 60 to 300. For example, dialkanolamines and trialkanolamines, eg. diethanolamine and triethanolamine, and, preferably, aliphatic diols and triols of 2 to 6 carbon atoms, eg. ethylene glycol, 1,4-butylene glycol, 1,6-hexamethylene glycol, glycerol and trimethylolpropane, may be used.
An essential feature of the process according to the invention is the use of a synergistic catalyst combination consisting of
(A) one or more compounds from the group comprising the alkali metal hydroxides, alkali metal alcoholates, alkali metal phenolates, alkali metal salts of weak acids and hexahydrotriazine derivatives and
(B) one or more compounds from the group comprising the organic zinc compounds, iron(II) compounds and, preferably, tin compounds
for accelerating the reaction between the aliphatic and/or cycloaliphatic polyisocyanates and polyols, in the presence or absence of water and chain extenders and/or cross-linking agents. The above catalyst combinations essentially comprise a strongly basic polyisocyanurate catalyst and an organo-metallic polyurethane catalyst. Suitable strongly basic polyisocyanurate catalysts include alkali metal hydroxides, especially sodium hydroxide and potassium hydroxide, alkali metal alcoholates, preferably sodium alcoholates and especially potassium alcoholates of alcohols of preferably 1 to 6 carbon atoms, eg. methanol, ethanol, propanol, isopropanol, n-butanol, iso-butanol and hexanol, phenolates, eg. sodium phenolate and potassium phenolate, salts of weak organic and inorganic acids, eg. sodium formate, potassium formate, sodium acetate, potassium acetate, sodium octoate, potassium octoate, sodium carbonate and potassium carbonate, and, preferably, hexahydrotriazine derivatives.
Particularly suitable hexahydrotriazine derivatives are 1,3,5-tris-(N,N-dialkylaminoalkyl)-s-hexahydrotriazines, for example 1,3,5-tris-(N,N-dimethyl-2-aminoethyl)-s-hexahydrotriazine, 1,3,5-tris-(N,N-dimethyl-3-aminopropyl)-s-hexahydrotriazine, 1,3,5-tris-(N,N-diethyl-2-aminoethyl)-s-hexahydrotriazine, 1,3,5-(N,N-diethyl-3-aminopropyl)-s-hexahydrotriazine and 1,3,5-tris-(N,N-dipropyl-2-aminoethyl)-s-hexahydrotriazine. For the purposes of the present invention, the use of 1,3,5-tris-(N,N-dimethyl-3-aminopropyl)-s-hexahydrotriazine is preferred.
These hexahydrotriazine components and their preparation are known and are described, for example, by Nicholas et al., Journal of Cellular Plastics 1 (1) (1965), 85 and by Graymore, Journal of the Chemical Society (1931), 1493.
The amounts of alkali metal hydroxide, alkali metal alcoholate, alkali metal phenolate, alkali metal salt of a weak acid and hexahydrotriazine derivative to be employed are from 0.01 to 5, preferably from 0.1 to 3, parts by weight per 100 parts by weight of polyol.
The other component of the catalyst combination is a zinc compound, iron(II) compound or, preferably, tin compound. Specific examples are iron acetylacetonate, zinc 2-ethyl-hexoate, zinc naphthenate, dibutyl-tin versatate and dibutyl-tin diacetate and preferably tin dioctoate and especially dibutyl-tin dilaurate. The amount of organic zinc compound, iron(II) compound or tin compound employed is from 0.01 to 5 parts by weight, preferably from 0.1 to 3 parts by weight, per 100 parts by weight of polyol.
A catalyst combination of tris-(N,N-dimethylaminopropyl)-s-hexahydrotriazine and dibutyl-tin dilaurate has proved particularly suitable and is therefore used preferentially.
A suitable blowing agent is water, which reacts with the polyisocyanates and provides carbon dioxide. Preferably, from 0.1 to 2% by weight, especially from 0.01 to 1% by weight, of water, based on the weight of polyol, is used. Instead of water, other, physically acting, blowing agents, or mixtures of water and physically acting blowing agents can be used. Physically acting blowing agents are usually chemically inert, low-boiling hydrocarbons or halohydrocarbons. For example, hydrocarbons or halohydrocarbons with boiling points, at atmospheric pressure, of below 50° C., preferably of from -50° C. to 30° C., are employed. Specific examples are halohydrocarbons, eg. monochlorodifluoromethane, dichloromonofluoromethane, dichlorodifluoromethane, trifluoromethane and mixtures of these, hydrocarbons, eg. propane and isobutane, and dimethyl ether. The amount of physically acting blowing agent which is required can readily be determined; it is a function of the desired foam density and is from about 2.5 to 20% by weight, preferably from 5 to 15% by weight, based on the weight of polyol. Suitable mixtures of water and hydrocarbons or halohydrocarbons in general comprise from 0.01 to 2% by weight, preferably from 0.1 to 1% by weight, of water and from 2.5 to 20% by weight, preferably from 5 to 10% by weight, of hydrocarbon or halohydrocarbon, the percentages being based on the weight of polyol.
Preferably, trichlorofluoromethane and methylene chloride, or a mixture of these blowing agents, in an amount of from 2.5 to 20 parts by weight per 100 parts by weight of polyol, are used to manufacture the integral skin foams. The content of water, where any is added, is usually less than 1 part by weight, preferably from 0.01 to 0.5 part by weight, per 100 parts by weight of polyol.
In addition, assistants and adjuvants, such as are conventionally used for the manufacture of polyurethane foams, may be incorporated into the foamable reaction mixtures. Examples include surfactants, flameproofing agents, pore regulators, antioxidants, anti-hydrolysis agents, colorants, fillers and other additives.
Suitable surfactants are, for example, compounds which serve to assist the homogenization of the starting materials and may also be able to regulate the cell structure of the polyurethane foams. Specific examples are siloxane-oxyalkylene copolymers and other organopolysiloxanes, oxyethylated alkylphenols, oxyethylated fatty alcohols, paraffin oils, castor oil, ricinoleic acid esters and turkey red oil; these are used in amounts of from 0.2 to 6 parts by weight per 100 parts by weight of polyisocyanate.
Flameproofing agents may be incorporated into the light-stable polyurethane foams manufactured according to the invention, in order to improve their flame-retardant characteristics. Examples are compounds containing phosphorus and/or halogen which can additionally reduce the brittleness of the foams and act as plasticizers, eg. tricresyl phosphate, tris-2-chloroethyl phosphate, tris-chloropropyl phosphate and tris-2,3-dibromopropyl phosphate, and inorganic flameproofing agents, eg. antimony trioxide, arsenic oxide, ammonium phosphate and the like. In general, it has proved advantageous to use from 1 to 10 parts by weight of the said flameproofing agents per 100 parts by weight of polyisocyanate.
Further data relating to the above additional conventional assistants and adjuvants are to be found in the relevant literature, for example the monograph by J. H. Saunders and K. C. Frisch "High Polymers", volume XVI, Polyurethanes, parts 1 and 2, Interscience Publishers 1962 and 1964.
The polyurethane integral skin foams are manufactured by conventional methods known for aromatic polyisocyanates, for example by the prepolymer process and preferably by the one-shot process.
If the polyurethane integral skin foams are manufactured by the one-shot process, the conventional procedure is to react a mixture of polyol, catalyst and blowing agent, with or without chain extender, crosslinking agent, assistants and adjuvants, with the aliphatic and/or cycloaliphatic polyisocyanate at from 15° to 60° C., preferably from 20° to 50° C., the amounts used being such that the ratio of hydroxyl groups of the polyol, together with any NCO-active hydrogen atoms of the chain extender and/or crosslinking agent, to NCO groups of the polyisocyanate is from 0.8:1 to 1.2:1, preferably about 1:1. If a mixing chamber with several feed nozzles is used, the liquid starting materials may be introduced individually or, where the components are solid, in the form of a solution or suspension, and be mixed thoroughly in the mixing chamber. However, it has proved particularly advantageous to employ the two-component process and use a mixture of polyol, catalyst and blowing agent, with or without chain extender and/or crosslinking agent, assistants and adjuvants, as component A, and the aliphatic and/or cycloaliphatic polyisocyanate as component B.
Regarding the manufacture of the integral skin foams, reference may also be made to the relevant technical literature, for example to A. Nicolay et al., Gummi, Asbest, Kantschuk 30, No. 4 (1977), 226-232 and H. Y. Fabris, Advances in Urethane Technology, 2 (1973), 203-220.
The polyurethane integral skin foams manufactured according to the invention have densities of from about 60 to 600 g/l and are particularly distinguished by their light stability.
The flexible products are particularly suitable for the manufacture of automotive components, eg. headrests, armrests, crash pads and fenders, shoe soles and sports mats.
The rigid products are used in sports goods and window frames and as a wood substitute.
In the Examples, parts are by weight.
Index of abbreviations used in the Table of the Examples:
______________________________________
Mole- Func- OH- Ethy- Propy-
cular tion- num- lene lene
A-component:
weight ality ber Starter
oxide oxide
______________________________________
Polyols A 6,500 3 26 TMP + +
B 4,000 2 28 EG + +
C 4,900 3 35 GLY + +
D 465 4 480 EDA - +
E 2,000 2 58 GLY + +
F 3,100 3 550 GLY - +
G 2,000 2 56 PG - +
H 2,000 2 56
Polyester-
ols I 2,000 2 56
______________________________________
Chain B 1,4 1,4-Butanediol
extenders:
EG Ethylene glycol
PG Propylene glycol
Crosslinking
GLY Glycerol
agents: TMP Trimethylolpropane
®Ortegol 615 (from Goldschmidt AG)
EDA Ethylenediamine
Lu 3420 An adduct of ethylene-
diamine and propylene
oxide, OH-number 480
Catalysts:
1. Polyurethane catalysts:
DBTDL Dibutyl-tin dilaurate
Sn Oct Tin dioctoate
Zn Oct Zinc dioctoate
Fe acetylacetonate
DBTDA Dibutyl-tin diacetate
DBTV Dibutyl-tin versatate
2. Polyisocyanurate catalysts:
KOH = 33% strength by weight potassium
hydroxide solution in EG
K But = 33% strength by weight potassium
tert.-butylate solution in EG
K Phen = 33% strength by weight potassium
phenolate solution in EG
K Oct = 50% strength by weight potassium
octoate solution in propylene
glycol
K Ac = 33% strength by weight potassium
acetate solution in EG
KF = 33% strength by weight potassium
formate solution in EG
HHT = Tris-(N,N-dimethylaminopropyl)-s-
hexahydrotriazine
Foam stabilizers:
®Tegostab B 3471 (Goldschmidt)
®Tegostab B 4113 (Goldschmidt)
®Tegostab B 2888 (Goldschmidt)
Emulsifiers:
SM (from Bayer)
OS 710 (from Bayer)
TDAO Tridecylammonium oleate
Blowing F 11 Monofluorotrichloromethane
agents: F 12 Difluorodichloromethane
F 113 Trifluorotrichloromethane
B-component:
Isocyanates:
HMDI Hexamethylene diisocyanate
TMHMDI Trimethylhexamethylene diisocyanate
H.sub.12 MDI
Dicyclohexylmethylene diisocyanate
IPDI Isophorone diisocyanate
XDI Xylylene diisocyanate
Isocyanate prepolymers:
HMDI biuret
Biuretized hexamethylene diisocyanate from
3 moles of HMDI
HMDI HPN Reaction product of 1 mole of neopentylglycol
mono-hydroxypivalate and 2 moles of HMDI
HMDI DPG Reaction product of 1 mole of dipropylene
glycol and 2 moles of HMDI
______________________________________
Notes on the Table showing the Examples:
The entries in the first column to all sub-
sequent columns unless a fresh entry is shown. The
test data of the foams have been obtained in accordance with
the following DIN and ASTM Standard Specifications:
Tensile strength and elongation
DIN 53,571
Tear propagation test DIN 53,515
Shore A hardness DIN 53,505
E-modulus (flexural test), flexural strength
DIN 53,423
Compressive strain at 10% compression
DIN 53,421
Shore D hardness DIN 53,505
ΔY (yellowness index difference)
ASTM D 1925
__________________________________________________________________________
Polyurethane soft integral skin foam
Example No. 1 2 3 4
Starting materials
Parts Parts Parts Parts
__________________________________________________________________________
Polyols A 21 A 21 A 21 A 21
B 68 B 68 B 68 B 68
Chain extenders B 1,4 8 B 1,4 8 B 1,4 8 B 1,4 8
Crosslinking agents
EG 0.5 EG 0.5 EG 0.5 EG 0.5
A Catalysts DBTDL 3 DBTDL 3 Sn Oct 3
DBTDL 3
KOH 0.75 HHT 3 KOH 0.75 KOH 0.75
Foam stabilizers SM 1
Blowing agents F 11 6 F 11 6 F 11 6 F 11 15
Water 0.5
Water 0.5
Water 0.5
--
__________________________________________________________________________
B Isocyanates HMDI HMDI HMDI HMDI
biuret 50
biuret 100
biuret 50
biuret 50
HMDI DPG 50
-- HMDI DPG 50
HMDI HPN 50
__________________________________________________________________________
Ratio B/100 A 70 51 80 80
Free density .kg/m.sup.3
180 180 180 100
Pot life sec 30 50 70 25
Rise time sec 60 75 120 50
Molded density kg/m.sup.3
400 600 400 350
Tensile strength N/mm.sup.2
0.8 1.4 0.8 1.0
Elongation % 120 100 110 120
Tear propagation
resistance N/mm 2.0 2.5 3.0 2.0
Shore A hardness 45 50 40 40
Δ(xenon test, 500 h)
0.5 1 3 5
__________________________________________________________________________
Polyurethane soft integral skin foam
Example No. 5 6 7 8
Starting materials
Parts Parts Parts Parts
__________________________________________________________________________
Polyols C 41 C 41 C 41 C 41
B 25 B 25 B 25 B 25
Chain extenders B 1,4 11 B 1,4 11 B 1,4 11 B 1,4 11
A Crosslinking agents
Lu 3420 1
Lu 3420 1
Lu 3420 1
Lu 3420 1
Catalysts HHT 3 HHT 3 KOH 0.75 KOH 1.5
DBTDL 3 DBTDL 3 Zn Oct 3 DBTL 1.5
Foam stabilizers Tegostab 0.3
Tegostab 0.3
--
B 3471 B 3471
SM 0.5 SM 0.5 SM 0.5 SM 0.25
Blowing agents F 11 20 -- F 11 20 F 11 15
Water 0.8
-- --
__________________________________________________________________________
B Isocyanates HMDI 50 HMDI 50 HMDI 50 HMDI 50
biuret
HMDI DPG 50
HMDI DPG 50
HMDI DPG 50
HMDI DPG 50
__________________________________________________________________________
Ratio B/100 A 80 80 70 70
Free density .kg/m.sup.3
90 140 90 90
Pot life sec 35 35 23 33
Rise time sec 60 75 45 70
Molded density kg/m.sup.3
350 300 400 250
Tensile strength N/mm.sup.2
1.1 1.0 1.1 0.7
Elongation % 130 130 100 140
Tear propagation
resistance N/mm 3.0 2.0 4 2
Shore A hardness 35 50 60 24
ΔY (xenon test 500 h)
2 0 5 3
__________________________________________________________________________
Polyurethane soft integral skin foam
Example No. 9 10 11 12
Starting materials
Parts Parts Parts Parts
__________________________________________________________________________
Polyols C 41 C 41 C 41 C 41
B 25 B 25 B 25 B 25
Chain extenders B 1,4 11 B 1,4 11 B 1,4 11 B 1,4 11
A Crosslinking agents
Catalysts HHT 3 HHT 3 HHT 3 HHT 3
DBTDL 3 DBTDL 3 DBTDL 3 DBTDL 3
Foam stabilizers Tegostab 0.3
Tegostab 0.3
Tegostab 0.3
Tegostab 0.3
B 3471
SM 0.5 SM 0.5 SM 0.5 SM 0.5
Blowing agent F 11 20 F 11 20 F 11 20 F 11 20
__________________________________________________________________________
B Isocyanates HMDI 100 TMHMDI 100
H.sub.12 MDI 100
IPDI 100
__________________________________________________________________________
Ratio B/100 A 27 35 45 35
Free density .kg/m.sup.3
50 50 60 70
Pot life sec 15" 25" 35 90"
Rise time sec 20" 35" 80 200"
Molded density kg/m.sup.3
200 200 250 300
Tensile strength N/mm.sup.2
1.0 1.1 0.8 0.9
Elongation % 50 50 70 100
Tear propagation
resistance N/mm 2 2.2 1.5 2.0
Shore A hardness 30 35 25 35
ΔY (xenon test 500 h)
2 -1 2 5
__________________________________________________________________________
Polyurethane soft integral skin foam
Example No. 13 14 15 16
Starting materials
Parts Parts Parts Parts
__________________________________________________________________________
Polyols A 21 A 21 A 21 A 21
B 68 B 68 B 68 B 68
Chain extenders B 1,4 8 B 1,4 8 B 1,4 8 B 1,4 8
A Crosslinking agents
EG 0.5 EG 0.5 EG 0.5 EG 0.5
Catalysts DBTDL 3.0
DBTDL 3.0
DBTDL 3.0
Sn Oct 3.0
KBut 0.75
K phenolate 1.5
K octoate 3.0
K acetate 3.0
Foam stabilizers Tegostab
B 3471 0.3
B 3471 0.3
B 3471 0.3
B 3471 0.3
SM 0.5 SM 0.5 SM 0.5 SM 0.5
Blowing agents F 11 6 F 11 6 F 11 6 F 11 6
F 113 6.0
F 113 6.0
__________________________________________________________________________
B Isocyanates HMDI
biuret 50
biuret 50
biuret 50
biuret 50
HMDI DPG 50
HMDI DPG 50
HMDI DPG 50
HMDI DPG 50
__________________________________________________________________________
Ratio B/100 A 70 70 70 70
Free density .kg/m.sup.3
150 200 150 150
Pot life sec 35 40 35 55
Rise time sec 75 100 70 150
Molded density kg/m.sup.3
600 600 350 400
Tensile strength N/mm.sup.2
2.0 2.0 1.5 1.3
Elongation % 120 150 170 160
Tear propagation
resistance N/mm 3.5 2.5 2 2
Shore A hardness 50 40 35 40
ΔY (xenon test 500 h)
0.7 6 3 5
__________________________________________________________________________
Polyurethane soft integral skin foam
Example No. 17 18 19 20
Starting materials
Parts Parts Parts Parts
__________________________________________________________________________
Polyols C 80 C 80 C 80 C 80
G 10 G 10 G 10 G 10
Chain extenders B 1,4 10 B 1,4 10 B 1,4 10 B 1,4 10
A Crosslinking agents
Ortegol
615 4.5 615 4.5 615 4.5 615 4.5
Catalysts HHT 3 KOH 0.75 KF 0.75 KF 0.75
DBTDL 3 DBTDL 3 DBTDL 3 DBTDL 3
Foam stabilizers Tegostab
B 9113 0.5
B 9113 0.5
B 9113 0.5
B 9113 0.5
Blowing agents F 11 5 F 11 5 F 11 5 F 11 5
Water 0.5
Water 0.5
Water 0.5
Water 0.5
__________________________________________________________________________
B Isocyanates HMDI biuret 100
HMDI biuret 50
HMDI 100 HMDI biuret 50
HMDI DPG 50
-- HMDI HPN 50
__________________________________________________________________________
Ratio B/100 A 60 65 26 65
Free density .kg/m.sup.3
180 100 90 110
Pot life sec 42 25 12 30
Rise time sec 70 50 35 80
Molded density kg/m.sup.3
250 300 150 250
Tensile strength N/mm.sup.2
1.0 1.2 0.5 1.5
Elongation % 110 150 120 130
Tear propagation
resistance N/mm 2.5 2.0 1.0 2.0
Shore A hardness 45 35 40 30
ΔY (xenon test 500 h)
0.5 3 3 5
__________________________________________________________________________
Polyurethane soft integral skin foam
Example No. 21 22 23 24
Starting materials
Parts Parts Parts Parts
__________________________________________________________________________
Polyols I 75 I 75 I 75 I 75
Chain extenders EG 10 EG 10 EG 10 EG 10
A Crosslinking agents
Calalysts HHT 3 HHT 3 KOH 0.75 KBut 1.0
DBTDL 3 Sn Oct 3 DBTDL 3 DBTDL 3.0
Foam stabilizers Tegostab
B 2888 0.3
B 2888 0.3
B 2888 0.3
B 2888 0.3
SM 0.3 SM 0.3 SM 0.3 SM 0.3
Blowing agent F 11 13 F 11 13 F 11 13 F 11 13
__________________________________________________________________________
B Isocyanates HMDI
biuret 50
biuret 50
biuret 50
biuret 50
HMDI DPG 50
HMDI DPG 50
HMDI DPG 50
HMDI DPG 50
__________________________________________________________________________
5
Ratio B/100 A 100 100 100 100
Free dentity .kg/m.sup.3
150 150 150 160
Pot life sec 25 28 20 15
Rise time sec 60 75 50 30
Molded density kg/m.sup.3
450 350 450 600
Tensile strength N/mm.sup.2
1.0 0.8 1.1 2
Elongation % 120 150 140 130
Tear propagation
resistance N/mm 8.0 7.0 8.0 9
Shore A hardness 60 55 70 80
ΔY (xenon test 500 h)
1 2 1.5 3
__________________________________________________________________________
Polyurethane soft integral skin foam
Example No. 25 26 27 28
Starting materials
Parts Parts Parts Parts
__________________________________________________________________________
Polyols H 86 H 86 H 86 H 86
Chain extenders B 1,4 11 B 1,4 11 B 1,4 11 B 1,4 11
A Crosslinking agents
Gly 0.5 Gly 0.5 Gly 0.5 Gly 0.5
Catalysts HHT 3 HHT 3 HHT 3 HHT 3
DBTDL 3 DBTDL 3 DBTDL 3 DBTDL 3
Foam stabilizers Tegostab
2888 0.2 2888 0.2 2888 0.2 2888 0.2
SM 1 --
Blowing agents F 11 10 F 11 10 F 11 10 F 11 10
Water 0.5
Water 0.5
-- --
__________________________________________________________________________
B Isocyanates HMDI
biuret 50
HMDI DPG 100
HMDI biuret 50
HMDI biuret 100
HMDI DPG 50
-- HMDI HPN 50
--
__________________________________________________________________________
Ratio B/100 A 80 90 90 85
Free density .kg/m.sup.3
150 150 160 160
Pot life sec 40 40 38 35
Rise time sec 75 75 70 60
Molded density kg/m.sup.3
300 350 450 400
Tensile strength N/mm.sup.2
0.8 0.9 1.5 1.5
Elongation % 150 140 150 120
Tear propagation
resistance N/mm 2.5 3.0 3.5 3
Shore A hardness 30 45 45 50
ΔY (xenon text 500 h)
0.7 1 2.5 0
__________________________________________________________________________
Polyurethane rigid integral skin foam
Example No. 29 30 31 32
Starting materials
Parts Parts Parts Parts
__________________________________________________________________________
Polyols D 30 D 30 D 30 D 30
E 48 E 48 E 48 E 48
Chain extenders EG 4.5 EG 4.5 EG 4.5 EG 4.5
A Crosslinking agents
TMP 12 TMP 12 TMP 12 TMP 12
Catalysts HHT 1.5 HHT 3 KOH 0.75 Kbut 1.0
DBTDL 1.5
DBTDL 3 DBTDL 1.5
DBTDL 1.5
Emulsifiers OS 710 0.8
OS 710 0.8
OS 710 0.8
OS 710 0.8
TDAO 3 TDAO 3 TDAO 3 TDAO 3
Blowing agents F 11 10 F 11 10 F 11 10 F 11 10
F 12 3.0 --
__________________________________________________________________________
B Isocyanates HMDI biuret 100
HMDI biuret 50
HMDI 100 H.sub.12 MDI 100
HMDI DPG 50
-- --
__________________________________________________________________________
Ratio B/100 A 170 180 75 105
Free density .kg/m.sup.3
260 250 180 200
Pot life sec 80 42 12 65
Rise time sec 120 80 50 140
Molded density kg/m.sup.3
600 500 700 600
E-modulus
(flexural test) N/mm.sup.2
1,400 1,200 1,400 1,300
Flexural strength N/mm.sup.2
35 30 25 30
Compressive strain
at 10% compression N/mm.sup.2
5 4 5 3
Shore D hardness 70 60 65 55
ΔY (xenon test 500 h)
0.5 1 0.5 3
__________________________________________________________________________
Polyurethane rigid integral skin foam
Example No. 33 34 35 36
Starting materials
Parts Parts Parts Parts
__________________________________________________________________________
Polyols F 53 F 53 F 53 F 53
C 10 C 10 C 10 C 10
Chain extenders
A Crosslinking agents
TMP 18 TMP 18 TMP 18 TMP 18
Catalysts HHT 1.5 KOH 0.75 KF 1.0 HHT 3
DBTDL 1.5
DBTDL 3 DBTDL 3 DBTDL 3
Emulsifiers OS 710 2 OS 710 2 OS 710 2 DS 710 2
SM 0.6 SM 0.6 SM 0.6 SM 0.6
Blowing agent F 11 10 F 11 10 F 11 10 F 11 10
__________________________________________________________________________
B Isocyanates HMDI biuret 50
HMDI biuret 50
-- HMDI biuret 50
HMDI HPN 50
HMDI HPN 50
HMDI HPN 100
HMDI 50
__________________________________________________________________________
Ratio B/100 A 220 100 110 80
Free density .kg/m.sup.3
125 200 200 200
Pot life sec 80 20 25 25
Rise time sec 135 60 75 65
Molded density kg/m.sup.3
700 600 750 600
E-modulus
(flexural test) N/mm.sup.2
1,200 1,400 1,200 1,300
Flexural strength N/mm.sup.2
25 30 35 40
Compressive strain
at 10% compression N/mm.sup.2
4 3 5 6
Shore D hardness 65 60 55 70
ΔY (xenon test 500 h)
3 2 0.5 5
__________________________________________________________________________
Polyurethane soft integral skin form
Example No. 37 38 39 40
Starting materials
Parts Parts Parts Parts
__________________________________________________________________________
Polyols A 21 A 21 A 21 A 21
B 68 B 68 B 68 B 68
Chain extenders B 1,4 8 B 1,4 8 B 1,4 8 B 1,4 8
A Crosslinking agents
EG 0.5 EG 0.5 EG 0.5 EG 0.5
Catalysts Fe acetyl-
acetonate 1
Zn Oct 3 DBTDA 3 DBTV 3
KOH 0.75 KOH 0.75 KOH 0.75 KOH 0.75
Foam stabilizers SM 0.25 SM 0.25 SM 0.25 SM 0.25
Blowing agent F 11 15 F 11 15 F 11 15 F 11 15
__________________________________________________________________________
B Isocyanates HMDI biuret 100
HMDI biuret 100
HMDI biuret 100
XDI 100
__________________________________________________________________________
Ratio B/100 A 80 80 80 80
Free density .kg/m.sup.3
150 120 180 160
Pot life sec 30 35 25 30
Rise time sec 55 60 45 75
Molded density kg/m.sup.3
350 400 450 500
Tensile strength N/mm.sup.2
1.5 1.0 1.2 1.1
Elongation % 150 120 130 110
Tear propagation
resistance N/mm 2.0 2.1 2.5 2.5
Shore A hardness 30 40 35 45
ΔY (xenon test 500 h)
0.5 1 2 3
__________________________________________________________________________
Claims (6)
1. A process for the manufacture of light-stable polyurethane integral skin foams by reacting a mixture of organic polyisocyanates, polyols, catalysts and blowing agents, with or without assistants and adjuvants, wherein
the organic polyisocyanates used are selected from the group consisting of aliphatic polyisocyanates, cycloaliphatic polyisocyanates, modified aliphatic polyisocyanates, modified cycloaliphatic polyisocyanates and mixtures thereof and
the catalysts used are synergistic catalyst combinations comprising
(A) a strongly basic polyisocyanurate catalyst selected from the group consisting of alkali metal hydroxides, alkali metal alcoholates, alkali metal phenolates, alkali metal salts of weak acids, 1,3,5-tris-(N,N-dialkylaminoalkyl)-s-hexahydrotriazines and mixtures thereof and
(B) dibutyl-tin dilaurate.
2. The process of claim 1 wherein the catalyst combination consists of
(A) from 0.01 to 5 parts by weight of an alkali metal hydroxide, alkali metal alcoholate, alkali metal phenolate, alkali metal salt of a weak acid and/or 1,3,5-tris-(N,N-dialkylaminoalkyl)-s-hexahydrotriazine and
(B) from 0.01 to 5 parts by weight of dibutyl-tin dilaurate, per 100 parts by weight of polyol.
3. The process of claim 1, wherein the organic polyisocyanate used is a urethane-modified aliphatic and/or cycloaliphatic polyisocyanate containing NCO groups.
4. The process of claim 3, wherein the urethane-modified polyisocyanate is prepared by reacting an aliphatic and/or cycloaliphatic diisocyanate and an alkanediol of 2 to 10 carbon atoms in the alkylene radical, in the molar ratio of about 2:1.
5. The process of claim 1, wherein the organic polyisocyanate used is an aliphatic and/or cycloaliphatic polyisocyanate containing biuret groups.
6. The process of claim 1, wherein the catalyst combination consists of tris-(dimethylaminopropyl)-s-hexahydrotriazine and dibutyl-tin dilaurate.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2825569 | 1978-06-10 | ||
| DE19782825569 DE2825569A1 (en) | 1978-06-10 | 1978-06-10 | PROCESS FOR THE MANUFACTURING OF LIGHT-STABLE POLYURETHANE INTEGRAL FOAM |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US4256841A true US4256841A (en) | 1981-03-17 |
Family
ID=6041533
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US06/038,853 Expired - Lifetime US4256841A (en) | 1978-06-10 | 1979-05-14 | Manufacture of light-stable polyurethane integral foams |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4256841A (en) |
| EP (1) | EP0006150B1 (en) |
| JP (1) | JPS54162795A (en) |
| AU (1) | AU4786379A (en) |
| DE (2) | DE2825569A1 (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4310633A (en) * | 1978-07-06 | 1982-01-12 | Bayer Aktiengesellschaft | Hexahydrotriazine carboxylates and the use thereof as catalysts in the production of polyisocyanurate plastics |
| US4314037A (en) * | 1980-12-15 | 1982-02-02 | Air Products And Chemicals, Inc. | Hetero nitrogen catalysts |
| US4521548A (en) * | 1983-04-12 | 1985-06-04 | The Dow Chemical Company | Preparation of polyether polyols |
| US4772639A (en) * | 1987-01-14 | 1988-09-20 | Bayer Aktiengesellschaft | Process for the production of molded polyurethane parts |
| US6133473A (en) * | 1998-06-25 | 2000-10-17 | Rohm And Haas Company | Synthesis of carbamate compounds |
| US6211258B1 (en) | 1996-11-08 | 2001-04-03 | Imperial Chemical Industries Plc | Process for preparing rigid and flexible polyurethane foams |
| WO2003074618A1 (en) * | 2002-03-02 | 2003-09-12 | Basf Coatings Ag | Electrodepositable paints free from insoluble solids |
| US20060160977A1 (en) * | 2005-01-14 | 2006-07-20 | Jung-Shun Ou | Prescription for preparation of non-yellowing polyurethane foam |
| US7727609B1 (en) * | 2007-03-02 | 2010-06-01 | Dean Crasno | Sectional interlocking T-foam impact barrier wall |
| US20110263741A1 (en) * | 2008-11-21 | 2011-10-27 | Chung Hsien Tu | Soft polyurethane foam with low resilience and the preparation method thereof |
| WO2015150408A1 (en) * | 2014-04-03 | 2015-10-08 | Huntsman International Llc | Isocyanate trimerization catalyst for making polyisocyanurate comprising foams |
| US9988504B2 (en) | 2014-03-28 | 2018-06-05 | Huntsman International Llc | Reinforced organic natural fiber composites |
| EP3611203A1 (en) | 2018-08-17 | 2020-02-19 | Covestro Deutschland AG | Flexible foams |
| US11332570B2 (en) | 2018-05-15 | 2022-05-17 | Covestro Deutschland Ag | Flexible foams |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4242463A (en) * | 1979-12-19 | 1980-12-30 | Sheller-Globe Corporation | Color stable integral skin foam |
| JPS56155220A (en) * | 1980-03-17 | 1981-12-01 | Troy Chemical Corp | Urethane reaction catalyst |
| US4426510A (en) * | 1982-08-05 | 1984-01-17 | Rohm And Haas Company | Polyurethane preparation using organo-zinc catalyst and time-lapse modifier |
| JPS60240416A (en) * | 1984-05-16 | 1985-11-29 | Mitui Toatsu Chem Inc | Shortening of mold removing time |
| GB8531180D0 (en) * | 1985-12-18 | 1986-01-29 | Ici Plc | Cocatalyst systems |
| JPH0439321A (en) * | 1990-06-04 | 1992-02-10 | Achilles Corp | Production of light-resistant polyurethane foam |
| JPH05222146A (en) * | 1992-02-14 | 1993-08-31 | Daikin Ind Ltd | Production of rigid polyurethane foam |
| AU1095197A (en) * | 1995-12-01 | 1997-06-27 | Rathor Ag | Rapid-foaming foam for prefabricated system building |
| DE102011015304A1 (en) | 2011-03-24 | 2012-09-27 | Gt Elektrotechnische Produkte Gmbh | New gradient polymers and processes for their preparation |
| EP4219578A1 (en) | 2022-01-28 | 2023-08-02 | Covestro Deutschland AG | Preparation of aliphatic polyurethane soft foams in a prepolymer process based on aliphatic oligomeric polyisocyanates and monohydroxy-functional compounds |
| WO2023144058A1 (en) | 2022-01-28 | 2023-08-03 | Covestro Deutschland Ag | Producing aliphatic soft polyurethane foams with reduced setting times (tack-free times) and rising times |
| EP4219579A1 (en) | 2022-01-28 | 2023-08-02 | Covestro Deutschland AG | Preparation of aliphatic polyurethane soft foams in a prepolymer process based on aliphatic oligomeric polyisocyanates and monohydroxy-functional compounds |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3476933A (en) * | 1966-10-21 | 1969-11-04 | Westinghouse Electric Corp | Large-celled polyurethane foam |
| US3726952A (en) * | 1969-10-24 | 1973-04-10 | Bayer Ag | Method of molding intergral skin polyurethane foams having mold release properties |
| US3793268A (en) * | 1970-03-23 | 1974-02-19 | Bayer Ag | Process for the production of polyurethane foam resins |
| US3799898A (en) * | 1970-01-05 | 1974-03-26 | Scott Paper Co | Stable hydrophilic polyurethane foams prepared by using a surfactant soluble in the hydrophilic polyol reactant |
| US3824199A (en) * | 1967-07-31 | 1974-07-16 | Upjohn Co | Process for preparing self-skinned polyurethane foam |
| US3899454A (en) * | 1969-05-13 | 1975-08-12 | Bayer Ag | Process for the production of synthetic plastics comprising urethane groups and biuret groups |
| US4025466A (en) * | 1973-10-03 | 1977-05-24 | S.A. Prb | Process for preparing polyurethane foam and foam so obtained |
| DE2710910A1 (en) | 1976-03-24 | 1977-10-06 | Philips Nv | TAPE TRANSPORT DEVICE FOR TENSIONING AND TRANSPORTING A MAGNETIC TAPE |
| US4058492A (en) * | 1974-01-10 | 1977-11-15 | Bayer Aktiengesellschaft | Process for molding polyurethane foams |
| US4065410A (en) * | 1975-03-27 | 1977-12-27 | Bayer Aktiengesellschaft | Polyurethane foams having an integral skin using a mixture of polyols as the chain extender |
| US4150206A (en) * | 1976-03-12 | 1979-04-17 | S.A. Prb | Process for preparing polyurethane with integral skin |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1719325B2 (en) * | 1967-08-23 | 1975-06-12 | Wacker-Chemie Gmbh, 8000 Muenchen | Process for achieving the weldability of elastic polyurethane foams |
| BE786971A (en) * | 1971-08-05 | 1973-01-31 | Basf Wyandotte Corp | RIGID FOAM MANUFACTURING PROCESS |
| DD113766A1 (en) * | 1974-07-26 | 1975-06-20 | ||
| ZA755593B (en) * | 1975-04-09 | 1976-08-25 | M & T Chemicals Inc | Polyurethane foams and compositions and processes for preparing rigid urethane foams |
| CH601370A5 (en) * | 1975-09-16 | 1978-07-14 | M & T Chemicals Inc |
-
1978
- 1978-06-10 DE DE19782825569 patent/DE2825569A1/en active Pending
-
1979
- 1979-05-14 US US06/038,853 patent/US4256841A/en not_active Expired - Lifetime
- 1979-05-28 EP EP79101619A patent/EP0006150B1/en not_active Expired
- 1979-05-28 DE DE7979101619T patent/DE2964667D1/en not_active Expired
- 1979-06-07 AU AU47863/79A patent/AU4786379A/en not_active Abandoned
- 1979-06-07 JP JP7066679A patent/JPS54162795A/en active Pending
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3476933A (en) * | 1966-10-21 | 1969-11-04 | Westinghouse Electric Corp | Large-celled polyurethane foam |
| US3824199A (en) * | 1967-07-31 | 1974-07-16 | Upjohn Co | Process for preparing self-skinned polyurethane foam |
| US3899454A (en) * | 1969-05-13 | 1975-08-12 | Bayer Ag | Process for the production of synthetic plastics comprising urethane groups and biuret groups |
| US3726952A (en) * | 1969-10-24 | 1973-04-10 | Bayer Ag | Method of molding intergral skin polyurethane foams having mold release properties |
| US3799898A (en) * | 1970-01-05 | 1974-03-26 | Scott Paper Co | Stable hydrophilic polyurethane foams prepared by using a surfactant soluble in the hydrophilic polyol reactant |
| US3793268A (en) * | 1970-03-23 | 1974-02-19 | Bayer Ag | Process for the production of polyurethane foam resins |
| US4025466A (en) * | 1973-10-03 | 1977-05-24 | S.A. Prb | Process for preparing polyurethane foam and foam so obtained |
| US4058492A (en) * | 1974-01-10 | 1977-11-15 | Bayer Aktiengesellschaft | Process for molding polyurethane foams |
| US4065410A (en) * | 1975-03-27 | 1977-12-27 | Bayer Aktiengesellschaft | Polyurethane foams having an integral skin using a mixture of polyols as the chain extender |
| US4150206A (en) * | 1976-03-12 | 1979-04-17 | S.A. Prb | Process for preparing polyurethane with integral skin |
| DE2710910A1 (en) | 1976-03-24 | 1977-10-06 | Philips Nv | TAPE TRANSPORT DEVICE FOR TENSIONING AND TRANSPORTING A MAGNETIC TAPE |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4310633A (en) * | 1978-07-06 | 1982-01-12 | Bayer Aktiengesellschaft | Hexahydrotriazine carboxylates and the use thereof as catalysts in the production of polyisocyanurate plastics |
| US4314037A (en) * | 1980-12-15 | 1982-02-02 | Air Products And Chemicals, Inc. | Hetero nitrogen catalysts |
| US4521548A (en) * | 1983-04-12 | 1985-06-04 | The Dow Chemical Company | Preparation of polyether polyols |
| US4772639A (en) * | 1987-01-14 | 1988-09-20 | Bayer Aktiengesellschaft | Process for the production of molded polyurethane parts |
| US6211258B1 (en) | 1996-11-08 | 2001-04-03 | Imperial Chemical Industries Plc | Process for preparing rigid and flexible polyurethane foams |
| US6133473A (en) * | 1998-06-25 | 2000-10-17 | Rohm And Haas Company | Synthesis of carbamate compounds |
| WO2003074618A1 (en) * | 2002-03-02 | 2003-09-12 | Basf Coatings Ag | Electrodepositable paints free from insoluble solids |
| US20060160977A1 (en) * | 2005-01-14 | 2006-07-20 | Jung-Shun Ou | Prescription for preparation of non-yellowing polyurethane foam |
| US7727609B1 (en) * | 2007-03-02 | 2010-06-01 | Dean Crasno | Sectional interlocking T-foam impact barrier wall |
| US20110263741A1 (en) * | 2008-11-21 | 2011-10-27 | Chung Hsien Tu | Soft polyurethane foam with low resilience and the preparation method thereof |
| US9988504B2 (en) | 2014-03-28 | 2018-06-05 | Huntsman International Llc | Reinforced organic natural fiber composites |
| WO2015150408A1 (en) * | 2014-04-03 | 2015-10-08 | Huntsman International Llc | Isocyanate trimerization catalyst for making polyisocyanurate comprising foams |
| CN106459335A (en) * | 2014-04-03 | 2017-02-22 | 亨茨曼国际有限公司 | Isocyanate trimerization catalyst for making polyisocyanurate comprising foams |
| CN106459335B (en) * | 2014-04-03 | 2020-02-14 | 亨茨曼国际有限公司 | Isocyanate trimerisation catalysts for making polyisocyanurate comprising foams |
| US11548973B2 (en) | 2014-04-03 | 2023-01-10 | Huntsman International Llc | Isocyanate trimerization catalyst for making polyisocyanurate comprising foams |
| US11332570B2 (en) | 2018-05-15 | 2022-05-17 | Covestro Deutschland Ag | Flexible foams |
| EP3611203A1 (en) | 2018-08-17 | 2020-02-19 | Covestro Deutschland AG | Flexible foams |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS54162795A (en) | 1979-12-24 |
| EP0006150A1 (en) | 1980-01-09 |
| AU4786379A (en) | 1979-12-20 |
| DE2964667D1 (en) | 1983-03-10 |
| DE2825569A1 (en) | 1979-12-20 |
| EP0006150B1 (en) | 1983-02-02 |
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