US3876422A - Elongated leaded steel casting - Google Patents

Abstract

Uncropped, unworked, elongated, leaded steel castings, such as ingots, of commercial size (1,000 lbs. and heavier) or strand cast section. Lead content greater than 0.35 wt. percent and up to 0.70 wt. percent. Commercially acceptable surface. Lead present in inclusion form of microscopic size. No lead macroinclusions at bottom of uncropped ingot. No rare earths or lead oxide inclusions. Process for making is described.

Description

United States Patent [1 1 Cantera et a1.

[4 1 Apr. 8, 1975 ELONGATED LEADED STEEL CASTING [75] Inventors: Gregorio Asua Cantera; Jose M.

Palacios Reparaz, both of Bilbao, Spain; Louis Molnar, Hammond, Ind.

[73] Assignees: Inland Steel Co., Chicago, 111.", S.A.

Echevarria, Bilbao, Spain 22 Filed: Oct. 3, 1973 211 Appl. No.: 403,065

Related U.S. Application Data [63] Continuation-impart of Ser. No. 256,806, May 25,

[52] U.S. Cl. 75/123 F; 75/129; 148/36 [51] Int. Cl. C22c 37/00 [58] Field of Search 75/129, 123 F, 130, 130.5; 266/34 T; 29/1875; 148/2, 36

[56] References Cited UNITED STATES PATENTS 2,914,400 11/1959 Roberts 75/123 F 3,141,767 7/1964 Funk 75/129 3,634,074 1/1972 Ito et al. 75/123 F 3,67l.224 6/1972 North et al...... 75/123 F 3,728,109 4/1973 Okubo et a1. 75/129 FOREIGN PATENTS OR APPLICATIONS 1,081,616 5/1960 Germany 75/129 OTHER PUBLICATIONS Lyman, et aL; Metals Handbook (Vol. I) ASM, Cleveland, 1961, p. 308.

Primary Examiner-Walter R. Satterfield Attorney, Agent, or FirmMerriam, Marshall, Shapiro & Klose [57] ABSTRACT 10 Claims, No lDrawings ELONGATED LEADED STEEL CASTING RELATED APPLICATION This is a continuation-in-part of application Ser. No. 256,806 filed May 25, 1972 and entitled Method For Adding Lead To Steel In A Ladle."

BACKGROUND OF THE INVENTION The present invention relates generally to leaded steel ingots and more particularly to uncropped, unworked, leaded steel ingots having a relatively high lead content (greater than 0.35 wt. percent and up to 0.50 wt. percent or higher) with the lead being present solely as microscopic inclusions, the bottom of the ingot being essentially devoid of lead macroinclusions or macrosegregation as that term is generally understood in the art. (e.g. see North et al., U.S. Pat. No. 3,671.224, cols. l and 2).

Lead is added to steel to improve the machinability of the steel. Increasing the lead content generally increases the machinability, for lead contents below 0.8 wt. percent. Lead is present in solidified steel as inclusions. Lead inclusions of microscopic size are desirable, but lead macroinclusions are undesirable.

Conventional attempts to produce commercial-size, leaded steel ingots with the relatively high lead content noted above and without lead macroinclusions in the as-cast ingot have been largely unsuccessful. Even with lead contents below 0.30 wt. percent, lead macroinclusions segregated at the bottom of the ascast ingot so that it was necessary to crop or cut off the bottom 4-10 percent of the ingot to eliminate the part of the ingot containing the undesirable lead macroinclusions. This reduced the yield from the ingot, which was undesirable.

There is prior art which teaches obtaining a relatively high lead content with an absence of lead macroinclusions in the as-cast ingot, but this art requires special addition ingredients, such as rare earths (Corradini U.S. Pat. No. 3,313,620) or special processing techniques which produce, upon cooling of the molten steel, lead oxide precipitates that do not settle by gravity in the molten steel (German Published Appln. No. 2,012,688).

There is some early prior art, dating back to the late l930s, describing solidified steel containing large amounts of lead occurring solely as uniformly dispersed microinclusions; but this combination of features has not been obtainable under commercial conditions or in commercial-size ingots (e.g., 1,000 lbs. and heavier), and more recent prior art has acknowledged this failure (North et al. U.S. Pat. No. 3,671,224, listing early prior art at Col. 1, lines 4042).

As previously noted, it is desirable to provide a commercial-size ingot with a high lead content and with essentiallyno lead macroinclusions at the bottom of the uncropped ingot, i.e., devoid of such lead macroinclusions as would render the bottom of the ingot commercially unacceptable and necessitate cropping the bottom of the ingot for that reason.

SUMMARY OF THE INVENTION The present invention is an uncropped ingot of commercial size and with a commercially acceptable surface devoid of surface defects usually associated with ingots sticking in the ingot mold, e.g., tears, cracks or mold pieces stuck on the ingot surface. This ingot has a lead content greater than 0.35 wt. percent and up to 0.50 wt. percent or higher, with essentially no lead macroinclusions in the bottom of the as-cast ingot, with no rare earths and with essentially no lead oxide inclusions.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS Commercial-size ingots in their as-cast, uncropped, unworked condition range in size from about 7 inches X 7 inches X inches or about 1,000 lbs. up to ingots of 25,000 lbs. and over. Such ingots taper slightly and may be either what are known as bit end up ingots or big end down ingots. A typical commercial-size big end up ingot (open top or hot top) is 28 inches X 34 inches X 84 inches or about 18,000 lbs. A typical big end down ingot is 29 inches X 29 inches X 89 inches (16,000 lbs.) or 32 inches X 36 inches X 89 inches (25,000 lbs.). (The cross-sectional dimensions of ingots are usually measured at the top).

The base composition of the steel (i.e., the steel composition without lead) includes virtually all base compositions to which lead has heretofore been added. The base composition for plain carbon steels may be in the following range:

For alloy steels, the base composition may contain, in addition to the above-listed elements, one or more of the following alloying elements:

Element Wt. /1

chromium O-l .60 nickel 03.75 molybdenum 0-.50 vanadium 0-.25 boron 0.003 titanium 0.50 zirconium 0-.25 columbium 0.25 aluminum 0-.l0 calcium 0.02

Typical examples of such base compositions in the AISI 1200 series of steels are within the following ranges:

Element Wt. 7:

carbon 0.13 max. manganese 0.60-l .00 phosphorous 007-0. 1 2 sulfur 0.08-0.33 iron essentially the balance To such base compositions, lead is added, to provide a final lead content greater than 0.35 wt. percent and typically up to 0.50 wt. percent, although higher lead contents are contemplated, e.g., up to 0.60-0.70 wt.

percent. Preferably, the lead content is in the range of 0.450.50 wt. percent or 0.45-0.60 wt. percent.

The lead is present in the solidified steel as inclusions, and these inclusions are relatively uniformly distributed throughout the length of the as-cast ingot. Es sentially all of the lead inclusions are microscopic, there being essentially no lead macroinclusions throughout the entire length of the as-cast ingot. There is essentially no peripheral segregation of leadcontaining macroinclusions; and the bottom of the ascast ingot is essentially devoid of lead macroinclusions, so that cropping of the ingot, to get rid of that portion of the ingot in which macroinclusions of lead have conventionally segregated, is not necessary.

The lead inclusions consist essentially of lead or a compound of lead other than lead oxide. The lead may be unassociated with other inclusions, or it may be associated with inclusions such as manganese sulfide or complexes of iron, manganese, oxygen and sulfur. An example of a lead compound is lead telluride (occurring when both tellurium and lead are added to the steel to improve machinability). Virtually none of the lead is present as lead oxide, no lead oxide having been found upon inspection of the microscopic inclusions containing lead. This condition occurs even in the absence of aluminum in amounts normally present when aluminum is added to kill the steel or refine the grain size (e.g., .015-0.65 wt. percent.

Prior to casting the ingot, the lead is added to the steel in the manner described below.

Molten steel of the desired composition, and at a temperature in the range 29003 100C., tapped from a steel-making furnace into a ladle while retaining most of the slag in the furnace. The ladle is covered to isolate the ladle interior from the outside atmosphere. Only a very thin layer of slag covers the bath of molten steel in the ladle at this time.

The ladle bottom contains a pair of spaced-apart porous plugs through which inert argon gas is introduced into the bath. The rising argon gas bubbles stir the molten steel and, where the argon bubbles breach the surface of the bath, the slag layer is pushed aside uncovering a portion of the top of the molten steel bath. After introducing argon to the steel for -20 seconds, lead is introduced through a port in the ladle cover onto the top of the bath at the portion of the bath surface not covered by the slag, but at a location not directly over a porous plug. Argon stirring is continued during the lead-adding step which takes about 2-3 minutes, and stirring with argon gas also continues for 2-3 minutes after the lead-adding step.

Gases accumulating at the top of the ladle during th argon stirring and lead-adding steps (e.g., argon and lead fumes) are exhausted through an exhaust conduit communicating with an exhaust opening in the ladle cover. A conventional exhaust blower may be used to remove gases accumulating at the top of the bath inside the ladle. Removal of gases can be controlled to provide a pressure within the covered ladle greater than atmospheric. A gaseous atmosphere, less oxidizing than the atmosphere outside the ladle, is maintained over the bath inside the covered ladle, during the leadadding step and thereafter.

Sufficient lead is added to give a final lead content greater then 0.35 wt. percent (preferably at least 0.45 wt. percent) up to 0.50 wt. percent or higher, consistent with obtaining the other objectives of the present invention. No rare earths are added to the steel; and the atmosphere within the ladle at the time the lead is added is less oxidizing than the atmosphere outside the ladle, a condition which does not favor the formation of lead oxide.

After the lead has been added and after the leadcontaining bath has been stirred with argon gas, as described above, introduction of argon gas is stopped, the cover is removed from the ladle, the top of the bath is covered with expanded vermiculite to suppress fuming, and the lead-containing molten steel is teemed into conventional ingot molds (either big end up or big end down) or into the tundish of a conventional continuous caster producing continuously cast strands of steel. After teeming, the slag is dumped from the ladle.

The temperature of the steel at the time of teeming is about 2850F., and this is below the temperature at which there would be mold sticking problems, as described below.

The conventional mold for commercial-size steel ingots is made of cast iron. 1f the steel is teemed into the ingot mold at too high a temperature (e.g., 3,0003100F.), the solidified ingot may weld or stick to the inside of the cast iron mold. When this occurs, it is difficult to remove the ingot and sometimes the mold even has to be broken open to remove the ingot. Because the cost of the mold is comparable to the value of the ingot, such a practice is commercially unacceptable. Moreover, ingots which stick in the ingot molds have surface defects, such as surface cracks, tears, etc., which render the ingot (and the steel rolled from such an ingot) commercially unacceptable without substantial special surface conditioning. An ingot in accordance with the present invention has, as-cast, a commercially acceptable surface, i.e., a surface devoid of such defects as would otherwise require said special surface conditioning.

The porous plugs are purged with an oxygen blow for about 5-10 seconds just before introducing the argon and for about 30-60 seconds after dumping the slag.

A further description of methods for adding lead to steel in a covered ladle is contained in parent application Ser. No. 256,806 filed May 25, 1972 and entitled Method For Adding Lead To Molten Steel In a Ladle.

When the lead-containing steel is continuously cast into strands, a typical commercial-size strand would be 3inches X 3inches, on the small side. Larger sizes include strands l0inches 23inches and over. Eventually these strands are cut into lengths up to 40 ft.

The present invention covers both continuously cast strands and ingots, both being included within the generic term elongated casting, and is directed to the casting before it has undergone working. In both embodiments, the casting, whether it be a continuously cast strand or an ingot, is elongated and uncropped, with a lead content greater then 0.35 wt. percent and up to 0.70 wt. percent (preferably 0.45-0.60 wt. percent and a weight greater than about 1,000 lbs., the lead being present in inclusion form of microscopic size, there being essentially no lead macroinclusions in the bottom of the uncropped, elongated casting. Nor does the casting contain any rare earths or any significant amounts of lead oxide inclusions.

The foregoing detailed description has been given for clearness of understanding only, and no unnecessary limitations should be understood therefrom, as modifications will be obvious to those skilled in the art.

What is claimed is:

1. An elongated, uncropped. as-cast unworked casting composed of leaded steel and comprising:

a weight greater than about 1000 pounds and a commercially acceptable surface;

a lead content greater than 0.35 wt. percent and up to 0.70 wt. percent;

lead inclusions, consisting essentially of microscopic inclusions comprising elemental lead, distributed throughout the length of said elongated casting; said elongated casting being essentially devoid of macroscopic lead inclusions throughout its length including the bottom portion of said uncropped, elongated casting;

said casting being devoid of rare earths.

2. An elongated casting as recited in claim 1 and which is essentially devoid of lead oxide inclusions and of aluminum.

3. An elongated casting as recited in claim 1 wherein said casting is an ingot.

4. An elongated casting as recited in claim 1 wherein said casting is a continuously cast strand.

5. An elongated casting as recited in claim 1 wherein said lead content is in the range 0.450.50 wt. percent.

6. An elongated casting as recited in claim 1 wherein said lead content is in the range 0.45-0.60 wt. percent.

7. An elongated, uncropped. as-cast ingot composed of leaded steel and comprising:

a weight greater than about l,000 pounds and a commercially acceptable surface;

a lead content greater than 0.35 wt. percent and up to 0.70 wt. percent;

lead inclusions, consisting essentially of microscopic inclusions comprising elemental lead, distributed throughout the length of said ingot;

said ingot being essentially devoid of macroscopic lead inclusions throughout: its length including the bottom portion of said uncropped ingot;

said ingot being devoid of rare earths.

8. An uncropped ingot as recited in claim 7 and which is essentially devoid of lead oxide inclusions and of aluminum.

9. An uncropped ingot as recited in claim 7 wherein said lead content is in the range 0.45-0.50 wt. percent.

10. An uncropped ingot as recited in claim 7 wherein said lead content is in the range 045-060 wt. percent. l= Il UNITED STATES PATENT OFFICE QEHHQATE @E QQECTEN 9 PATENT NO. 3,876,422

DATED 1 April 8 1975 iNVENTOR(S) 1 Gregorio Asua Cantera, et al.

it is certified that error appears in the above-identified patent and that said Letters Patent Q are hereby corrected as shown below:

Col 1, line 46, after "1930's" insert or early l940's--=. Col, 2, line 13, delete "bit" and insert big-.

Col, 3, line 4 after "these" insert lead.

Col 3, line 28, delete "0,65" and insert --.065.,

C Col, 3, line 28 after "percent" insert Cole 3, line 32, delete "C.," and. insert F., is--.

igned and eaie this 0 ni z h fig August 1975 {SEAL} AtlSt.

@ erm-i c. MASON c4 MARSHALL DANN ,-1Ims'rmg ()fjr'rer (mnmrlssrimvr uj'Palenrs and Trademarkx

Claims (10)

1. AN ELONGATED, UNCROPPED, AS-CAST UNWORKED CASTING COMPOSED OF LEADED STEEL AND COMPRISING: A WEIGHT GREATER THAN ABOUT 1000 POUNDS AND A COMMERCIALLY ACCEPTABLE SURFACE; A LEAD CONTENT GREATER THAN 0.35 WT. PERCENT AND UP TO 0.70 WT. PERCENT; LEAD INCLUSIONS, CONSISTING ESSENTIALLY OF MICROSCOPIC INCLUSIONS COMPRISING ELEMENTAL LEAD, DISTRUBTED THROUGOUT THE LENGTH OF SAID ELONGATED CASTING; SAID ELONGATED CAUSING BEING ESSENTIALLY DEVOID OF MACROSCOPIC LEAD INCLUSIONS THROUGHOUT ITS LENGTH INCLUDING THE BOTTOM PORTION OF SAID UNCROPPED, ELONGATED CAUSTING; SAID CASTING BEING DEVOID OF RARE EARTHS.

2. An elongated casting as recited in claim 1 and which is essentially devoid of lead oxide inclusions and of aluminum.

3. An elongated casting as recited in claim 1 wherein said casting is an ingot.

4. An elongated casting as recited in claim 1 wherein said casting is a continuously cast strand.

5. An elongated casting as recited in claim 1 wherein said lead content is in the range 0.45-0.50 wt. percent.

6. An elongated casting as recited in claim 1 wherein said lead content is in the range 0.45-0.60 wt. percent.

7. An elongated, uncropped, as-cast ingot composed of leaded steel and comprising: a weight greater than about 1,000 pounds and a commercially acceptable surface; a lead content greater than 0.35 wt. percent and up to 0.70 wt. percent; lead inclusions, consisting essentially of microscopic inclusions comprising elemental lead, distributed throughout the length of said ingot; said ingot being essentially devoid of macroscopic lead inclusions throughout its length including the bottom portion of said uncropped ingot; said ingot being devoid of rare earths.

8. An uncropped ingot as recited in claim 7 and which is essentially devoid of lead oxide inclusions and of aluminum.

9. An uncropped ingot as recited in claim 7 wherein said lead content is in the range 0.45-0.50 wt. percent.

10. An uncropped ingot as recited in claim 7 wherein said lead content is in the range 0.45-0.60 wt. percent.