US20080155762A1 - Process for dyeing a textile web - Google Patents
Process for dyeing a textile web Download PDFInfo
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- US20080155762A1 US20080155762A1 US11/617,473 US61747306A US2008155762A1 US 20080155762 A1 US20080155762 A1 US 20080155762A1 US 61747306 A US61747306 A US 61747306A US 2008155762 A1 US2008155762 A1 US 2008155762A1
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- Prior art keywords
- web
- dye
- textile web
- textile
- microwave
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/20—Physical treatments affecting dyeing, e.g. ultrasonic or electric
- D06P5/2011—Application of vibrations, pulses or waves for non-thermic purposes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B13/00—Treatment of textile materials with liquids, gases or vapours with aid of vibration
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B19/00—Treatment of textile materials by liquids, gases or vapours, not provided for in groups D06B1/00 - D06B17/00
- D06B19/0005—Fixing of chemicals, e.g. dyestuffs, on textile materials
- D06B19/007—Fixing of chemicals, e.g. dyestuffs, on textile materials by application of electric energy
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/20—Physical treatments affecting dyeing, e.g. ultrasonic or electric
- D06P5/2066—Thermic treatments of textile materials
- D06P5/2083—Thermic treatments of textile materials heating with IR or microwaves
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
- D06B3/20—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics with means to improve the circulation of the treating material on the surface of the fabric
- D06B3/205—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics with means to improve the circulation of the treating material on the surface of the fabric by vibrating
- D06B3/206—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics with means to improve the circulation of the treating material on the surface of the fabric by vibrating the textile material
Definitions
- This invention relates generally to processes for dyeing textile webs, and more particularly to a process for dyeing a textile web in which both ultrasonic energy and microwave energy is used to facilitate the dyeing process.
- the dyeing of textile webs is commonly achieved in one of two manners, one being immersing the textile web into a bath of dye solution so that the dye soaks into the textile web and the second being applying dye to (e.g., by spraying or coating) one or both faces of the textile web.
- Immersion also commonly referred to as a dip-coating process
- the textile web requires a substantial amount of dye solution to be used to saturate the textile web.
- the textile web must be washed to remove a substantial amount of unbound dye from the web. While dip-coating results in good penetration of the dye throughout the entire textile web, it presents a relatively inefficient use of the dye solution and requires considerable post-processing of the web.
- Dye may instead be applied (such as by spraying or coating) to one or both faces of the textile web by any number of application techniques including, without limitation, ink jet systems, spray systems, gravure roll, slot die, rod coater, rotary screen curtain coater, air knife, brush and the like.
- application techniques including, without limitation, ink jet systems, spray systems, gravure roll, slot die, rod coater, rotary screen curtain coater, air knife, brush and the like.
- the web is often heated and/or steamed to promote binding of the dye to the textile web.
- the textile web is then washed, such as in a bath of water or other cleaning solution, to remove unbound and excess dye from the web.
- the dye is applied to the web, it is also common to subject the dyed web to a drying and curing process, such as where the web is placed in an oven at a suitable temperature to dry the dye to thereby facilitate binding of the dye to the web.
- a drying and curing process such as where the web is placed in an oven at a suitable temperature to dry the dye to thereby facilitate binding of the dye to the web.
- a drying process often takes a relatively considerable amount of time compared to the desired speed at which the web is to be moved.
- a process for dyeing a textile web having a first face and a second face opposite the first face generally comprises applying dye to the textile web and then moving the web in an open configuration thereof over a contact surface of an ultrasonic vibration system with the textile web in direct contact with the contact surface of the ultrasonic vibration system.
- the ultrasonic vibration system is operated to impart ultrasonic energy to the textile web to facilitate the distribution of dye throughout the web.
- the web is then moved further in its open configuration through a microwave application chamber of a microwave system and the microwave system is operated to impart microwave energy to the web in the microwave application chamber to facilitate binding of the dye to the web.
- a process for dyeing a textile web having a first face, a second face opposite the first face and a thickness from the first face to the second face generally comprises applying dye to the textile web throughout the thickness thereof.
- the web is then moved in an open configuration thereof through a microwave application chamber of a microwave system and the microwave system is operated to impart microwave energy to the web in the microwave application chamber to facilitate binding of the dye in the web.
- FIG. 1 is a schematic of one embodiment of apparatus for dyeing a textile web according to one embodiment of a process for dyeing a textile web;
- FIG. 2 is a side elevation of an ultrasonic vibration system and support frame of the apparatus of FIG. 1 ;
- FIG. 3 is a front elevation of the ultrasonic vibration system of the apparatus of FIG. 1 ;
- FIG. 4 is a side elevation thereof
- FIG. 5 is a perspective of one embodiment of a microwave system for use with the apparatus of FIG. 1 ;
- FIG. 6 is a perspective of a second embodiment of a microwave system for use with the apparatus of FIG. 1 ;
- FIG. 7 is a perspective of a third embodiment of a microwave system for use with the apparatus of FIG. 1 ;
- FIG. 8 is a perspective of a fourth embodiment of a microwave system for use with the apparatus of FIG. 1 ;
- FIG. 9 is a perspective of a fifth embodiment of a microwave system for use with the apparatus of FIG. 1 ;
- FIG. 10 is a perspective of a sixth embodiment of a microwave system for use with the apparatus of FIG. 1 .
- the textile web 23 to be processed by the apparatus 21 is suitably a woven web, but may also be a non-woven web, including without limitation bonded-carded webs, spunbond webs and meltblown webs, polyesters, polyolefins, cotton, nylon, silks, hydroknit, coform, nanofiber, fluff batting, foam, elastomerics, rubber, film laminates, combinations of these materials or other suitable materials.
- the textile web 23 may be a single web layer or a multilayer laminate in which one or more layers of the laminate are suitable for being dyed.
- spunbond refers to small diameter fibers which are formed by extruding molten thermoplastic material as filaments from a plurality of fine, usually circular capillaries of a spinneret with the diameter of the extruded filaments then being rapidly reduced as by, for example, in U.S. Pat. No. 4,340,563 to Appel et al., and U.S. Pat. No. 3,692,618 to Dorschner et al., U.S. Pat. No. 3,802,817 to Matsuki et al., U.S. Pat. Nos. 3,338,992 and 3,341,394 to Kinney, U.S. Pat. No. 3,502,763 to Hartman, and U.S. Pat.
- Spunbond fibers are generally not tacky when they are deposited onto a collecting surface. Spunbond fibers are generally continuous and have average diameters (from a sample of at least 10) larger than 7 microns, more particularly, between about 10 and 20 microns.
- meltblown refers to fibers formed by extruding a molten thermoplastic material through a plurality of fine, usually circular, die capillaries as molten threads or filaments into converging high velocity, usually hot, gas (e.g. air) streams which attenuate the filaments of molten thermoplastic material to reduce their diameter, which may be to microfiber diameter. Thereafter, the meltblown fibers are carried by the high velocity gas stream and are deposited on a collecting surface to form a web of randomly dispersed meltblown fibers.
- gas e.g. air
- Laminates of spunbond and meltblown fibers may be made, for example, by sequentially depositing onto a moving forming belt first a spunbond web layer, then a meltblown web layer and last another spunbond web layer and then bonding the layers together. Alternatively, the web layers may be made individually, collected in rolls, and combined in a separate bonding step. Such laminates usually have a basis weight of from about 0.1 to 12 osy (6 to 400 gsm), or more particularly from about 0.75 to about 3 osy.
- the textile web 23 is sufficiently open or porous so that dye applied to the web may migrate throughout the thickness of the web.
- the “porosity” of the textile web 23 is a measurement of the void space within the textile and is measured for a particular web specimen in the following manner.
- a web specimen For a given length (in centimeters) and width (in centimeters) of a web specimen (e.g., over which the web is generally homogeneous and, as such, has a uniform specific gravity), the specimen is weighed (in grams) by a suitable balance and the thickness (in centimeters) is measured using a suitable device, such as a VIR Electronic Thickness Tester, Model Number 89-1-AB commercially available from Thwing-Albert Instrument Company of Philadelphia, Pa., U.S.A. A total volume (in cubic centimeters) of the web specimen is determined as length ⁇ width ⁇ thickness.
- a material volume (in cubic centimeters) of the web specimen i.e., the volume taken up just by the material in the web specimen
- the porosity (in percent) of the web specimen is then determined as ((total volume ⁇ material volume)/total volume) ⁇ 100.
- the textile web 23 has a porosity of at least about 10 percent, and more suitably at least about 20 percent.
- the porosity as determined by the Porosity Test may be at least about 50 and in others the porosity may be at least about 75. More suitably, the porosity is in the range of about 10 percent to about 90 percent, and more suitably in the range of about 20 percent to about 90 percent.
- suitable textile webs include a cotton fabric commercially available from Springs Global of Ft. Mill, S.C., U.S.A. as Spring Global Muslin CPG W/O-SKU 743006050371 (having a basis weight of about 105 grams/square meter (gsm)); a polyester fabric commercially available from John Boyle & Company of Statesville, N.C., U.S.A. as Main Street Fabrics—European Fashion PP—SKU 1713874 (having a basis weight of about 61 gsm); and a spunbond non-woven web commercially available from Pegas Nonwovens S.R.O.
- one unsuitable web material is paper, such as ink jet paper, and in particular ink jet paper commercially available as RSA Premium Inkjet Paper IJC2436300—24 pound (having a basis weight of about 92.4 gsm).
- the following table provides the porosity for each of these web materials, as determined by using the above measurement technique on four 7.5 cm ⁇ 7.5 cm web specimens for each material and averaging the data.
- the dyeing apparatus 21 suitably comprises a dye applicating device, schematically and generally indicated at 25 , operable to apply dye to at least one of the faces 24 a , 24 b of the textile web 23 .
- the dye applicating device is particularly operable to apply dye to only one face 24 a of the textile web. It is understood, however, that the applicating device may be operable to apply dye only to the opposite face 24 b of the textile web 23 , or to both faces of the web. It is also contemplated that more than one applicating device may be used (e.g., one corresponding to each face 24 a , 24 b of the textile web 23 ) to apply ink to both faces of the textile web either concurrently or sequentially.
- dye refers to a substance that imparts more or less permanent color to other materials, such as to the textile web 23 .
- Suitable dyes include, without limitation, inks, lakes (also often referred to as color lakes), dyestuffs (for example but not limited to acid dyes, azoic dyes, basic dyes, direct dyes, disperse dyes, food, drug and cosmetic dyes, ingrain dyes, leather dyes, mordant dyes, natural dyes, reactive dyes, solvent dyes sulfur dyes and vat dyes), pigments (organic and inorganic) and other colorants (for example but not limited to fluorescent brighteners, developers, oxidation bases).
- inks also often referred to as color lakes
- dyestuffs for example but not limited to acid dyes, azoic dyes, basic dyes, direct dyes, disperse dyes, food, drug and cosmetic dyes, ingrain dyes, leather dyes, mordant dyes, natural dyes, reactive dyes, solvent dyes sulfur dye
- the dye suitably has a viscosity in the range of about 2 to about 100 centipoises, more suitably in the range of about 2 to about 20 centipoises, and even more suitably in the range of about 2 to about 10 centipoises to facilitate flow of the dye into and throughout the web.
- the dye is of a composition that provides an enhanced absorption of microwave energy, such as by having a relatively high dielectric loss factor.
- the “dielectric loss factor” is a measure of the receptivity of a material to high-frequency energy.
- the measured value of ⁇ ′ is most often referred to as the dielectric constant, while the measured value of ⁇ ′′ is denoted as the dielectric loss factor.
- dielectric loss factor is measured at a frequency of either 915 MHz or 2,450 MHz (and at room temperature, such as about 25 degrees Celsius).
- one suitable measuring system can include an HP8720D Dielectric Probe, and a model HP8714C Network Analyzer, both available from Agilent Technologies of Brookfield, Wis., U.S.A. Substantially equivalent devices may also be employed.
- ⁇ ′′ is always positive, and a value of less than zero is occasionally observed when ⁇ ′ is near zero due to the measurement error of the analyzer.
- the dye has a dielectric loss factor at 915 MHz and 25 degrees Celsius of at least about 10, more suitably at least about 50, and even more suitably at least about 100,
- the dielectric loss factor of water under the same conditions is about 1.2.
- the dye has a dielectric loss factor at 2,450 MHz and 25 degrees Celsius of at least about 25, more suitably at least about 50, and even more suitably at least about 100. Water has a dielectric loss factor of about 12 under these same conditions.
- the dye may include additives or other materials to enhance the affinity of the dye to microwave energy.
- additives and materials include, without limitation, various mixed valent oxides, such as magnetite, nickel oxide and the like; carbon, carbon black and graphite; sulfide semiconductors, such as FeS 2 and CuFeS 2 ; silicon carbide; various metal powders such as powders of aluminum, iron and the like; various hydrated salts and other salts, such as calcium chloride dihydrate; diatomaceous earth; aliphatic polyesters (e.g., polybutylene succinate and poly(butylene succinate-co-adipate), polymers and copolymers of polylactic acid and polyethylene glycols; various hygroscopic or water absorbing materials or more generally polymers or copolymers with many sites of —OH groups.
- various mixed valent oxides such as magnetite, nickel oxide and the like
- sulfide semiconductors such as FeS 2 and CuFeS 2
- Examples of other suitable inorganic microwave absorbers include, without limitation, aluminum hydroxide, zinc oxide, barium titanate.
- suitable organic microwave absorbers include, without limitation, polymers containing ester, aldehyde ketone, isocyanate, phenol, nitrile, carboxyl, vinylidene chloride, ethylene oxide, methylene oxide, epoxy, amine groups, polypyrroles, polyanilines, polyalkylthiophenes. Mixtures of the above are also suitable for use in the dye applied to be applied to the textile web.
- the selective additive or material may be ionic or dipolar, such that the applied energy field can activate the molecule.
- Non-limiting examples of suitable dyes that have the desired dielectric loss factor are inks commercially available from Yuhan-Kimberly of South Korea under the following designations: 67581-11005579 NanoColorant Cyan 220 ml; 67582-11005580 NanoColorant Magenta 220 ml; 67583-11005581 NanoColorant Yellow 220 ml; 67584-11005582 NanoColorant Black 220 ml; 67587-11005585 NanoColorant Red 220 ml; 67588-11005586 NanoColorant Orange 220 ml; 67591-11005589 NanoColorant Gray 220 ml; 67626-11006045 NanoColorant Violet 220 ml.
- the dye applicating device 25 may comprise any suitable device used for applying dye to textile webs 23 other than by saturating the entire web (e.g., by immersing the textile web in a bath of dye solution to saturate the web), whether the dye is pre-metered (e.g., in which little or no excess dye is applied to the web upon initial application of the dye) or post-metered (i.e., an excess amount of dye is applied to the textile web and subsequently removed). It is understood that the dye itself may be applied to the textile web 23 or the dye may be used in a dye solution that is applied to the web.
- suitable pre-metered dye applicating devices 25 include, without limitation, devices for carrying out the following known applicating techniques:
- Direct gravure The dye is in small cells in a gravure roll.
- the textile web 23 comes into direct contact with the gravure roll and the dye in the cells is transferred onto the textile web.
- Offset gravure with reverse roll transfer Similar to the direct gravure technique except the gravure roll transfers the coating material to a second roll. This second roll then comes into contact with the textile web 23 to transfer dye onto the textile web.
- Slide (Cascade) coating A technique similar to curtain coating except the multiple layers of dye come into direct contact with the textile web 23 upon exiting the coating head. There is no open gap between the coating head and the textile web 23 .
- Forward and reverse roll coating also known as transfer roll coating: This consists of a stack of rolls which transfers the dye from one roll to the next for metering purposes. The final roll comes into contact with the textile web 23 . The moving direction of the textile web 23 and the rotation of the final roll determine whether the process is a forward process or a reverse process.
- Extrusion coating This technique is similar to the slot die technique except that the dye is a solid at room temperature. The dye is heated to melting temperature in the print head and metered as a liquid through the slot directly onto the textile web 23 . Upon cooling, the dye becomes a solid again.
- Rotary screen The dye is pumped into a roll which has a screen surface. A blade inside the roll forces the dye out through the screen for transfer onto the textile.
- Spray nozzle application The dye is forced through a spray nozzle directly onto the textile web 23 .
- the desired amount (pre-metered) of dye can be applied, or the textile web 23 may be saturated by the spraying nozzle and then the excess dye can be squeezed out (post-metered) by passing the textile web through a nip roller.
- Flexographic printing The dye is transferred onto a raised patterned surface of a roll. This patterned roll then contacts the textile web 23 to transfer the dye onto the textile.
- the dye is loaded in an ink jet cartridge and jetted onto the textile web 23 as the textile web passes under the ink jet head.
- suitable post-metering dye applicating devices for applying the dye to the textile web 23 include without limitation devices that operate according to the following known applicating techniques:
- Rod coating The dye is applied to the surface of the textile web 23 and excess dye is removed by a rod.
- a Mayer rod is the prevalent device for metering off the excess dye.
- Air knife coating The dye is applied to the surface of the textile web 23 and excess dye is removed by blowing it off using a stream of high pressure air.
- Knife coating The dye is applied to the surface of the textile web 23 and excess dye is removed by a head in the form of a knife.
- Blade coating The dye is applied to the surface of the textile web 23 and excess dye is removed by a head in the form of a flat blade.
- Fountain coating The dye is applied to the textile web 23 by a flooded fountain head and excess material is removed by a blade.
- Brush application The dye is applied to the textile web 23 by a brush and excess material is regulated by the movement of the brush across the surface of the web.
- the textile web is suitably delivered to an ultrasonic vibration system, generally indicated at 61 , having a contact surface 63 ( FIG. 2 ) over which the dyed web 23 passes in contact with the vibration system such that the vibration system imparts ultrasonic energy to the web.
- the ultrasonic vibration system 61 has a terminal end 65 , at least a portion of which defines the contact surface 63 contacted by the textile web 23
- the textile web 23 is suitably in the form of a generally continuous web, and more particularly a rolled web wherein the web is unrolled during processing and then rolled up following processing for transport to other post-processing stations.
- the ultrasonic vibration system 61 may be suitably mounted on a support frame 67 ( FIG. 2 ) intermediate an unwind roll 45 and a wind roll 49 (the unwind roll and wind roll also being mounted on suitable respective support frames (not shown)).
- the textile web 23 may alternatively be in the form of one or more discrete webs during treatment without departing from the scope of this invention.
- the dye applicating device 25 is located between the unwind roll 45 and the ultrasonic vibration system to apply dye to the one face 24 a of the textile web before the web advances to the vibration system. It is understood, however, that dye may be applied to the textile web 23 other than immediately upstream of the ultrasonic vibration system, such as at a station that is entirely separate from that at which the web is ultrasonically treated, without departing from the scope of this invention.
- the textile web 23 is suitably advanced (i.e., moved), such as by a suitable drive mechanism 51 ( FIG. 1 ) at the wind roll 49 , in a machine direction (indicated by the direction arrows in FIGS. 1 and 2 ) from the unwind roll past the dye applicating device 25 and the ultrasonic vibration system 61 to the wind roll.
- machine direction refers generally to the direction in which the textile web 23 is moved (e.g., longitudinally of the web in the illustrated embodiment) during processing.
- the term “cross-machine direction” is used herein to refer to the direction normal to the machine direction of the textile web 23 and generally in the plane of the web (e.g., widthwise of the web in the illustrated embodiment).
- the textile web 23 suitably advances toward the contact surface 63 (e.g., at the terminal end 65 of the ultrasonic vibration system 61 ) at an approach angle A 1 relative to a longitudinal axis X of the ultrasonic vibration system 61 , and after passing over the contact surface the web further advances away from the contact surface at a departure angle B 1 relative to the longitudinal axis X of the ultrasonic vibration system.
- the approach angle A 1 of the textile web 23 in one embodiment, is suitably in the range of about 1 to about 89 degrees, more suitably in the range of about 1 to about 45 degrees, and even more suitably in the range of about 10 to about 45 degrees.
- the departure angle B 1 of the web 23 is suitably approximately equal to the approach angle A 1 as illustrated in FIG. 2 . However, it is understood that the departure angle B 1 may be greater than or less than the approach angle A 1 without departing from the scope of this invention.
- the ultrasonic vibration system 61 is adjustably mounted on the support frame 67 for movement relative to the support frame (e.g., vertically in the embodiment illustrated in FIG. 2 ) and the unwind and wind rolls 45 , 49 to permit adjustment of the contact surface 63 of the ultrasonic vibration system relative to the web 23 to be treated.
- the ultrasonic vibration system 61 is selectively positionable between a first position (not shown) at which the approach angle A 1 and departure angle B 1 of the web is substantially zero or at least relatively small, and a second position illustrated in FIGS. 1 and 2 . In the first position of the vibration system 61 , the contact surface 63 of the vibration system may but need not necessarily be in contact with the textile web 23 .
- the terminal end 65 (and hence the contact surface 63 ) of the vibration system is substantially spaced from the first position and is in contact with the textile web 23 . Movement of the vibration system 61 from its first position to its second position in this embodiment urges the web 23 to along with the contact surface 63 so as to form the approach and departure angles A 1 , B 1 of the web.
- Moving the ultrasonic vibration system 61 from its first position to its second position in this manner may also serve to tension, or increase the tension in, the textile web 23 at least along the segment of the web that lies against the contact surface 63 of the vibration system while the web is held between the unwind roll 45 and the wind roll 49 .
- the textile web 23 may be held in uniform tension along its width (i.e., its cross-machine direction dimension), at least at that segment of the web that is contacted by the contact surface 63 of the ultrasonic vibration system 61 , in the range of about 0.025 pounds/inch of web width to about 3 pounds/inch of web width, and more suitably in the range of about 0.1 to about 1.25 pounds/inch of web width.
- the ultrasonic vibration system 61 is particularly located relative to the textile web 23 so that the contact surface 63 of the vibration system contacts the face 24 b of the web opposite the face 24 a to which the dye was initially applied. While in the illustrated embodiment the dye is applied to the one face 24 a of the textile web while the ultrasonic vibration system 61 contacts the opposite face 24 b , it is understood that the dye may instead be applied to the face 24 b while the ultrasonic vibration system contacts the opposite face 24 a.
- the ultrasonic vibration system 61 in one embodiment suitably comprises an ultrasonic horn, generally indicated at 71 , having a terminal end 73 that in the illustrated embodiment defines the terminal end 65 of the vibration system, and more particularly defines the contact surface 63 of the vibration system.
- the ultrasonic horn 71 of FIG. 3 is suitably configured as what is referred to herein as an ultrasonic bar (also sometimes referred to as a blade horn) in which the terminal end 73 of the horn is generally elongate, e.g., along its width w.
- the ultrasonic horn 71 in one embodiment is suitably of unitary construction such that the contact surface 63 defined by the terminal end 73 of the horn is continuous across the entire width w of the horn.
- the terminal end 73 of the horn 71 is suitably configured so that the contact surface 63 defined by the terminal end of the ultrasonic horn is generally flat and rectangular. It is understood, however, that the horn 71 may be configured so that the contact surface 63 defined by the terminal end 73 of the horn is more rounded or other than flat without departing from the scope of this invention.
- the ultrasonic horn 71 is suitably oriented relative to the moving textile web 23 so that the terminal end 73 of the horn extends in the cross-machine direction across the width of the web.
- the width w of the horn 71 at least at its terminal end 73 , is suitably sized approximately equal to and may even be greater than the width of the web.
- a thickness t ( FIG. 4 ) of the ultrasonic horn 71 is suitably greater at a connection end 75 of the horn (i.e., the longitudinal end of the horn opposite the terminal end 73 thereof) than at the terminal end of the horn to facilitate increased vibratory displacement of the terminal end of the horn during ultrasonic vibration.
- the ultrasonic horn 71 of the illustrated embodiment of FIGS. 3 and 4 has a thickness t at its connection end 75 of approximately 1.5 inches (3.81 cm) while its thickness at the terminal end 73 is approximately 0.5 inches (1.27 cm).
- the illustrated horn 71 also has a width w of about 6.0 inches (15.24 cm) and a length (e.g., height in the illustrated embodiment) of about 5.5 inches (13.97 cm).
- the thickness t of the illustrated ultrasonic horn 71 tapers inward as the horn extends longitudinally toward the terminal end 73 . It is understood, however, that the horn 71 may be configured other than as illustrated in FIGS. 3 and 4 and remain within the scope of this invention as long as the horn defines a contact surface 63 of the vibration system 61 suitable for contacting the textile web 23 to impart ultrasonic energy to the web.
- the ultrasonic vibration system 61 of the illustrated embodiment is suitably in the form of what is commonly referred to as a stack, comprising the ultrasonic horn, a booster 77 coaxially aligned (e.g., longitudinally) with and connected at one end to the ultrasonic horn 71 at the connection end 75 of the horn, and a converter 79 (also sometimes referred to as a transducer) coaxially aligned with and connected to the opposite end of the booster.
- the converter 79 is in electrical communication with a power source or generator (not shown) to receive electrical energy from the power source and convert the electrical energy to high frequency mechanical vibration.
- a power source or generator not shown
- one suitable type of converter 79 relies on piezoelectric material to convert the electrical energy to mechanical vibration.
- the booster 77 is configured to amplify (although it may instead be configured to reduce, if desired) the amplitude of the mechanical vibration imparted by the converter 79 .
- the amplified vibration is then imparted to the ultrasonic horn 71 .
- the booster 77 may instead be omitted from the ultrasonic vibration system 61 without departing from the scope of this invention. Construction and operation of a suitable power source, converter 79 and booster 77 are known to those skilled in the art and need not be further described herein.
- the ultrasonic vibration system 61 is operable (e.g., by the power source) at a frequency in the range of about 15 kHz to about 100 kHz, more suitably in the range of about 15 kHz to about 60 kHz, and even more suitably in the range of about 20 kHz to about 40 kHz.
- the amplitude (e.g., displacement) of the horn 71 , and more particularly the terminal end 73 thereof, upon ultrasonic vibration may be varied by adjusting the input power of the power source, with the amplitude generally increasing with increased input power.
- the input power is in the range of about 0.1 kW to about 4 kW, more suitably in the range of about 0.5 kW to about 2 kW and more suitably about 1 kW.
- a rolled textile web 23 is initially unwound from an unwind roll 45 , e.g., by the wind roll 49 and drive mechanism 51 , with the web passing the dye applicator 25 and the ultrasonic vibration system 61 .
- the ultrasonic vibration system 61 is in its second position (as illustrated in FIGS. 1 and 2 ) with the terminal end 65 (and hence the contact surface 63 ) of the vibration system displaced along with the textile web to the desired approach and departure angles A 1 , B 1 of the textile web.
- the textile web 23 may also be tensioned in the second position of the vibration system 61 and/or by further winding the wind roll 49 , by back winding the unwind roll 45 , by both, or by other suitable tensioning structure and/or techniques.
- the textile web 23 is suitably configured in what is referred to herein as a generally open configuration as the web passes over the contact surface 63 of the ultrasonic vibration system 61 .
- the term “open configuration” is intended to mean that the textile web 23 is generally flat or otherwise unfolded, ungathered and untwisted, at least at the segment of the web in contact with the contact surface 63 of the vibration system 61 .
- a feed rate of the web 23 i.e., the rate at which the web moves in the machine direction over the contact surface 63 of the vibration system 61
- the width of the contact surface i.e., the thickness t of the terminal end 73 of the horn 71 in the illustrated embodiment, or where the contact surface is not flat or planar, the total length of the contact surface from one side of the terminal end of the horn to the opposite side thereof
- the dwell time of the web on the contact surface of the vibration system determine what is referred to herein as the dwell time of the web on the contact surface of the vibration system.
- the term “dwell time” refers herein to the length of time that a segment of the textile web 23 is in contact with the contact surface 63 of the vibration system 61 as the web is drawn over the contact surface (e.g., the width of the contact surface divided by the feed rate of the web).
- the feed rate of the web 23 across the contact surface 63 of the vibration system 61 is in the range of about 0.5 feet/minute to about 2,000 feet/minute, more suitably in the range of about 1 feet/minute to about 100 feet/minute and even more suitably in the range of about 2 feet/minute to about 10 feet/minute. It is understood, however, that the feed rate may be other than as set forth above without departing from the scope of this invention.
- the dwell time is suitably in the range of about 0.1 second to about 60 seconds, more suitably in the range of about 1 second to about 10 seconds, and even more suitably in the range of about 2 seconds to about 5 seconds. It is understood, however, that the dwell time may be other than as set forth above depending for example on the material from which the web 23 is made, the dye composition, the frequency and vibratory amplitude of the horn 71 of the vibration system 61 and/or other factors, without departing from the scope of this invention.
- the ultrasonic vibration system 61 is operated by the power source to ultrasonically vibrate the ultrasonic horn 71 as the opposite face 24 b of the textile web 23 is drawn over the contact surface 63 of the vibration system.
- the horn 71 imparts ultrasonic energy to the segment of the textile web 23 that is in contact with the contact surface 63 defined by the terminal end 73 of the horn. Imparting ultrasonic energy to the opposite face 24 b of the textile web 23 facilitates the migration of dye from the one face 24 a of the web into and through the web to the opposite face 24 b of the web.
- the face 24 a i.e., the face on which the dye is applied
- the face 24 a of the textile web 23 may oppose and contact the contact surface 63 of the vibration system 61 without departing from the scope of this invention.
- a second ultrasonic vibration system (not shown) may be used to apply ultrasonic energy to the face 24 a of the web, either concurrently or sequentially with the first ultrasonic vibration system 61 applying ultrasonic energy to the opposite face 24 b of the web.
- the textile web is further advanced to, and through, a microwave system, generally indicated at 101 operable to direct high frequency, electromagnetic radiant energy, and more suitably microwave energy, to the dyed textile web 23 to facilitate expedited and enhanced binding of the dye to the web.
- the microwave system 101 may employ energy having a frequency in the range of about 1 MHz to about 5,800 MHz, and more suitably in the range of about 900 MHz to about 5,800 MHz. In one embodiment the frequency is more suitably about 915 MHz. In another embodiment the frequency is more suitably about 2,450 MHz.
- the microwave system 101 suitably comprises a microwave generator 103 operable to produce the desired amount of microwave energy, a wave-guide 105 and an application chamber 107 through which the textile web 23 passes while moving in the machine direction (indicated by the direction arrow in FIG. 5 ).
- the input power of the microwave generator is suitably in the range of about 1,500 watts to about 6,000 watts. It is understood, however, that in other embodiments the power input may be substantially greater, such as about 75,000 watts or more, without departing from the scope of this invention.
- the application chamber 107 comprises a housing 126 operatively connected to the wave-guide 105 and having end walls 128 , an entrance opening (not shown in FIG. 6 but similar to an entrance opening 102 shown in FIG. 7 ) for receiving the textile web 23 into the application chamber, and an outlet opening 104 through which the textile web exits the application chamber for subsequent movement to the wind roll 49 .
- the entrance and exit openings 102 , 104 can be suitably sized and configured slightly larger than the textile web 23 so as to allow the textile web, in its open configuration, to pass through the entrance and exit while inhibiting an excessive leakage of energy from the application chamber.
- the wave-guide 105 and application chamber 107 may be constructed from suitable non-ferrous, electrically-conductive materials, such as aluminum, copper, brass, bronze, gold and silver, as well as combinations thereof.
- the application chamber 107 in one particularly suitable embodiment is a tuned chamber within which the microwave energy can produce an operative standing wave.
- the application chamber 107 may be configured to be a resonant chamber. Examples of suitable arrangements for a resonant application chamber 107 are described in U.S. Pat. No. 5,536,921 entitled SYSTEM FOR APPLYING MICROWAVE ENERGY 1 N SHEET-LIKE MATERIAL by Hedrick et al., issued Jul. 16, 1996; and in U.S. Pat. No. 5,916,203 entitled COMPOSITE MATERIAL WITH ELASTICIZED PORTIONS AND A METHOD OF MAKING THE SAME by Brandon et al, issued Jun. 29, 1999. The entire disclosures of these documents are incorporated herein by reference in a manner that is consistent herewith.
- the effectiveness of the application chamber 107 can be determined by measuring the power that is reflected back from the impedance load provided by the combination of the application chamber 107 and the target material (e.g. the textile web 23 ) in the application chamber.
- the application chamber 107 may be configured to provide a reflected power which is not more than a maximum of about 50% of the power that is delivered to the impedance load.
- the reflected power can alternatively be not more than about 20% of the delivered power, and can optionally be not more than about 10% of the delivered power. In other embodiments, however, the reflected power may be substantially zero.
- the reflected power may be about 1%, or less, of the delivered power, and can optionally be about 5%, or less, of the delivered power. If the reflected power is too high, inadequate levels of energy are being absorbed by the dyed textile web 23 and the power being directed into the dyed web is being inefficiently utilized.
- the application chamber 107 may also be configured to provide a Q-factor of at least a minimum of about 200.
- the Q-factor can alternatively be at least about 5,000, and can optionally be at least about 10,000. In other embodiments, the Q-factor can up to about 20,000, or more. If the Q-factor is too low, inadequate electrical field strengths are provided to the dyed textile web.
- the Q-factor can be determined by the following formula (which may be found in the book entitled Industrial Microwave Heating by R. C. Metaxas and R. J. Meredith, published by Peter Peregrinus, Limited, located in London, England, copyright 1983, reprinted 1993):
- f o intended resonant frequency (typically the frequency produced by the high-frequency generator)
- ⁇ f frequency separation between the half-power points.
- the power absorbed by the dyed textile web 23 is deemed to be the power delivered into the application chamber 107 to the web, minus the reflected power returned from the application chamber.
- the peak-power is the power absorbed by the dyed textile web 23 when the power is provided at the intended resonant frequency, f o .
- the half-power points are the frequencies at which the power absorbed by the dyed textile web 23 falls to one-half of the peak-power.
- a suitable measuring system can include an HP8720D Dielectric Probe, and a model HP8714C Network Analyzer, both available from Agilent Technologies, a business having offices located at Brookfield, Wis., U.S.A.
- a suitable procedure for determining the Q-factor is described in the User's Manual dated 1998, part number 08712-90056. Substantially equivalent devices and procedures may also be employed.
- the application chamber 107 may be configured for selective tuning to operatively “match” the load impedance produced by the presence of the target material (e.g. the dyed textile web 23 ) in the application chamber.
- the tuning of the application chamber 107 can, for example, be provided by any of the techniques that are useful for “tuning” microwave devices. Such techniques can include configuring the application chamber 107 to have a selectively variable geometry, changing the size and/or shape of a wave-guide aperture, employing adjustable impedance components (e.g. stub tuners), employing a split-shell movement of the application chamber, employing a variable frequency energy source that can be adjusted to change the frequency of the energy delivered to the application chamber, or employing like techniques, as well as employing combinations thereof.
- the variable geometry of the application chamber 107 can, for example, be provided by a selected moving of either or both of the end walls 128 to adjust the distance therebetween.
- the tuning feature may comprise an aperture plate 130 having a selectively sized aperture 132 or other opening.
- the aperture plate 130 may be positioned at or operatively proximate the location at which the wave-guide 105 joins the application chamber housing 126 .
- the aperture 132 can be suitably configured and sized to adjust the waveform and/or wavelength of the energy being directed into the application chamber 107 .
- a stub tuner 134 may be operatively connected to the wave-guide 105 .
- the wave-guide 105 can direct the microwave energy into the chamber 107 at a location that is interposed between the two end walls 128 .
- Either or both of the end walls 128 may be movable to provide selectively positionable end-caps, and either or both of the end walls may include a variable impedance device, such as provided by the representatively shown stub tuner 134 .
- one or more stub tuners 134 may be positioned at other operative locations in the application chamber 107 .
- the wave-guide 105 may be arranged to deliver the microwave energy into one end of the application chamber 107 . Additionally, the end wall 128 at the opposite end of the chamber 107 may be selectively movable to adjust the distance between the aperture plate 130 and the end wall 128 .
- the application chamber 107 comprises a housing 126 that is non-rectilinear.
- the housing 126 may be divided to provide operatively movable split portions 126 a and 126 b .
- the chamber split-portions 126 a , 126 b can be selectively postionable to adjust the size and shape of the application chamber 107 .
- either or both of the end walls 128 are movable to provide selectively positionable end-caps, and either or both of the end walls may include a variable impedance device, such as provided by the representatively shown stub tuner 134 .
- one or more stub tuners 134 may be positioned at other operative locations in the chamber 107 .
- the appointed tuning components are adjusted and varied in a conventional, iterative manner to maximize the power into the load (e.g. into the dyed textile web), and to minimize the reflected power.
- the tuning components can be systematically varied to maximize the power into the textile web 23 and minimize the reflected power.
- the reflected power can be detected with a conventional power sensor, and can be displayed on a conventional power meter.
- the reflected power may, for example, be detected at the location of an isolator.
- the isolator is a conventional, commercially available device which is employed to protect a magnetron from reflected energy. Typically, the isolator is placed between the magnetron and the wave-guide 105 .
- Suitable power sensors and power meters are available from commercial vendors.
- a suitable power sensor can be provided by a HP E4412 CW power sensor which is available from Agilent Technologies of Brookfield, Wis., U.S.A.
- a suitable power meter can be provided by a HP E4419B power meter, also available from Agilent Technologies.
- a properly sized aperture plate 130 and a properly sized aperture 132 can help reduce the amount of variable tuning adjustments needed to accommodate a continuous product.
- the variable impedance device e.g. stub tuner 134
- the variable-position end walls 128 or end caps can allow for easier adjustments to accommodate a varying load.
- the split-housing 126 a , 126 b (e.g., as illustrated in FIG. 9 ) configuration of the application chamber 107 can help accommodate a web 23 having a varying thickness.
- the microwave system 101 may comprise two or more application chamber 107 (e.g. 107 a + 107 b + . . . ).
- the plurality of activation chambers 107 can, for example, be arranged in the representatively shown serial array.
- the chamber may suitably have a machine-directional (indicated by the direction arrow in the various embodiments) length (e.g., from the entrance 102 to the exit 104 , along which the web is exposed to the microwave energy in the chamber) of at least about 4 cm.
- the chamber 107 length can be up to a maximum of about 800 cm, or more.
- the chamber 107 length can alternatively be up to about 400 cm, and can optionally be up to about 200 cm.
- the chamber 107 length is suitably about 4.4 cm. for an operating frequency of about 5,800 MHz applicator, about 8.9 cm. for an operating frequency of about 2,450 MHz. and about 25 cm. for an operating frequency of about 915 MHz for tuned circular cavities.
- Such lengths may be much longer for multimode microwave systems.
- the total sum of the machine-directional lengths provided by the plurality of chambers may be at least about 10 cm and proportionally longer for lower frequencies.
- the total of the chamber 107 lengths can be up to a maximum of about 3000 cm, or more.
- the total of the chamber 107 lengths can alternatively be up to about 2000 cm, and can optionally be up to about 1000 cm.
- the total residence time within the application chamber 107 or chambers can provide a distinctively efficient dwell time.
- dwell time in reference to the microwave system 101 refers to the amount of time that a particular portion of the dyed textile web 23 spends within the application chamber 107 , e.g., in moving from the entrance opening 102 to the exit opening 104 of the chamber.
- the dwell time is suitably at least about 0.0002 sec.
- the dwell time can alternatively be at least about 0.005 sec, and can optionally be at least about 0.01 sec.
- the dwell time can be up to a maximum of about 3 sec, more suitably up to about 2 sec, and optionally up to about 1.5 sec.
- the web is moved (e.g., drawn, in the illustrated embodiment) through the application chamber 107 of the microwave system 101 .
- the microwave system 101 is operated to direct microwave energy into the application chamber 107 for absorption by the dye (e.g., which in one embodiment suitably has an affinity for, or couples with, the microwave energy).
- the dye is thus heated rapidly, thereby substantially speeding up the rate at which at the dye becomes bound to the textile web (e.g., as opposed to conventional heating methods such as curing in an oven).
- the web is subsequently moved downstream of the microwave system 101 for subsequent post-processing, such as washing to remove any unbound dye, and other suitable post-processing steps.
- the textile web 23 is thus first subjected to ultrasonic energy to facilitate distribution of the dye through the web, and then subjected to microwave energy to facilitate enhanced (and expedited) binding of the dye into the web. While this combination of processes has been found to result in better binding of the dye into the web than omitting the ultrasonic vibration step and just applying the microwave energy to the web, it is understood that that in other embodiments the web may be subjected to the microwave energy after the dye application, thereby omitting the ultrasonic vibration step, without departing from the scope of this invention.
- dye may be initially applied throughout the web by saturating the web (e.g., by dipping the web in a dye bath) or by other suitable dyeing techniques that do not involve applying ultrasonic energy directly to the web.
- Color is commonly measured by using a spectrodensitometer, which measures reflected light and provides calorimetric data as will be described hereinafter.
- the light which is reflected in the visual range i.e., having a wavelength of 400 nm to 700 nm
- An example of such a device is the X-Rite 938 reflection spectrodensitometer available from X-Rite, Incorporated of Grandville, Mich.
- a suitable program for analyzing the data generated by this instrument is the X-Rite QA Master 2000 software available from X-Rite, Incorporated.
- Color can be described generally in terms of three elements, hue, chroma (or saturation) and lightness (sometimes called value or brightness).
- Hue (h) is the perceived attribute of a specific color that fixes the color's spectrum position and classifies it as blue, green, red or yellow.
- Chroma describes the vividness or dullness of a color. It is a measurement of how close the color is to either gray (a mixture of all colors) or to the pure hue.
- Chroma (C) can be broken into two measurements: a—the measurement of the redness or greenness of the color; and b—the measurement of the yellowness or blueness of the color.
- Lightness is the luminous intensity of a color, or how close the color is to white or black and ranges in value from 0 (black) to 100 (white). All of these attributes can be determined using the aforementioned spectrodensitometer, and analyzed with the QA Master 2000 software.
- a black ink, commercially available from Yuhan-Kimberly of South Korea under the designation 67584 11005582 NanoColorant Black 220 ml was used as the ink solution.
- the ink applicator was an electrometric air atomization spray applicator nozzle commercially available as Spraymation Electromatic Air Atomized Applicator Head, Model 79200 from Spraymation of Fort Lauderdale, Fla.
- the ink was pumped into this nozzle using a Masterflex L/S-Computerized drive pump, Model number 7550-10 available from Cole Parmer Instrument Company.
- the pump was manufactured by Barnant Company of Barrington, Ill.
- the applicator was operated at a rate of about 35 grams/square meter.
- the various components that were used are commercially available from Dukane Ultrasonics of St. Charles, Ill., U.S.A as the following model numbers: power supply—Model 20A3000; converter—Model 110-3123; booster—Model 2179T; and horn Model 11608A.
- the horn had a thickness at its connection end of approximately 1.5 inches (3.81 cm), a thickness at its terminal end of approximately 0.5 inches (1.27 cm), a width of about 6.0 inches (15.24 cm) and a length (e.g., height in the illustrated embodiment) of about 5.5 inches (13.97 cm).
- the contact surface defined by the terminal end of the horn was flat, resulting in a contact surface length (e.g., approximately equal to the thickness of the horn at its terminal end) of about 0.5 inches (1.27 cm).
- the microwave system used was similar to that described above and illustrated in FIG. 5 and operated by a power source commercially available as National Electronics Model GEN6KW480 from National Electronics of LaFox, Ill. and capable of delivering up to 6 KW of power.
- the resonant cavity of the microwave system had a depth (i.e., in the machine direction of movement of the web through the cavity) of about 3.5 inches (8.9 cm).
- the opposite face of the web i.e., the face that is opposite that on which the dye was sprayed—referred to further herein as the back face of the web
- the contact surface of the ultrasonic vibration system e.g., in direct contact therewith. This resulted in a dwell time of the web on the contact surface of the ultrasonic vibration system of about 0.63 seconds.
- a uniform tension of approximately one pound per inch of web width was applied to the web.
- the approach and departure angles of the web relative to the longitudinal axis of the ultrasonic vibration system were each about 20 degrees.
- the web was subsequently drawn through the resonant cavity of the microwave system and then to the wind roll.
- At least about 20 feet of the master roll of web material was run in accordance with each process to be tested. Once a particular process run was completed, a representative three foot sample of the dyed web was cut from the processed web and the L, a and b values of the sample was measured as described previously for both the front and back faces of the web. The web sample was then hand washed in a one gallon bath of detergent mixture comprised of 99.9% by volume of water and 0.1% by volume detergent (available from Procter and Gamble of Cincinnati, Ohio under the tradename Joy) to remove unbound dye from the web sample. The bath was intermittently dumped and refilled with a clean detergent solution until little or no dye washed out of the web sample. The L, a and b values for the front and back faces of the web were again measured after washing. Using the pre-washed color data as a reference, a “ ⁇ E” value was determined as follows:
- ⁇ E ( ⁇ L 2 + ⁇ a 2 + ⁇ b 2 ) 1/2 i.
- both the ultrasonic vibration system and the microwave system were turned off.
- the web sample cut from the dyed web was placed in an oven at 180 degrees Celsius for a period of three minutes prior to taking the pre-wash color data measurements.
- the ultrasonic vibration system was turned off while the microwave system was operated at 2,450 MHz and an absorbed power of 200 watts.
- the third web was processed with the ultrasonic vibration system operating at 20 kHZ and the microwave system operated at 2,450 kHZ and an absorbed power of 200 watts.
- the dye was a black dye so the nearer to zero the lightness L is, the more “black” the respective face of the web appears.
- the back face the face to which the dye solution was not applied
- the front face to which the dye was initially applied
- the dye solution did not distribute well through the web from the front face to the back face of the web.
- the specimen subjected only to the microwave energy In contrast, for the specimen subjected to ultrasonic vibration the dye was more adequately pulled through the web to the back face thereof, as indicated by the nearly equal lightness values for the front and back faces of the web.
- the ⁇ E value provides an indication of the effectiveness of the tested processes for binding the dye into the respective web specimens. That is, because the ⁇ E is based on the difference of the L, a and b values taken before and after washing, a positive ⁇ E means that dye was washed away by the washing process, thereby slightly fading or rendering less intense the appearance of the black dye.
- the ⁇ E was higher that it was for the control web specimen. Thus, subjecting the web only to microwave energy does not itself assure a better binding of the dye into the web.
Abstract
In a process for dyeing a textile web having a first face and a second face opposite the first face, dye is applied to the textile web and the web is then moved in an open configuration thereof over a contact surface of an ultrasonic vibration system with the textile web in direct contact with the contact surface of the ultrasonic vibration system. The ultrasonic vibration system is operated to impart ultrasonic energy to the textile web to facilitate the distribution of dye throughout the web. The web is then moved further in its open configuration through a microwave application chamber of a microwave system and the microwave system is operated to impart microwave energy to the web in the microwave application chamber to facilitate binding of the dye to the web.
Description
- This invention relates generally to processes for dyeing textile webs, and more particularly to a process for dyeing a textile web in which both ultrasonic energy and microwave energy is used to facilitate the dyeing process.
- The dyeing of textile webs is commonly achieved in one of two manners, one being immersing the textile web into a bath of dye solution so that the dye soaks into the textile web and the second being applying dye to (e.g., by spraying or coating) one or both faces of the textile web. Immersion (also commonly referred to as a dip-coating process) of the textile web requires a substantial amount of dye solution to be used to saturate the textile web. In addition, following saturation the textile web must be washed to remove a substantial amount of unbound dye from the web. While dip-coating results in good penetration of the dye throughout the entire textile web, it presents a relatively inefficient use of the dye solution and requires considerable post-processing of the web.
- Dye may instead be applied (such as by spraying or coating) to one or both faces of the textile web by any number of application techniques including, without limitation, ink jet systems, spray systems, gravure roll, slot die, rod coater, rotary screen curtain coater, air knife, brush and the like. Following the application of dye to the web, the web is often heated and/or steamed to promote binding of the dye to the textile web. The textile web is then washed, such as in a bath of water or other cleaning solution, to remove unbound and excess dye from the web.
- Applying dye to the textile web in this manner (e.g., as opposed to dip-coating) requires considerably less dye to be initially applied to the web, and thus reduces the time spent heating/steaming the web to facilitate binding of the dye to the web, and also reduces the amount of unbound dye that needs to be subsequently washed from the web. Such dyeing operations where the dye is applied to only one face of the textile generally use less dye, but run the associated risk that dye does not adequately penetrate into and through the web to the opposite face to provide even or uniform coloring of the web. While dyeing both faces of the textile web somewhat reduces this risk it also requires additional dye to be used, resulting in more unbound dye that must be subsequently removed from the web.
- Once the dye is applied to the web, it is also common to subject the dyed web to a drying and curing process, such as where the web is placed in an oven at a suitable temperature to dry the dye to thereby facilitate binding of the dye to the web. Where webs are dyed in a continuous, or line feed process, such a drying process often takes a relatively considerable amount of time compared to the desired speed at which the web is to be moved.
- There is a need, therefore, for a dyeing process that reduces the amount of dye that needs to be used in dyeing a textile web and facilitates improved penetration of the dye into and through the web and subsequent binding of the dye to the web.
- In one embodiment, a process for dyeing a textile web having a first face and a second face opposite the first face generally comprises applying dye to the textile web and then moving the web in an open configuration thereof over a contact surface of an ultrasonic vibration system with the textile web in direct contact with the contact surface of the ultrasonic vibration system. The ultrasonic vibration system is operated to impart ultrasonic energy to the textile web to facilitate the distribution of dye throughout the web. The web is then moved further in its open configuration through a microwave application chamber of a microwave system and the microwave system is operated to impart microwave energy to the web in the microwave application chamber to facilitate binding of the dye to the web.
- In another embodiment, a process for dyeing a textile web having a first face, a second face opposite the first face and a thickness from the first face to the second face generally comprises applying dye to the textile web throughout the thickness thereof. The web is then moved in an open configuration thereof through a microwave application chamber of a microwave system and the microwave system is operated to impart microwave energy to the web in the microwave application chamber to facilitate binding of the dye in the web.
-
FIG. 1 is a schematic of one embodiment of apparatus for dyeing a textile web according to one embodiment of a process for dyeing a textile web; -
FIG. 2 is a side elevation of an ultrasonic vibration system and support frame of the apparatus ofFIG. 1 ; -
FIG. 3 is a front elevation of the ultrasonic vibration system of the apparatus ofFIG. 1 ; -
FIG. 4 is a side elevation thereof; -
FIG. 5 is a perspective of one embodiment of a microwave system for use with the apparatus ofFIG. 1 ; -
FIG. 6 is a perspective of a second embodiment of a microwave system for use with the apparatus ofFIG. 1 ; -
FIG. 7 is a perspective of a third embodiment of a microwave system for use with the apparatus ofFIG. 1 ; -
FIG. 8 is a perspective of a fourth embodiment of a microwave system for use with the apparatus ofFIG. 1 ; -
FIG. 9 is a perspective of a fifth embodiment of a microwave system for use with the apparatus ofFIG. 1 ; and -
FIG. 10 is a perspective of a sixth embodiment of a microwave system for use with the apparatus ofFIG. 1 . - Corresponding reference characters indicate corresponding parts throughout the drawings.
- With reference now to the drawings and in particular to
FIG. 1 , one embodiment of apparatus for use in dyeing atextile web 23 is generally designated 21. In one suitable embodiment, thetextile web 23 to be processed by theapparatus 21 is suitably a woven web, but may also be a non-woven web, including without limitation bonded-carded webs, spunbond webs and meltblown webs, polyesters, polyolefins, cotton, nylon, silks, hydroknit, coform, nanofiber, fluff batting, foam, elastomerics, rubber, film laminates, combinations of these materials or other suitable materials. Thetextile web 23 may be a single web layer or a multilayer laminate in which one or more layers of the laminate are suitable for being dyed. - The term “spunbond” refers to small diameter fibers which are formed by extruding molten thermoplastic material as filaments from a plurality of fine, usually circular capillaries of a spinneret with the diameter of the extruded filaments then being rapidly reduced as by, for example, in U.S. Pat. No. 4,340,563 to Appel et al., and U.S. Pat. No. 3,692,618 to Dorschner et al., U.S. Pat. No. 3,802,817 to Matsuki et al., U.S. Pat. Nos. 3,338,992 and 3,341,394 to Kinney, U.S. Pat. No. 3,502,763 to Hartman, and U.S. Pat. No. 3,542,615 to Dobo et al. Spunbond fibers are generally not tacky when they are deposited onto a collecting surface. Spunbond fibers are generally continuous and have average diameters (from a sample of at least 10) larger than 7 microns, more particularly, between about 10 and 20 microns.
- The term “meltblown” refers to fibers formed by extruding a molten thermoplastic material through a plurality of fine, usually circular, die capillaries as molten threads or filaments into converging high velocity, usually hot, gas (e.g. air) streams which attenuate the filaments of molten thermoplastic material to reduce their diameter, which may be to microfiber diameter. Thereafter, the meltblown fibers are carried by the high velocity gas stream and are deposited on a collecting surface to form a web of randomly dispersed meltblown fibers. Such a process is disclosed, for example, in U.S. Pat. No. 3,849,241 to Butin et al. Meltblown fibers are microfibers which may be continuous or discontinuous, are generally smaller than 10 microns in average diameter, and are generally tacky when deposited onto a collecting surface.
- Laminates of spunbond and meltblown fibers may be made, for example, by sequentially depositing onto a moving forming belt first a spunbond web layer, then a meltblown web layer and last another spunbond web layer and then bonding the layers together. Alternatively, the web layers may be made individually, collected in rolls, and combined in a separate bonding step. Such laminates usually have a basis weight of from about 0.1 to 12 osy (6 to 400 gsm), or more particularly from about 0.75 to about 3 osy.
- More suitably, the
textile web 23 is sufficiently open or porous so that dye applied to the web may migrate throughout the thickness of the web. The “porosity” of thetextile web 23 is a measurement of the void space within the textile and is measured for a particular web specimen in the following manner. For a given length (in centimeters) and width (in centimeters) of a web specimen (e.g., over which the web is generally homogeneous and, as such, has a uniform specific gravity), the specimen is weighed (in grams) by a suitable balance and the thickness (in centimeters) is measured using a suitable device, such as a VIR Electronic Thickness Tester, Model Number 89-1-AB commercially available from Thwing-Albert Instrument Company of Philadelphia, Pa., U.S.A. A total volume (in cubic centimeters) of the web specimen is determined as length×width×thickness. A material volume (in cubic centimeters) of the web specimen (i.e., the volume taken up just by the material in the web specimen) is determined as the weight of the web specimen divided by the specific gravity (in grams/cubic centimeter) of the material from which the web is constructed. The porosity (in percent) of the web specimen is then determined as ((total volume−material volume)/total volume)×100. - In particularly suitable embodiments, the
textile web 23 has a porosity of at least about 10 percent, and more suitably at least about 20 percent. In other embodiments the porosity as determined by the Porosity Test may be at least about 50 and in others the porosity may be at least about 75. More suitably, the porosity is in the range of about 10 percent to about 90 percent, and more suitably in the range of about 20 percent to about 90 percent. - Some non-limiting examples of suitable textile webs include a cotton fabric commercially available from Springs Global of Ft. Mill, S.C., U.S.A. as Spring Global Muslin CPG W/O-SKU 743006050371 (having a basis weight of about 105 grams/square meter (gsm)); a polyester fabric commercially available from John Boyle & Company of Statesville, N.C., U.S.A. as Main Street Fabrics—European Fashion PP—SKU 1713874 (having a basis weight of about 61 gsm); and a spunbond non-woven web commercially available from Pegas Nonwovens S.R.O. of Znojmo, Czech Republic as 23 gsm Pegas PP Liner necked to a basis weight of about 42 gsm. As a contrasting example, one unsuitable web material is paper, such as ink jet paper, and in particular ink jet paper commercially available as RSA Premium Inkjet Paper IJC2436300—24 pound (having a basis weight of about 92.4 gsm). The following table provides the porosity for each of these web materials, as determined by using the above measurement technique on four 7.5 cm×7.5 cm web specimens for each material and averaging the data.
-
specific total material pore weight thickness gravity volume volume volume porosity (grams) (cm) (g/cc) (cc) (cc) (cc) (percent) Cotton fabric 0.59 0.0288 1.490 1.62 0.39 1.23 76 Polyester fabric 0.35 0.0140 0.930 0.79 0.38 0.41 52 Spunbond 0.25 0.0350 0.900 1.97 0.28 1.70 86 non-woven Inkjet paper 0.52 0.0098 0.929 0.55 0.55 0.00 0 - The
dyeing apparatus 21 suitably comprises a dye applicating device, schematically and generally indicated at 25, operable to apply dye to at least one of thefaces textile web 23. For example, in the embodiment illustrated inFIG. 1 , the dye applicating device is particularly operable to apply dye to only oneface 24 a of the textile web. It is understood, however, that the applicating device may be operable to apply dye only to theopposite face 24 b of thetextile web 23, or to both faces of the web. It is also contemplated that more than one applicating device may be used (e.g., one corresponding to each face 24 a, 24 b of the textile web 23) to apply ink to both faces of the textile web either concurrently or sequentially. - The term “dye” as used herein refers to a substance that imparts more or less permanent color to other materials, such as to the
textile web 23. Suitable dyes include, without limitation, inks, lakes (also often referred to as color lakes), dyestuffs (for example but not limited to acid dyes, azoic dyes, basic dyes, direct dyes, disperse dyes, food, drug and cosmetic dyes, ingrain dyes, leather dyes, mordant dyes, natural dyes, reactive dyes, solvent dyes sulfur dyes and vat dyes), pigments (organic and inorganic) and other colorants (for example but not limited to fluorescent brighteners, developers, oxidation bases). The dye suitably has a viscosity in the range of about 2 to about 100 centipoises, more suitably in the range of about 2 to about 20 centipoises, and even more suitably in the range of about 2 to about 10 centipoises to facilitate flow of the dye into and throughout the web. - In a particularly suitable embodiment, the dye is of a composition that provides an enhanced absorption of microwave energy, such as by having a relatively high dielectric loss factor. As used herein, the “dielectric loss factor” is a measure of the receptivity of a material to high-frequency energy. The measured value of ε′ is most often referred to as the dielectric constant, while the measured value of ε″ is denoted as the dielectric loss factor. These values can be measured directly using any suitable measurement devices, such as a Network Analyzer with a low power, external electric field (i.e., 0 dBm to +5 dBm) typically over a frequency range of 300 KHz to 3 GHz, although Network Analyzers to 20 GHz are readily available. Most commonly dielectric loss factor is measured at a frequency of either 915 MHz or 2,450 MHz (and at room temperature, such as about 25 degrees Celsius). For example, one suitable measuring system can include an HP8720D Dielectric Probe, and a model HP8714C Network Analyzer, both available from Agilent Technologies of Brookfield, Wis., U.S.A. Substantially equivalent devices may also be employed. By definition ε″ is always positive, and a value of less than zero is occasionally observed when ε′ is near zero due to the measurement error of the analyzer.
- In one particularly suitable embodiment, the dye has a dielectric loss factor at 915 MHz and 25 degrees Celsius of at least about 10, more suitably at least about 50, and even more suitably at least about 100, For comparison purposes, the dielectric loss factor of water under the same conditions is about 1.2. In another suitable embodiment, the dye has a dielectric loss factor at 2,450 MHz and 25 degrees Celsius of at least about 25, more suitably at least about 50, and even more suitably at least about 100. Water has a dielectric loss factor of about 12 under these same conditions.
- As an example, the dye may include additives or other materials to enhance the affinity of the dye to microwave energy. Examples of such additives and materials include, without limitation, various mixed valent oxides, such as magnetite, nickel oxide and the like; carbon, carbon black and graphite; sulfide semiconductors, such as FeS2 and CuFeS2; silicon carbide; various metal powders such as powders of aluminum, iron and the like; various hydrated salts and other salts, such as calcium chloride dihydrate; diatomaceous earth; aliphatic polyesters (e.g., polybutylene succinate and poly(butylene succinate-co-adipate), polymers and copolymers of polylactic acid and polyethylene glycols; various hygroscopic or water absorbing materials or more generally polymers or copolymers with many sites of —OH groups.
- Examples of other suitable inorganic microwave absorbers include, without limitation, aluminum hydroxide, zinc oxide, barium titanate. Examples of other suitable organic microwave absorbers include, without limitation, polymers containing ester, aldehyde ketone, isocyanate, phenol, nitrile, carboxyl, vinylidene chloride, ethylene oxide, methylene oxide, epoxy, amine groups, polypyrroles, polyanilines, polyalkylthiophenes. Mixtures of the above are also suitable for use in the dye applied to be applied to the textile web. The selective additive or material may be ionic or dipolar, such that the applied energy field can activate the molecule.
- Non-limiting examples of suitable dyes that have the desired dielectric loss factor are inks commercially available from Yuhan-Kimberly of South Korea under the following designations: 67581-11005579 NanoColorant Cyan 220 ml; 67582-11005580 NanoColorant Magenta 220 ml; 67583-11005581 NanoColorant Yellow 220 ml; 67584-11005582 NanoColorant Black 220 ml; 67587-11005585 NanoColorant Red 220 ml; 67588-11005586 NanoColorant Orange 220 ml; 67591-11005589 NanoColorant Gray 220 ml; 67626-11006045 NanoColorant Violet 220 ml.
- The
dye applicating device 25 according to one embodiment may comprise any suitable device used for applying dye totextile webs 23 other than by saturating the entire web (e.g., by immersing the textile web in a bath of dye solution to saturate the web), whether the dye is pre-metered (e.g., in which little or no excess dye is applied to the web upon initial application of the dye) or post-metered (i.e., an excess amount of dye is applied to the textile web and subsequently removed). It is understood that the dye itself may be applied to thetextile web 23 or the dye may be used in a dye solution that is applied to the web. - Examples of suitable pre-metered
dye applicating devices 25 include, without limitation, devices for carrying out the following known applicating techniques: - Slot die: The dye is metered through a slot in a printing head directly onto the
textile web 23. - Direct gravure: The dye is in small cells in a gravure roll. The
textile web 23 comes into direct contact with the gravure roll and the dye in the cells is transferred onto the textile web. - Offset gravure with reverse roll transfer: Similar to the direct gravure technique except the gravure roll transfers the coating material to a second roll. This second roll then comes into contact with the
textile web 23 to transfer dye onto the textile web. - Curtain coating: This is a coating head with multiple slots in it. Dye is metered through these slots and drops a given distance down onto the
textile web 23. - Slide (Cascade) coating: A technique similar to curtain coating except the multiple layers of dye come into direct contact with the
textile web 23 upon exiting the coating head. There is no open gap between the coating head and thetextile web 23. - Forward and reverse roll coating (also known as transfer roll coating): This consists of a stack of rolls which transfers the dye from one roll to the next for metering purposes. The final roll comes into contact with the
textile web 23. The moving direction of thetextile web 23 and the rotation of the final roll determine whether the process is a forward process or a reverse process. - Extrusion coating: This technique is similar to the slot die technique except that the dye is a solid at room temperature. The dye is heated to melting temperature in the print head and metered as a liquid through the slot directly onto the
textile web 23. Upon cooling, the dye becomes a solid again. - Rotary screen: The dye is pumped into a roll which has a screen surface. A blade inside the roll forces the dye out through the screen for transfer onto the textile.
- Spray nozzle application: The dye is forced through a spray nozzle directly onto the
textile web 23. The desired amount (pre-metered) of dye can be applied, or thetextile web 23 may be saturated by the spraying nozzle and then the excess dye can be squeezed out (post-metered) by passing the textile web through a nip roller. - Flexographic printing: The dye is transferred onto a raised patterned surface of a roll. This patterned roll then contacts the
textile web 23 to transfer the dye onto the textile. - Digital textile printing: The dye is loaded in an ink jet cartridge and jetted onto the
textile web 23 as the textile web passes under the ink jet head. - Examples of suitable post-metering dye applicating devices for applying the dye to the
textile web 23 include without limitation devices that operate according to the following known applicating techniques: - Rod coating: The dye is applied to the surface of the
textile web 23 and excess dye is removed by a rod. A Mayer rod is the prevalent device for metering off the excess dye. - Air knife coating: The dye is applied to the surface of the
textile web 23 and excess dye is removed by blowing it off using a stream of high pressure air. - Knife coating: The dye is applied to the surface of the
textile web 23 and excess dye is removed by a head in the form of a knife. - Blade coating: The dye is applied to the surface of the
textile web 23 and excess dye is removed by a head in the form of a flat blade. - Spin coating: The
textile web 23 is rotated at high speed and excess dye applied to the rotating textile web spins off the surface of the web. - Fountain coating: The dye is applied to the
textile web 23 by a flooded fountain head and excess material is removed by a blade. - Brush application: The dye is applied to the
textile web 23 by a brush and excess material is regulated by the movement of the brush across the surface of the web. - Following the application of dye to the
textile web 23, the textile web is suitably delivered to an ultrasonic vibration system, generally indicated at 61, having a contact surface 63 (FIG. 2 ) over which the dyedweb 23 passes in contact with the vibration system such that the vibration system imparts ultrasonic energy to the web. In the illustrated embodiment, theultrasonic vibration system 61 has aterminal end 65, at least a portion of which defines thecontact surface 63 contacted by thetextile web 23 - In one particularly suitable embodiment, the
textile web 23 is suitably in the form of a generally continuous web, and more particularly a rolled web wherein the web is unrolled during processing and then rolled up following processing for transport to other post-processing stations. For example, as illustrated inFIGS. 1 and 2 , theultrasonic vibration system 61 may be suitably mounted on a support frame 67 (FIG. 2 ) intermediate an unwindroll 45 and a wind roll 49 (the unwind roll and wind roll also being mounted on suitable respective support frames (not shown)). It is understood, however, that thetextile web 23 may alternatively be in the form of one or more discrete webs during treatment without departing from the scope of this invention. Thedye applicating device 25 is located between the unwindroll 45 and the ultrasonic vibration system to apply dye to the oneface 24 a of the textile web before the web advances to the vibration system. It is understood, however, that dye may be applied to thetextile web 23 other than immediately upstream of the ultrasonic vibration system, such as at a station that is entirely separate from that at which the web is ultrasonically treated, without departing from the scope of this invention. - The
textile web 23 is suitably advanced (i.e., moved), such as by a suitable drive mechanism 51 (FIG. 1 ) at thewind roll 49, in a machine direction (indicated by the direction arrows inFIGS. 1 and 2 ) from the unwind roll past thedye applicating device 25 and theultrasonic vibration system 61 to the wind roll. The term “machine direction” as used herein refers generally to the direction in which thetextile web 23 is moved (e.g., longitudinally of the web in the illustrated embodiment) during processing. The term “cross-machine direction” is used herein to refer to the direction normal to the machine direction of thetextile web 23 and generally in the plane of the web (e.g., widthwise of the web in the illustrated embodiment). With particular reference toFIG. 2 , thetextile web 23 suitably advances toward the contact surface 63 (e.g., at theterminal end 65 of the ultrasonic vibration system 61) at an approach angle A1 relative to a longitudinal axis X of theultrasonic vibration system 61, and after passing over the contact surface the web further advances away from the contact surface at a departure angle B1 relative to the longitudinal axis X of the ultrasonic vibration system. - The approach angle A1 of the
textile web 23, in one embodiment, is suitably in the range of about 1 to about 89 degrees, more suitably in the range of about 1 to about 45 degrees, and even more suitably in the range of about 10 to about 45 degrees. The departure angle B1 of theweb 23 is suitably approximately equal to the approach angle A1 as illustrated inFIG. 2 . However, it is understood that the departure angle B1 may be greater than or less than the approach angle A1 without departing from the scope of this invention. - In one particularly suitable embodiment, the
ultrasonic vibration system 61 is adjustably mounted on thesupport frame 67 for movement relative to the support frame (e.g., vertically in the embodiment illustrated inFIG. 2 ) and the unwind and wind rolls 45, 49 to permit adjustment of thecontact surface 63 of the ultrasonic vibration system relative to theweb 23 to be treated. For example, theultrasonic vibration system 61 is selectively positionable between a first position (not shown) at which the approach angle A1 and departure angle B1 of the web is substantially zero or at least relatively small, and a second position illustrated inFIGS. 1 and 2 . In the first position of thevibration system 61, thecontact surface 63 of the vibration system may but need not necessarily be in contact with thetextile web 23. - In the second, or operating position of the
ultrasonic vibration system 61, the terminal end 65 (and hence the contact surface 63) of the vibration system is substantially spaced from the first position and is in contact with thetextile web 23. Movement of thevibration system 61 from its first position to its second position in this embodiment urges theweb 23 to along with thecontact surface 63 so as to form the approach and departure angles A1, B1 of the web. - Moving the
ultrasonic vibration system 61 from its first position to its second position in this manner may also serve to tension, or increase the tension in, thetextile web 23 at least along the segment of the web that lies against thecontact surface 63 of the vibration system while the web is held between the unwindroll 45 and thewind roll 49. For example, in one embodiment thetextile web 23 may be held in uniform tension along its width (i.e., its cross-machine direction dimension), at least at that segment of the web that is contacted by thecontact surface 63 of theultrasonic vibration system 61, in the range of about 0.025 pounds/inch of web width to about 3 pounds/inch of web width, and more suitably in the range of about 0.1 to about 1.25 pounds/inch of web width. - In one particularly suitable embodiment, the
ultrasonic vibration system 61 is particularly located relative to thetextile web 23 so that thecontact surface 63 of the vibration system contacts theface 24 b of the web opposite theface 24 a to which the dye was initially applied. While in the illustrated embodiment the dye is applied to the oneface 24 a of the textile web while theultrasonic vibration system 61 contacts theopposite face 24 b, it is understood that the dye may instead be applied to theface 24 b while the ultrasonic vibration system contacts theopposite face 24 a. - With particular reference now to
FIG. 3 , theultrasonic vibration system 61 in one embodiment suitably comprises an ultrasonic horn, generally indicated at 71, having aterminal end 73 that in the illustrated embodiment defines theterminal end 65 of the vibration system, and more particularly defines thecontact surface 63 of the vibration system. In particular, theultrasonic horn 71 ofFIG. 3 is suitably configured as what is referred to herein as an ultrasonic bar (also sometimes referred to as a blade horn) in which theterminal end 73 of the horn is generally elongate, e.g., along its width w. Theultrasonic horn 71 in one embodiment is suitably of unitary construction such that thecontact surface 63 defined by theterminal end 73 of the horn is continuous across the entire width w of the horn. - Additionally, the
terminal end 73 of thehorn 71 is suitably configured so that thecontact surface 63 defined by the terminal end of the ultrasonic horn is generally flat and rectangular. It is understood, however, that thehorn 71 may be configured so that thecontact surface 63 defined by theterminal end 73 of the horn is more rounded or other than flat without departing from the scope of this invention. Theultrasonic horn 71 is suitably oriented relative to the movingtextile web 23 so that theterminal end 73 of the horn extends in the cross-machine direction across the width of the web. The width w of thehorn 71, at least at itsterminal end 73, is suitably sized approximately equal to and may even be greater than the width of the web. - A thickness t (
FIG. 4 ) of theultrasonic horn 71 is suitably greater at aconnection end 75 of the horn (i.e., the longitudinal end of the horn opposite theterminal end 73 thereof) than at the terminal end of the horn to facilitate increased vibratory displacement of the terminal end of the horn during ultrasonic vibration. As one example, theultrasonic horn 71 of the illustrated embodiment ofFIGS. 3 and 4 has a thickness t at its connection end 75 of approximately 1.5 inches (3.81 cm) while its thickness at theterminal end 73 is approximately 0.5 inches (1.27 cm). The illustratedhorn 71 also has a width w of about 6.0 inches (15.24 cm) and a length (e.g., height in the illustrated embodiment) of about 5.5 inches (13.97 cm). The thickness t of the illustratedultrasonic horn 71 tapers inward as the horn extends longitudinally toward theterminal end 73. It is understood, however, that thehorn 71 may be configured other than as illustrated inFIGS. 3 and 4 and remain within the scope of this invention as long as the horn defines acontact surface 63 of thevibration system 61 suitable for contacting thetextile web 23 to impart ultrasonic energy to the web. - The
ultrasonic vibration system 61 of the illustrated embodiment is suitably in the form of what is commonly referred to as a stack, comprising the ultrasonic horn, abooster 77 coaxially aligned (e.g., longitudinally) with and connected at one end to theultrasonic horn 71 at the connection end 75 of the horn, and a converter 79 (also sometimes referred to as a transducer) coaxially aligned with and connected to the opposite end of the booster. Theconverter 79 is in electrical communication with a power source or generator (not shown) to receive electrical energy from the power source and convert the electrical energy to high frequency mechanical vibration. For example, one suitable type ofconverter 79 relies on piezoelectric material to convert the electrical energy to mechanical vibration. - The
booster 77 is configured to amplify (although it may instead be configured to reduce, if desired) the amplitude of the mechanical vibration imparted by theconverter 79. The amplified vibration is then imparted to theultrasonic horn 71. It is understood that thebooster 77 may instead be omitted from theultrasonic vibration system 61 without departing from the scope of this invention. Construction and operation of a suitable power source,converter 79 andbooster 77 are known to those skilled in the art and need not be further described herein. - In one embodiment, the
ultrasonic vibration system 61 is operable (e.g., by the power source) at a frequency in the range of about 15 kHz to about 100 kHz, more suitably in the range of about 15 kHz to about 60 kHz, and even more suitably in the range of about 20 kHz to about 40 kHz. The amplitude (e.g., displacement) of thehorn 71, and more particularly theterminal end 73 thereof, upon ultrasonic vibration may be varied by adjusting the input power of the power source, with the amplitude generally increasing with increased input power. For example, in one suitable embodiment the input power is in the range of about 0.1 kW to about 4 kW, more suitably in the range of about 0.5 kW to about 2 kW and more suitably about 1 kW. - In operation according to one embodiment of a process for dyeing a textile web, a
rolled textile web 23 is initially unwound from an unwindroll 45, e.g., by thewind roll 49 anddrive mechanism 51, with the web passing thedye applicator 25 and theultrasonic vibration system 61. Theultrasonic vibration system 61 is in its second position (as illustrated inFIGS. 1 and 2 ) with the terminal end 65 (and hence the contact surface 63) of the vibration system displaced along with the textile web to the desired approach and departure angles A1, B1 of the textile web. Thetextile web 23 may also be tensioned in the second position of thevibration system 61 and/or by further winding thewind roll 49, by back winding the unwindroll 45, by both, or by other suitable tensioning structure and/or techniques. - During processing between the unwind
roll 45 and thewind roll 49, thetextile web 23 is suitably configured in what is referred to herein as a generally open configuration as the web passes over thecontact surface 63 of theultrasonic vibration system 61. The term “open configuration” is intended to mean that thetextile web 23 is generally flat or otherwise unfolded, ungathered and untwisted, at least at the segment of the web in contact with thecontact surface 63 of thevibration system 61. - A feed rate of the web 23 (i.e., the rate at which the web moves in the machine direction over the
contact surface 63 of the vibration system 61) and the width of the contact surface (i.e., the thickness t of theterminal end 73 of thehorn 71 in the illustrated embodiment, or where the contact surface is not flat or planar, the total length of the contact surface from one side of the terminal end of the horn to the opposite side thereof) determine what is referred to herein as the dwell time of the web on the contact surface of the vibration system. It will be understood, then, that the term “dwell time” refers herein to the length of time that a segment of thetextile web 23 is in contact with thecontact surface 63 of thevibration system 61 as the web is drawn over the contact surface (e.g., the width of the contact surface divided by the feed rate of the web). In one suitable embodiment, the feed rate of theweb 23 across thecontact surface 63 of thevibration system 61 is in the range of about 0.5 feet/minute to about 2,000 feet/minute, more suitably in the range of about 1 feet/minute to about 100 feet/minute and even more suitably in the range of about 2 feet/minute to about 10 feet/minute. It is understood, however, that the feed rate may be other than as set forth above without departing from the scope of this invention. - In other embodiments, the dwell time is suitably in the range of about 0.1 second to about 60 seconds, more suitably in the range of about 1 second to about 10 seconds, and even more suitably in the range of about 2 seconds to about 5 seconds. It is understood, however, that the dwell time may be other than as set forth above depending for example on the material from which the
web 23 is made, the dye composition, the frequency and vibratory amplitude of thehorn 71 of thevibration system 61 and/or other factors, without departing from the scope of this invention. - As the
textile web 23 passes thedye applicating device 25, dye is applied to the oneface 24 a of the web. Theultrasonic vibration system 61 is operated by the power source to ultrasonically vibrate theultrasonic horn 71 as theopposite face 24 b of thetextile web 23 is drawn over thecontact surface 63 of the vibration system. Thehorn 71 imparts ultrasonic energy to the segment of thetextile web 23 that is in contact with thecontact surface 63 defined by theterminal end 73 of the horn. Imparting ultrasonic energy to theopposite face 24 b of thetextile web 23 facilitates the migration of dye from the oneface 24 a of the web into and through the web to theopposite face 24 b of the web. - It is understood, however, that the
face 24 a (i.e., the face on which the dye is applied) of thetextile web 23 may oppose and contact thecontact surface 63 of thevibration system 61 without departing from the scope of this invention. It is also contemplated that a second ultrasonic vibration system (not shown) may be used to apply ultrasonic energy to theface 24 a of the web, either concurrently or sequentially with the firstultrasonic vibration system 61 applying ultrasonic energy to theopposite face 24 b of the web. - With reference now back to
FIG. 1 , following ultrasonic treatment of the dyed textile web, the textile web is further advanced to, and through, a microwave system, generally indicated at 101 operable to direct high frequency, electromagnetic radiant energy, and more suitably microwave energy, to the dyedtextile web 23 to facilitate expedited and enhanced binding of the dye to the web. In one particularly suitable embodiment, for example, themicrowave system 101 may employ energy having a frequency in the range of about 1 MHz to about 5,800 MHz, and more suitably in the range of about 900 MHz to about 5,800 MHz. In one embodiment the frequency is more suitably about 915 MHz. In another embodiment the frequency is more suitably about 2,450 MHz. - The
microwave system 101, with reference toFIG. 5 suitably comprises amicrowave generator 103 operable to produce the desired amount of microwave energy, a wave-guide 105 and anapplication chamber 107 through which thetextile web 23 passes while moving in the machine direction (indicated by the direction arrow inFIG. 5 ). For example, the input power of the microwave generator is suitably in the range of about 1,500 watts to about 6,000 watts. It is understood, however, that in other embodiments the power input may be substantially greater, such as about 75,000 watts or more, without departing from the scope of this invention. - In a particular embodiment, illustrated in
FIG. 6 , theapplication chamber 107 comprises ahousing 126 operatively connected to the wave-guide 105 and havingend walls 128, an entrance opening (not shown inFIG. 6 but similar to anentrance opening 102 shown inFIG. 7 ) for receiving thetextile web 23 into the application chamber, and anoutlet opening 104 through which the textile web exits the application chamber for subsequent movement to thewind roll 49. The entrance andexit openings textile web 23 so as to allow the textile web, in its open configuration, to pass through the entrance and exit while inhibiting an excessive leakage of energy from the application chamber. The wave-guide 105 andapplication chamber 107 may be constructed from suitable non-ferrous, electrically-conductive materials, such as aluminum, copper, brass, bronze, gold and silver, as well as combinations thereof. - The
application chamber 107 in one particularly suitable embodiment is a tuned chamber within which the microwave energy can produce an operative standing wave. For example, theapplication chamber 107 may be configured to be a resonant chamber. Examples of suitable arrangements for aresonant application chamber 107 are described in U.S. Pat. No. 5,536,921 entitled SYSTEM FOR APPLYING MICROWAVE ENERGY 1N SHEET-LIKE MATERIAL by Hedrick et al., issued Jul. 16, 1996; and in U.S. Pat. No. 5,916,203 entitled COMPOSITE MATERIAL WITH ELASTICIZED PORTIONS AND A METHOD OF MAKING THE SAME by Brandon et al, issued Jun. 29, 1999. The entire disclosures of these documents are incorporated herein by reference in a manner that is consistent herewith. - In another embodiment, the effectiveness of the
application chamber 107 can be determined by measuring the power that is reflected back from the impedance load provided by the combination of theapplication chamber 107 and the target material (e.g. the textile web 23) in the application chamber. In a particular aspect, theapplication chamber 107 may be configured to provide a reflected power which is not more than a maximum of about 50% of the power that is delivered to the impedance load. The reflected power can alternatively be not more than about 20% of the delivered power, and can optionally be not more than about 10% of the delivered power. In other embodiments, however, the reflected power may be substantially zero. Alternatively, the reflected power may be about 1%, or less, of the delivered power, and can optionally be about 5%, or less, of the delivered power. If the reflected power is too high, inadequate levels of energy are being absorbed by the dyedtextile web 23 and the power being directed into the dyed web is being inefficiently utilized. - The
application chamber 107 may also be configured to provide a Q-factor of at least a minimum of about 200. The Q-factor can alternatively be at least about 5,000, and can optionally be at least about 10,000. In other embodiments, the Q-factor can up to about 20,000, or more. If the Q-factor is too low, inadequate electrical field strengths are provided to the dyed textile web. The Q-factor can be determined by the following formula (which may be found in the book entitled Industrial Microwave Heating by R. C. Metaxas and R. J. Meredith, published by Peter Peregrinus, Limited, located in London, England, copyright 1983, reprinted 1993): -
Q-factor=f o /Δf - where:
- fo=intended resonant frequency (typically the frequency produced by the high-frequency generator), and
- Δf=frequency separation between the half-power points.
- In determining the Q-factor, the power absorbed by the dyed
textile web 23 is deemed to be the power delivered into theapplication chamber 107 to the web, minus the reflected power returned from the application chamber. The peak-power is the power absorbed by the dyedtextile web 23 when the power is provided at the intended resonant frequency, fo. The half-power points are the frequencies at which the power absorbed by the dyedtextile web 23 falls to one-half of the peak-power. - For example, a suitable measuring system can include an HP8720D Dielectric Probe, and a model HP8714C Network Analyzer, both available from Agilent Technologies, a business having offices located at Brookfield, Wis., U.S.A. A suitable procedure for determining the Q-factor is described in the User's Manual dated 1998, part number 08712-90056. Substantially equivalent devices and procedures may also be employed.
- In another aspect, the
application chamber 107 may be configured for selective tuning to operatively “match” the load impedance produced by the presence of the target material (e.g. the dyed textile web 23) in the application chamber. The tuning of theapplication chamber 107 can, for example, be provided by any of the techniques that are useful for “tuning” microwave devices. Such techniques can include configuring theapplication chamber 107 to have a selectively variable geometry, changing the size and/or shape of a wave-guide aperture, employing adjustable impedance components (e.g. stub tuners), employing a split-shell movement of the application chamber, employing a variable frequency energy source that can be adjusted to change the frequency of the energy delivered to the application chamber, or employing like techniques, as well as employing combinations thereof. The variable geometry of theapplication chamber 107 can, for example, be provided by a selected moving of either or both of theend walls 128 to adjust the distance therebetween. - As representatively shown in
FIGS. 7-10 , the tuning feature may comprise anaperture plate 130 having a selectivelysized aperture 132 or other opening. Theaperture plate 130 may be positioned at or operatively proximate the location at which the wave-guide 105 joins theapplication chamber housing 126. Theaperture 132 can be suitably configured and sized to adjust the waveform and/or wavelength of the energy being directed into theapplication chamber 107. Additionally, astub tuner 134 may be operatively connected to the wave-guide 105. With reference toFIG. 7 , the wave-guide 105 can direct the microwave energy into thechamber 107 at a location that is interposed between the twoend walls 128. Either or both of theend walls 128 may be movable to provide selectively positionable end-caps, and either or both of the end walls may include a variable impedance device, such as provided by the representatively shownstub tuner 134. Alternatively, one ormore stub tuners 134 may be positioned at other operative locations in theapplication chamber 107. - With reference to
FIG. 8 , the wave-guide 105 may be arranged to deliver the microwave energy into one end of theapplication chamber 107. Additionally, theend wall 128 at the opposite end of thechamber 107 may be selectively movable to adjust the distance between theaperture plate 130 and theend wall 128. - In the embodiment illustrated in
FIG. 9 , theapplication chamber 107 comprises ahousing 126 that is non-rectilinear. In a further feature, thehousing 126 may be divided to provide operativelymovable split portions portions application chamber 107. As representatively shown, either or both of theend walls 128 are movable to provide selectively positionable end-caps, and either or both of the end walls may include a variable impedance device, such as provided by the representatively shownstub tuner 134. Alternatively, one ormore stub tuners 134 may be positioned at other operative locations in thechamber 107. - To tune the
application chamber 107, the appointed tuning components are adjusted and varied in a conventional, iterative manner to maximize the power into the load (e.g. into the dyed textile web), and to minimize the reflected power. Accordingly, the tuning components can be systematically varied to maximize the power into thetextile web 23 and minimize the reflected power. For example, the reflected power can be detected with a conventional power sensor, and can be displayed on a conventional power meter. The reflected power may, for example, be detected at the location of an isolator. The isolator is a conventional, commercially available device which is employed to protect a magnetron from reflected energy. Typically, the isolator is placed between the magnetron and the wave-guide 105. Suitable power sensors and power meters are available from commercial vendors. For example, a suitable power sensor can be provided by a HP E4412 CW power sensor which is available from Agilent Technologies of Brookfield, Wis., U.S.A. A suitable power meter can be provided by a HP E4419B power meter, also available from Agilent Technologies. - In the various configurations of the
application chamber 107, a properlysized aperture plate 130 and a properlysized aperture 132 can help reduce the amount of variable tuning adjustments needed to accommodate a continuous product. The variable impedance device (e.g. stub tuner 134) can also help to reduce the amount of variable tuning adjustments needed to accommodate the processing of acontinuous web 23. The variable-position end walls 128 or end caps can allow for easier adjustments to accommodate a varying load. The split-housing FIG. 9 ) configuration of theapplication chamber 107 can help accommodate aweb 23 having a varying thickness. - In another embodiment, illustrated in
FIG. 10 , themicrowave system 101 may comprise two or more application chamber 107 (e.g. 107 a+107 b+ . . . ). The plurality ofactivation chambers 107 can, for example, be arranged in the representatively shown serial array. - As one example of the size of the
application chamber 107, throughout the various embodiments the chamber may suitably have a machine-directional (indicated by the direction arrow in the various embodiments) length (e.g., from theentrance 102 to theexit 104, along which the web is exposed to the microwave energy in the chamber) of at least about 4 cm. In other aspects, thechamber 107 length can be up to a maximum of about 800 cm, or more. Thechamber 107 length can alternatively be up to about 400 cm, and can optionally be up to about 200 cm. As more particular examples, thechamber 107 length is suitably about 4.4 cm. for an operating frequency of about 5,800 MHz applicator, about 8.9 cm. for an operating frequency of about 2,450 MHz. and about 25 cm. for an operating frequency of about 915 MHz for tuned circular cavities. Such lengths may be much longer for multimode microwave systems. - Where the
microwave system 101 employs two ormore application chambers 107 arranged in series, the total sum of the machine-directional lengths provided by the plurality of chambers may be at least about 10 cm and proportionally longer for lower frequencies. For example, in other aspects the total of thechamber 107 lengths can be up to a maximum of about 3000 cm, or more. The total of thechamber 107 lengths can alternatively be up to about 2000 cm, and can optionally be up to about 1000 cm. - The total residence time within the
application chamber 107 or chambers can provide a distinctively efficient dwell time. The term “dwell time” in reference to themicrowave system 101 refers to the amount of time that a particular portion of the dyedtextile web 23 spends within theapplication chamber 107, e.g., in moving from the entrance opening 102 to the exit opening 104 of the chamber. In a particular aspect, the dwell time is suitably at least about 0.0002 sec. The dwell time can alternatively be at least about 0.005 sec, and can optionally be at least about 0.01 sec. In other embodiments the dwell time can be up to a maximum of about 3 sec, more suitably up to about 2 sec, and optionally up to about 1.5 sec. - In operation, after the
dyed textile web 23 is moved past theultrasonic vibration system 61, which facilitates distribution of the dye through the thickness of the web, the web is moved (e.g., drawn, in the illustrated embodiment) through theapplication chamber 107 of themicrowave system 101. Themicrowave system 101 is operated to direct microwave energy into theapplication chamber 107 for absorption by the dye (e.g., which in one embodiment suitably has an affinity for, or couples with, the microwave energy). The dye is thus heated rapidly, thereby substantially speeding up the rate at which at the dye becomes bound to the textile web (e.g., as opposed to conventional heating methods such as curing in an oven). The web is subsequently moved downstream of themicrowave system 101 for subsequent post-processing, such as washing to remove any unbound dye, and other suitable post-processing steps. - In the illustrated embodiment, the
textile web 23 is thus first subjected to ultrasonic energy to facilitate distribution of the dye through the web, and then subjected to microwave energy to facilitate enhanced (and expedited) binding of the dye into the web. While this combination of processes has been found to result in better binding of the dye into the web than omitting the ultrasonic vibration step and just applying the microwave energy to the web, it is understood that that in other embodiments the web may be subjected to the microwave energy after the dye application, thereby omitting the ultrasonic vibration step, without departing from the scope of this invention. In such an embodiment, it is contemplated that dye may be initially applied throughout the web by saturating the web (e.g., by dipping the web in a dye bath) or by other suitable dyeing techniques that do not involve applying ultrasonic energy directly to the web. - An experiment was conducted to determine the effectiveness of the above process in which the dyed web is subjected first to ultrasonic vibration and then to microwave energy, and to compare this effectiveness to that of the above process without the ultrasonic vibration step (e.g., microwave only), and to a conventional process in which the dyed web is simply cured in an oven after being dyed (e.g., no ultrasonics or microwave). Assessment of these processes was based on the color intensity of the dye on both the front and back faces of the web after processing.
- Color is commonly measured by using a spectrodensitometer, which measures reflected light and provides calorimetric data as will be described hereinafter. The light which is reflected in the visual range (i.e., having a wavelength of 400 nm to 700 nm) can be processed to give a numerical indication of the color. An example of such a device is the X-Rite 938 reflection spectrodensitometer available from X-Rite, Incorporated of Grandville, Mich. A suitable program for analyzing the data generated by this instrument is the X-Rite QA Master 2000 software available from X-Rite, Incorporated.
- Color can be described generally in terms of three elements, hue, chroma (or saturation) and lightness (sometimes called value or brightness). Hue (h) is the perceived attribute of a specific color that fixes the color's spectrum position and classifies it as blue, green, red or yellow. Chroma describes the vividness or dullness of a color. It is a measurement of how close the color is to either gray (a mixture of all colors) or to the pure hue. Chroma (C) can be broken into two measurements: a—the measurement of the redness or greenness of the color; and b—the measurement of the yellowness or blueness of the color. The range for a is from −60 to 60, with the range segment from 0 to 60 indicating increasing saturation of red as you approach 60, and the range segment 0 to −60 indicating increasing saturation of green as you approach −60. Chroma is defined as C=(a2+b2)1/2. Lightness is the luminous intensity of a color, or how close the color is to white or black and ranges in value from 0 (black) to 100 (white). All of these attributes can be determined using the aforementioned spectrodensitometer, and analyzed with the QA Master 2000 software.
- For this experiment, a master roll of cotton web commercially available from Test Fabrics, Inc. of West Pittston, Pa., U.S.A. as Style No. 419—bleached, mercerized, combed broadcloth was used as the textile web. The web has a basis weight of about 120 grams per square meter and is approximately four inches (about 10.2 cm) wide.
- A black ink, commercially available from Yuhan-Kimberly of South Korea under the designation 67584 11005582 NanoColorant Black 220 ml was used as the ink solution. The ink applicator was an electrometric air atomization spray applicator nozzle commercially available as Spraymation Electromatic Air Atomized Applicator Head, Model 79200 from Spraymation of Fort Lauderdale, Fla. The ink was pumped into this nozzle using a Masterflex L/S-Computerized drive pump, Model number 7550-10 available from Cole Parmer Instrument Company. The pump was manufactured by Barnant Company of Barrington, Ill. The applicator was operated at a rate of about 35 grams/square meter.
- For the ultrasonic vibration system, the various components that were used are commercially available from Dukane Ultrasonics of St. Charles, Ill., U.S.A as the following model numbers: power supply—Model 20A3000; converter—Model 110-3123; booster—Model 2179T; and horn Model 11608A. In particular, the horn had a thickness at its connection end of approximately 1.5 inches (3.81 cm), a thickness at its terminal end of approximately 0.5 inches (1.27 cm), a width of about 6.0 inches (15.24 cm) and a length (e.g., height in the illustrated embodiment) of about 5.5 inches (13.97 cm). The contact surface defined by the terminal end of the horn was flat, resulting in a contact surface length (e.g., approximately equal to the thickness of the horn at its terminal end) of about 0.5 inches (1.27 cm).
- The microwave system used was similar to that described above and illustrated in
FIG. 5 and operated by a power source commercially available as National Electronics Model GEN6KW480 from National Electronics of LaFox, Ill. and capable of delivering up to 6 KW of power. The resonant cavity of the microwave system had a depth (i.e., in the machine direction of movement of the web through the cavity) of about 3.5 inches (8.9 cm). - Three different processes were tested for this experiment: 1) a control in which the web was subjected to oven curing instead of ultrasonic vibration and microwave energy, 2) a process in which the web was subjected to microwave energy but not ultrasonic vibration, and 3) a process in which the web was subjected to both ultrasonic vibration and microwave energy. For each process, the master web, in rolled form, was placed on an unwind roll and unrolled and drawn past the ultrasonic vibration system and through the microwave system in an open configuration by a suitable wind roll and drive mechanism at a feed rate of about 4 ft./min. (about 1.2 meters/min.). Before the web reached the ultrasonic vibration system, the dye solution was sprayed by the dye applicator onto the face of the web that faces away from the ultrasonic vibration system (referred to further herein as the front face of the web).
- The opposite face of the web (i.e., the face that is opposite that on which the dye was sprayed—referred to further herein as the back face of the web) was then drawn over the contact surface of the ultrasonic vibration system (e.g., in direct contact therewith). This resulted in a dwell time of the web on the contact surface of the ultrasonic vibration system of about 0.63 seconds. A uniform tension of approximately one pound per inch of web width was applied to the web. The approach and departure angles of the web relative to the longitudinal axis of the ultrasonic vibration system were each about 20 degrees. The web was subsequently drawn through the resonant cavity of the microwave system and then to the wind roll.
- At least about 20 feet of the master roll of web material was run in accordance with each process to be tested. Once a particular process run was completed, a representative three foot sample of the dyed web was cut from the processed web and the L, a and b values of the sample was measured as described previously for both the front and back faces of the web. The web sample was then hand washed in a one gallon bath of detergent mixture comprised of 99.9% by volume of water and 0.1% by volume detergent (available from Procter and Gamble of Cincinnati, Ohio under the tradename Joy) to remove unbound dye from the web sample. The bath was intermittently dumped and refilled with a clean detergent solution until little or no dye washed out of the web sample. The L, a and b values for the front and back faces of the web were again measured after washing. Using the pre-washed color data as a reference, a “ΔE” value was determined as follows:
-
ΔE=(ΔL 2 +Δa 2 +Δb 2)1/2 i. - For the control process both the ultrasonic vibration system and the microwave system were turned off. The web sample cut from the dyed web was placed in an oven at 180 degrees Celsius for a period of three minutes prior to taking the pre-wash color data measurements. For the second process, the ultrasonic vibration system was turned off while the microwave system was operated at 2,450 MHz and an absorbed power of 200 watts. The third web was processed with the ultrasonic vibration system operating at 20 kHZ and the microwave system operated at 2,450 kHZ and an absorbed power of 200 watts.
- The results of the experiment are summarized in the table below.
-
Process L Description ΔE (after wash) Control Front Face 1.25 22.73 Back Face 2.05 28.89 Microwave Only Front Face 4.01 26.53 Back Face 2.10 30.33 Ultrasonic/Microwave Front Face 1.12 23.69 Back Face 0.86 22.70 - Focusing first on the lightness L, the dye was a black dye so the nearer to zero the lightness L is, the more “black” the respective face of the web appears. As is readily seen from the control, the back face (the face to which the dye solution was not applied) has a higher lightness L than the front face (to which the dye was initially applied), which means that the dye solution did not distribute well through the web from the front face to the back face of the web. The same is true for the specimen subjected only to the microwave energy. In contrast, for the specimen subjected to ultrasonic vibration the dye was more adequately pulled through the web to the back face thereof, as indicated by the nearly equal lightness values for the front and back faces of the web.
- The ΔE value provides an indication of the effectiveness of the tested processes for binding the dye into the respective web specimens. That is, because the ΔE is based on the difference of the L, a and b values taken before and after washing, a positive ΔE means that dye was washed away by the washing process, thereby slightly fading or rendering less intense the appearance of the black dye. For the web specimen that was subjected only to microwave energy (e.g., and not ultrasonic energy), the ΔE was higher that it was for the control web specimen. Thus, subjecting the web only to microwave energy does not itself assure a better binding of the dye into the web. Subjecting the web to ultrasonic energy before the microwave energy, however, resulted in a lower ΔE than for the control process, particularly on the back face of the web. This indicates that the combination of the ultrasonic energy with the microwave energy provides and enhanced binding of the dye into the web during processing.
- When introducing elements of the present invention or preferred embodiments thereof, the articles “a”, “an”, “the”, and “said” are intended to mean that there are one or more of the elements. The terms “comprising”, “including”, and “having” are intended to be inclusive and mean that there may be additional elements other than the listed elements.
- As various changes could be made in the above constructions and methods without departing from the scope of the invention, it is intended that all matter contained in the above description and shown in the accompanying drawings shall be interpreted as illustrative and not in a limiting sense.
Claims (27)
1. A process for dyeing a textile web, said textile web having a first face and a second face opposite the first face, said method comprising:
applying dye to the textile web;
moving the web in an open configuration thereof over a contact surface of an ultrasonic vibration system with the textile web in direct contact with the contact surface of the ultrasonic vibration system;
operating the ultrasonic vibration system to impart ultrasonic energy to said textile web to facilitate the distribution of dye throughout the web;
moving the web in its open configuration through a microwave application chamber of a microwave system subsequent to imparting ultrasonic energy to said web; and
operating the microwave system to impart microwave energy to the web in the microwave application chamber to facilitate binding of the dye to the web.
2. The process set forth in claim 1 wherein the step of applying dye to the textile web comprises applying dye to the first face of the web other than by saturating the web.
3. The process set forth in claim 2 wherein the step of moving the web over the contact surface of an ultrasonic vibration system comprises moving said web of said contact surface with the second face of said web in direct contact with said contact surface of the ultrasonic vibration system.
4. The process set forth in claim 1 wherein the ultrasonic vibration system has a longitudinal axis, the textile web being moved in a machine direction from a location upstream from the contact surface of the ultrasonic vibration system into contact with the contact surface of the ultrasonic vibration system, said movement of the web in the machine direction being along an approach angle relative to said longitudinal axis of the ultrasonic vibration system, said approach angle being in the range of about 1 to about 89 degrees.
5. The process set forth in claim 4 wherein the approach angle is in the range of about 10 to about 45 degrees.
6. The process set forth in claim 4 wherein the textile web is further moved in the machine direction along a departure angle relative to the longitudinal axis of the ultrasonic vibration system from said contact of the web with the contact surface of the ultrasonic vibration system to a location downstream from said contact surface of the ultrasonic vibration system, said departure angle being in the range of about 1 to about 89 degrees.
7. The process set forth in claim 1 wherein the textile web has a width, the process further comprising holding the textile web in uniform tension across the width of the textile web at least at a portion of said textile web in direct contact with the contact surface of the ultrasonic vibration system, said tension being in the range of about 0.025 to about 3 pounds per inch of width of the textile web.
8. The process set forth in claim 1 wherein the ultrasonic vibration system is vibrated at a frequency in the range of about 20 kHz to about 40 kHz.
9. The process set forth in claim 1 wherein the step of operating the ultrasonic vibration system comprises supplying a power input to said system, the power input being in the range of about 0.5 kW to about 2 kw.
10. The process set forth in claim 1 wherein the textile web has a width, the ultrasonic vibration system comprising an ultrasonic horn having a terminal end defining said contact surface, said terminal end of the ultrasonic horn having a width that is approximately equal to or greater than the width of the web, the step of moving the web in an open configuration thereof over the contact surface of an ultrasonic vibration system comprising moving the web lengthwise over the contact surface of the ultrasonic vibration system with the terminal end of the ultrasonic vibration system oriented to extend widthwise across the width of the web with the contact surface in direct contact with the web.
11. The process set forth in claim 1 wherein the step of operating the microwave system comprises operating the microwave system at a frequency in the range of about 900 MHz to about 5,800 MHz.
12. The process set forth in claim 1 wherein the step of operating the microwave system comprises operating the microwave system at a power input in the range of about 1,500 watts to about 6,000 watts.
13. The process set forth in claim 1 wherein the microwave application chamber has a length along which microwave energy is imparted to the web as the web passes along the length of said chamber, the step of moving the web through the microwave application chamber comprising moving the web through said chamber at a rate relative to said microwave application chamber length to define a dwell time of the web within said chamber in the range of about 0.0002 seconds to about 3 seconds.
14. The process set forth in claim 1 wherein the step of applying dye to the textile web comprises applying a dye having a dielectric loss factor at 915 MHz of at least about 10 to the textile web.
15. The process set forth in claim 14 wherein the step of applying dye to the textile web comprises applying a dye having a dielectric loss factor at 915 MHz of at least about 50 to the textile web.
16. The process set forth in claim 15 wherein the step of applying dye to the textile web comprises applying a dye having a dielectric loss factor at 915 MHz of at least about 100 to the textile web.
17. The process set forth in claim 1 wherein the step of applying dye to the textile web comprises applying a dye having a dielectric loss factor at 2,450 MHz of at least about 50 to the textile web.
18. The process set forth in claim 17 wherein the step of applying dye to the textile web comprises applying a dye having a dielectric loss factor at 2,450 MHz of at least about 100 to the textile web.
19. A process for dyeing a textile web, said textile web having a first face, a second face opposite the first face and a thickness from said first face to said second face, said method comprising:
applying dye to the textile web throughout the thickness thereof;
moving the web in an open configuration thereof through a microwave application chamber of a microwave system subsequent to applying dye to the web; and
operating the microwave system to impart microwave energy to the web in the microwave application chamber to facilitate binding of the dye to the web.
20. The process set forth in claim 19 wherein the step of operating the microwave system comprises operating the microwave system at a frequency in the range of about 900 MHz to about 5,800 MHz.
21. The process set forth in claim 19 wherein the microwave application chamber has a length along which microwave energy is imparted to the web as the web passes along the length of said chamber, the step of moving the web through the microwave application chamber comprising moving the web through said chamber at a rate relative to said microwave application chamber length to define a dwell time of the web within said chamber in the range of about 0.0002 seconds to about 3 seconds.
22. The process set forth in claim 19 wherein the step of applying dye to the textile web comprises applying a dye having a dielectric loss factor at 915 MHz of at least about 10 to the textile web.
23. The process set forth in claim 22 wherein the step of applying dye to the textile web comprises applying a dye having a dielectric loss factor at 915 MHz of at least about 50 to the textile web.
24. The process set forth in claim 23 wherein the step of applying dye to the textile web comprises applying a dye having a dielectric loss factor at 915 MHz of at least about 100 to the textile web.
25. The process set forth in claim 19 wherein the step of applying dye to the textile web comprises applying a dye having a dielectric loss factor at 2,450 MHz of at least about 50 to the textile web.
26. The process set forth in claim 25 wherein the step of applying dye to the textile web comprises applying a dye having a dielectric loss factor at 2,450 MHz of at least about 100 to the textile web.
27. The process set forth in claim 19 wherein the step of operating the microwave system comprises operating the microwave system at a power input in the range of about 1,500 watts to about 6,000 watts.
Priority Applications (4)
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US11/777,128 US8182552B2 (en) | 2006-12-28 | 2007-07-12 | Process for dyeing a textile web |
PCT/IB2007/054909 WO2008081364A1 (en) | 2006-12-28 | 2007-12-03 | Process for dyeing a textile web |
KR1020097013598A KR101415790B1 (en) | 2006-12-28 | 2007-12-03 | Process for dyeing a textile web |
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US11/617,473 US20080155762A1 (en) | 2006-12-28 | 2006-12-28 | Process for dyeing a textile web |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
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Citations (95)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US664026A (en) * | 1899-03-06 | 1900-12-18 | Lewis Hallock Nash | Speed-regulator. |
US2904981A (en) * | 1957-05-09 | 1959-09-22 | Patex Corp | Means for treating web materials |
US3202281A (en) * | 1964-10-01 | 1965-08-24 | Weston David | Method for the flotation of finely divided minerals |
US3249453A (en) * | 1961-07-29 | 1966-05-03 | Bayer Ag | Ultrasonic preparation of finely dispersed dyestuff |
US3273631A (en) * | 1964-01-13 | 1966-09-20 | Neuman Entpr Ltd | Ultrasonic fluid heating, vaporizing, cleaning and separating apparatus |
US3275787A (en) * | 1963-12-30 | 1966-09-27 | Gen Electric | Process and apparatus for producing particles by electron melting and ultrasonic agitation |
US3289328A (en) * | 1965-08-30 | 1966-12-06 | Ursula E Abel | Sport sock |
US3325348A (en) * | 1964-09-24 | 1967-06-13 | Fitchburg Paper | Ultrasonic device for placing materials in suspension |
US3338992A (en) * | 1959-12-15 | 1967-08-29 | Du Pont | Process for forming non-woven filamentary structures from fiber-forming synthetic organic polymers |
US3341394A (en) * | 1966-12-21 | 1967-09-12 | Du Pont | Sheets of randomly distributed continuous filaments |
US3410116A (en) * | 1966-10-24 | 1968-11-12 | Melvin L. Levinson | Microwave and ultrasonic apparatus |
US3471248A (en) * | 1962-05-03 | 1969-10-07 | Geigy Ag J R | Dye carrier compositions |
US3484179A (en) * | 1966-08-17 | 1969-12-16 | Stevens & Co Inc J P | Method for selective heating in textiles with microwaves |
US3490584A (en) * | 1965-08-31 | 1970-01-20 | Cavitron Corp | Method and apparatus for high frequency screening of materials |
US3502763A (en) * | 1962-02-03 | 1970-03-24 | Freudenberg Carl Kg | Process of producing non-woven fabric fleece |
US3519517A (en) * | 1966-09-30 | 1970-07-07 | Raytheon Co | Method of and means for microwave heating of organic materials |
US3542615A (en) * | 1967-06-16 | 1970-11-24 | Monsanto Co | Process for producing a nylon non-woven fabric |
US3620876A (en) * | 1969-07-28 | 1971-11-16 | Richard J Guglielmo Sr | Liquid electromagnetic adhesive and method of joining materials thereby |
US3620875A (en) * | 1964-12-11 | 1971-11-16 | Ema Corp | Electromagnetic adhesive and method of joining material thereby |
US3653952A (en) * | 1958-06-26 | 1972-04-04 | Union Carbide Corp | Dyeable resin bonded fibrous substrates |
US3692618A (en) * | 1969-10-08 | 1972-09-19 | Metallgesellschaft Ag | Continuous filament nonwoven web |
US3707773A (en) * | 1971-01-27 | 1973-01-02 | Service Business Forms | Multi-line gluing of superimposed leaves |
US3762188A (en) * | 1972-04-05 | 1973-10-02 | Pvo International Inc | Apparatus for treating textile fibers in staple fiber form |
US3782547A (en) * | 1971-10-12 | 1974-01-01 | Harry Dietert Co | Structure for ultrasonic screening |
US3802817A (en) * | 1969-10-01 | 1974-04-09 | Asahi Chemical Ind | Apparatus for producing non-woven fleeces |
US3849241A (en) * | 1968-12-23 | 1974-11-19 | Exxon Research Engineering Co | Non-woven mats by melt blowing |
US3888715A (en) * | 1970-09-21 | 1975-06-10 | Weyerhaeuser Co | Method of inducing high frequency electric current into a thermosetting adhesive joint |
US3902414A (en) * | 1970-10-01 | 1975-09-02 | Peter Zimmer | Screen printer using vibration to improve ink penetration |
US4046073A (en) * | 1976-01-28 | 1977-09-06 | International Business Machines Corporation | Ultrasonic transfer printing with multi-copy, color and low audible noise capability |
US4060438A (en) * | 1976-09-02 | 1977-11-29 | Home Curtain Corporation | Process for imparting color on a discrete basis to the thermally fused portion of quilted synthetic resinous materials |
US4062768A (en) * | 1972-11-14 | 1977-12-13 | Locker Industries Limited | Sieving of materials |
US4086112A (en) * | 1976-01-20 | 1978-04-25 | Imperial Chemical Industries Limited | Method of printing fabrics |
US4131424A (en) * | 1977-07-21 | 1978-12-26 | Milliken Research Corporation | Method of dyeing using the combination of certain halogenated hydrocarbons and aromatic solvents in an aqueous dye admixture |
US4156626A (en) * | 1977-07-18 | 1979-05-29 | Souder James J | Method and apparatus for selectively heating discrete areas of surfaces with radiant energy |
US4234775A (en) * | 1978-08-17 | 1980-11-18 | Technical Developments, Inc. | Microwave drying for continuously moving webs |
US4302485A (en) * | 1979-07-18 | 1981-11-24 | Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of National Defence | Fabric treatment with ultrasound |
US4339295A (en) * | 1978-12-20 | 1982-07-13 | The United States Of America As Represented By The Secretary Of The Department Of Health & Human Services | Hydrogel adhesives and sandwiches or laminates using microwave energy |
US4340563A (en) * | 1980-05-05 | 1982-07-20 | Kimberly-Clark Corporation | Method for forming nonwoven webs |
US4419160A (en) * | 1982-01-15 | 1983-12-06 | Burlington Industries, Inc. | Ultrasonic dyeing of thermoplastic non-woven fabric |
US4548611A (en) * | 1983-05-31 | 1985-10-22 | Paterson James G T | Method and apparatus for dyeing textile yarn substrates by impacting a foam |
US4612016A (en) * | 1984-03-08 | 1986-09-16 | Ciba-Geigy Corporation | Process for dyeing cellulosic textile materials |
US4626642A (en) * | 1985-10-08 | 1986-12-02 | General Motors Corporation | Microwave method of curing a thermoset polymer |
US4707402A (en) * | 1985-10-11 | 1987-11-17 | Phillips Petroleum Company | Formation of laminated structures by selective dielectric heating of bonding film |
US4751529A (en) * | 1986-12-19 | 1988-06-14 | Xerox Corporation | Microlenses for acoustic printing |
US4879564A (en) * | 1989-02-02 | 1989-11-07 | Eastman Kodak Company | Ultrasonic dye image fusing |
US4906497A (en) * | 1987-11-16 | 1990-03-06 | Uzin-Werk Georg Utz Gmbh & Co. Kg | Microwave-activatable hot-melt adhesive |
US4945121A (en) * | 1987-08-18 | 1990-07-31 | Koh-I-Noor Radiograph, Inc. | Thermosetting dyed latex colorant dispersions |
US4969968A (en) * | 1988-07-22 | 1990-11-13 | William C. Heller, Jr. | Method of inductive heating with an integrated multiple particle agent |
US5189078A (en) * | 1989-10-18 | 1993-02-23 | Minnesota Mining And Manufacturing Company | Microwave radiation absorbing adhesive |
US5193913A (en) * | 1989-05-11 | 1993-03-16 | Baxter International Inc. | RF energy sealable web of film |
US5193362A (en) * | 1991-08-01 | 1993-03-16 | Milliken Research Corporation | Apparatus for textile treatment |
US5217768A (en) * | 1991-09-05 | 1993-06-08 | Advanced Dielectric Technologies | Adhesiveless susceptor films and packaging structures |
US5238975A (en) * | 1989-10-18 | 1993-08-24 | Minnesota Mining And Manufacturing Company | Microwave radiation absorbing adhesive |
US5244525A (en) * | 1987-11-02 | 1993-09-14 | Kimberly-Clark Corporation | Methods for bonding, cutting and printing polymeric materials using xerographic printing of IR absorbing material |
US5272216A (en) * | 1990-12-28 | 1993-12-21 | Westinghouse Electric Corp. | System and method for remotely heating a polymeric material to a selected temperature |
US5338611A (en) * | 1990-02-20 | 1994-08-16 | Aluminum Company Of America | Method of welding thermoplastic substrates with microwave frequencies |
US5340649A (en) * | 1991-07-03 | 1994-08-23 | Minnesota Mining And Manufacturing | Microwaveable adhesive article and method of use |
US5346932A (en) * | 1990-01-26 | 1994-09-13 | Shin-Etsu Chemical Co., Ltd. | Silicone rubber composition and method for curing the same |
US5368199A (en) * | 1990-08-06 | 1994-11-29 | Loctite Corporation | Microwaveable hot melt dispenser |
US5400460A (en) * | 1992-07-02 | 1995-03-28 | Minnesota Mining And Manufacturing Company | Microwaveable adhesive article and method of use |
US5446270A (en) * | 1989-04-07 | 1995-08-29 | Minnesota Mining And Manufacturing Company | Microwave heatable composites |
US5487853A (en) * | 1990-07-12 | 1996-01-30 | The C. A. Lawton Company | Energetic stitching for complex preforms |
US5536921A (en) * | 1994-02-15 | 1996-07-16 | International Business Machines Corporation | System for applying microware energy in processing sheet like materials |
US5603795A (en) * | 1994-09-01 | 1997-02-18 | Martin Marietta Energy Systems, Inc. | Joining of thermoplastic substrates by microwaves |
US5770296A (en) * | 1996-08-05 | 1998-06-23 | Senco Products, Inc. | Adhesive device |
US5798395A (en) * | 1994-03-31 | 1998-08-25 | Lambda Technologies Inc. | Adhesive bonding using variable frequency microwave energy |
US5856245A (en) * | 1988-03-14 | 1999-01-05 | Nextec Applications, Inc. | Articles of barrier webs |
US5871872A (en) * | 1997-05-30 | 1999-02-16 | Shipley Company, Ll.C. | Dye incorporated pigments and products made from same |
US5916203A (en) * | 1997-11-03 | 1999-06-29 | Kimberly-Clark Worldwide, Inc. | Composite material with elasticized portions and a method of making the same |
US6007662A (en) * | 1996-08-05 | 1999-12-28 | Senco Products, Inc. | Method of adhesively adhering rubber components |
US6024822A (en) * | 1998-02-09 | 2000-02-15 | Ato Findley, Inc. | Method of making disposable nonwoven articles with microwave activatable hot melt adhesive |
US6045648A (en) * | 1993-08-06 | 2000-04-04 | Minnesta Mining And Manufacturing Company | Thermoset adhesive having susceptor particles therein |
US6103812A (en) * | 1997-11-06 | 2000-08-15 | Lambda Technologies, Inc. | Microwave curable adhesive |
US6114676A (en) * | 1999-01-19 | 2000-09-05 | Ramut University Authority For Applied Research And Industrial Development Ltd. | Method and device for drilling, cutting, nailing and joining solid non-conductive materials using microwave radiation |
US6117192A (en) * | 1999-05-24 | 2000-09-12 | Tatecraft Industries, Inc. | Dye composition, dyeing apparatus and dyeing method |
US6203151B1 (en) * | 1999-06-08 | 2001-03-20 | Hewlett-Packard Company | Apparatus and method using ultrasonic energy to fix ink to print media |
US6266836B1 (en) * | 1996-10-04 | 2001-07-31 | Consejo Superior De Investigaciones Cientificas | Process and device for continuous ultrasonic washing of textile |
US6348679B1 (en) * | 1998-03-17 | 2002-02-19 | Ameritherm, Inc. | RF active compositions for use in adhesion, bonding and coating |
US20020074380A1 (en) * | 1999-01-15 | 2002-06-20 | Dr. Hielscher Gmbh | Method for the constant maintenance of the mean gap width between a sonotrode of an ultrasonic system and a tool of an ultrasonic cutting device designed as a counter surface |
US6419798B1 (en) * | 2000-12-15 | 2002-07-16 | Kimberly-Clark Worldwide, Inc. | Methods of making disposable products having materials having shape-memory |
US20030119406A1 (en) * | 2001-12-20 | 2003-06-26 | Abuto Francis Paul | Targeted on-line stabilized absorbent structures |
US6649888B2 (en) * | 1999-09-23 | 2003-11-18 | Codaco, Inc. | Radio frequency (RF) heating system |
US6652602B2 (en) * | 2001-12-21 | 2003-11-25 | N.V. Bekaert S.A. | Color dyeing system for plastic films |
US6689730B2 (en) * | 1998-02-20 | 2004-02-10 | The Procter & Gamble Company | Garment stain removal product which uses sonic or ultrasonic waves |
US6734409B1 (en) * | 2002-10-31 | 2004-05-11 | Corning Incorporated | Microwave assisted bonding method and joint |
US6783623B2 (en) * | 2002-10-23 | 2004-08-31 | Sonoco Development, Inc. | Method of making a dry bonded paperboard structure |
US6846448B2 (en) * | 2001-12-20 | 2005-01-25 | Kimberly-Clark Worldwide, Inc. | Method and apparatus for making on-line stabilized absorbent materials |
US6855760B1 (en) * | 1999-05-26 | 2005-02-15 | Henkel Kommanditgesellschaft Auf Aktien | Detachable adhesive compounds |
US6901683B2 (en) * | 2002-02-15 | 2005-06-07 | International Business Machines Corporation | Method and apparatus for electromagnetic drying of printed media |
US20050132906A1 (en) * | 2003-12-19 | 2005-06-23 | Sca Hygiene Products Ab | Production Of A Dyed Patterned Web |
US6938683B2 (en) * | 2004-01-07 | 2005-09-06 | Inventec Corporation | Radiator |
US20050202578A1 (en) * | 2001-10-19 | 2005-09-15 | Nano-Proprietary, Inc. | Ink jet application for carbon nanotubes |
US20050238804A1 (en) * | 2002-06-13 | 2005-10-27 | Arkady Garbar | Nano-powder-based coating and ink compositions |
US7034266B1 (en) * | 2005-04-27 | 2006-04-25 | Kimberly-Clark Worldwide, Inc. | Tunable microwave apparatus |
US20080155763A1 (en) * | 2006-12-28 | 2008-07-03 | Kimberly-Clark Worldwide, Inc. | Process for dyeing a textile web |
-
2006
- 2006-12-28 US US11/617,473 patent/US20080155762A1/en not_active Abandoned
Patent Citations (99)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US664026A (en) * | 1899-03-06 | 1900-12-18 | Lewis Hallock Nash | Speed-regulator. |
US2904981A (en) * | 1957-05-09 | 1959-09-22 | Patex Corp | Means for treating web materials |
US3653952A (en) * | 1958-06-26 | 1972-04-04 | Union Carbide Corp | Dyeable resin bonded fibrous substrates |
US3338992A (en) * | 1959-12-15 | 1967-08-29 | Du Pont | Process for forming non-woven filamentary structures from fiber-forming synthetic organic polymers |
US3249453A (en) * | 1961-07-29 | 1966-05-03 | Bayer Ag | Ultrasonic preparation of finely dispersed dyestuff |
US3502763A (en) * | 1962-02-03 | 1970-03-24 | Freudenberg Carl Kg | Process of producing non-woven fabric fleece |
US3471248A (en) * | 1962-05-03 | 1969-10-07 | Geigy Ag J R | Dye carrier compositions |
US3275787A (en) * | 1963-12-30 | 1966-09-27 | Gen Electric | Process and apparatus for producing particles by electron melting and ultrasonic agitation |
US3273631A (en) * | 1964-01-13 | 1966-09-20 | Neuman Entpr Ltd | Ultrasonic fluid heating, vaporizing, cleaning and separating apparatus |
US3325348A (en) * | 1964-09-24 | 1967-06-13 | Fitchburg Paper | Ultrasonic device for placing materials in suspension |
US3202281A (en) * | 1964-10-01 | 1965-08-24 | Weston David | Method for the flotation of finely divided minerals |
US3620875A (en) * | 1964-12-11 | 1971-11-16 | Ema Corp | Electromagnetic adhesive and method of joining material thereby |
US3289328A (en) * | 1965-08-30 | 1966-12-06 | Ursula E Abel | Sport sock |
US3490584A (en) * | 1965-08-31 | 1970-01-20 | Cavitron Corp | Method and apparatus for high frequency screening of materials |
US3484179A (en) * | 1966-08-17 | 1969-12-16 | Stevens & Co Inc J P | Method for selective heating in textiles with microwaves |
US3519517A (en) * | 1966-09-30 | 1970-07-07 | Raytheon Co | Method of and means for microwave heating of organic materials |
US3410116A (en) * | 1966-10-24 | 1968-11-12 | Melvin L. Levinson | Microwave and ultrasonic apparatus |
US3341394A (en) * | 1966-12-21 | 1967-09-12 | Du Pont | Sheets of randomly distributed continuous filaments |
US3542615A (en) * | 1967-06-16 | 1970-11-24 | Monsanto Co | Process for producing a nylon non-woven fabric |
US3849241A (en) * | 1968-12-23 | 1974-11-19 | Exxon Research Engineering Co | Non-woven mats by melt blowing |
US3620876A (en) * | 1969-07-28 | 1971-11-16 | Richard J Guglielmo Sr | Liquid electromagnetic adhesive and method of joining materials thereby |
US3802817A (en) * | 1969-10-01 | 1974-04-09 | Asahi Chemical Ind | Apparatus for producing non-woven fleeces |
US3692618A (en) * | 1969-10-08 | 1972-09-19 | Metallgesellschaft Ag | Continuous filament nonwoven web |
US3888715A (en) * | 1970-09-21 | 1975-06-10 | Weyerhaeuser Co | Method of inducing high frequency electric current into a thermosetting adhesive joint |
US3902414A (en) * | 1970-10-01 | 1975-09-02 | Peter Zimmer | Screen printer using vibration to improve ink penetration |
US3707773A (en) * | 1971-01-27 | 1973-01-02 | Service Business Forms | Multi-line gluing of superimposed leaves |
US3782547A (en) * | 1971-10-12 | 1974-01-01 | Harry Dietert Co | Structure for ultrasonic screening |
US3762188A (en) * | 1972-04-05 | 1973-10-02 | Pvo International Inc | Apparatus for treating textile fibers in staple fiber form |
US4062768A (en) * | 1972-11-14 | 1977-12-13 | Locker Industries Limited | Sieving of materials |
US4086112A (en) * | 1976-01-20 | 1978-04-25 | Imperial Chemical Industries Limited | Method of printing fabrics |
US4046073A (en) * | 1976-01-28 | 1977-09-06 | International Business Machines Corporation | Ultrasonic transfer printing with multi-copy, color and low audible noise capability |
US4060438A (en) * | 1976-09-02 | 1977-11-29 | Home Curtain Corporation | Process for imparting color on a discrete basis to the thermally fused portion of quilted synthetic resinous materials |
US4156626A (en) * | 1977-07-18 | 1979-05-29 | Souder James J | Method and apparatus for selectively heating discrete areas of surfaces with radiant energy |
US4131424A (en) * | 1977-07-21 | 1978-12-26 | Milliken Research Corporation | Method of dyeing using the combination of certain halogenated hydrocarbons and aromatic solvents in an aqueous dye admixture |
US4234775A (en) * | 1978-08-17 | 1980-11-18 | Technical Developments, Inc. | Microwave drying for continuously moving webs |
US4339295A (en) * | 1978-12-20 | 1982-07-13 | The United States Of America As Represented By The Secretary Of The Department Of Health & Human Services | Hydrogel adhesives and sandwiches or laminates using microwave energy |
US4302485A (en) * | 1979-07-18 | 1981-11-24 | Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of National Defence | Fabric treatment with ultrasound |
US4340563A (en) * | 1980-05-05 | 1982-07-20 | Kimberly-Clark Corporation | Method for forming nonwoven webs |
US4419160A (en) * | 1982-01-15 | 1983-12-06 | Burlington Industries, Inc. | Ultrasonic dyeing of thermoplastic non-woven fabric |
US4548611A (en) * | 1983-05-31 | 1985-10-22 | Paterson James G T | Method and apparatus for dyeing textile yarn substrates by impacting a foam |
US4612016A (en) * | 1984-03-08 | 1986-09-16 | Ciba-Geigy Corporation | Process for dyeing cellulosic textile materials |
US4626642A (en) * | 1985-10-08 | 1986-12-02 | General Motors Corporation | Microwave method of curing a thermoset polymer |
US4707402A (en) * | 1985-10-11 | 1987-11-17 | Phillips Petroleum Company | Formation of laminated structures by selective dielectric heating of bonding film |
US4751529A (en) * | 1986-12-19 | 1988-06-14 | Xerox Corporation | Microlenses for acoustic printing |
US4945121A (en) * | 1987-08-18 | 1990-07-31 | Koh-I-Noor Radiograph, Inc. | Thermosetting dyed latex colorant dispersions |
US5244525A (en) * | 1987-11-02 | 1993-09-14 | Kimberly-Clark Corporation | Methods for bonding, cutting and printing polymeric materials using xerographic printing of IR absorbing material |
US4906497A (en) * | 1987-11-16 | 1990-03-06 | Uzin-Werk Georg Utz Gmbh & Co. Kg | Microwave-activatable hot-melt adhesive |
US5856245A (en) * | 1988-03-14 | 1999-01-05 | Nextec Applications, Inc. | Articles of barrier webs |
US4969968A (en) * | 1988-07-22 | 1990-11-13 | William C. Heller, Jr. | Method of inductive heating with an integrated multiple particle agent |
US4879564A (en) * | 1989-02-02 | 1989-11-07 | Eastman Kodak Company | Ultrasonic dye image fusing |
US5446270A (en) * | 1989-04-07 | 1995-08-29 | Minnesota Mining And Manufacturing Company | Microwave heatable composites |
US5193913A (en) * | 1989-05-11 | 1993-03-16 | Baxter International Inc. | RF energy sealable web of film |
US5238975A (en) * | 1989-10-18 | 1993-08-24 | Minnesota Mining And Manufacturing Company | Microwave radiation absorbing adhesive |
US5189078A (en) * | 1989-10-18 | 1993-02-23 | Minnesota Mining And Manufacturing Company | Microwave radiation absorbing adhesive |
US5346932A (en) * | 1990-01-26 | 1994-09-13 | Shin-Etsu Chemical Co., Ltd. | Silicone rubber composition and method for curing the same |
US5338611A (en) * | 1990-02-20 | 1994-08-16 | Aluminum Company Of America | Method of welding thermoplastic substrates with microwave frequencies |
US5487853A (en) * | 1990-07-12 | 1996-01-30 | The C. A. Lawton Company | Energetic stitching for complex preforms |
US5368199A (en) * | 1990-08-06 | 1994-11-29 | Loctite Corporation | Microwaveable hot melt dispenser |
US5272216A (en) * | 1990-12-28 | 1993-12-21 | Westinghouse Electric Corp. | System and method for remotely heating a polymeric material to a selected temperature |
US5340649A (en) * | 1991-07-03 | 1994-08-23 | Minnesota Mining And Manufacturing | Microwaveable adhesive article and method of use |
US5193362A (en) * | 1991-08-01 | 1993-03-16 | Milliken Research Corporation | Apparatus for textile treatment |
US5217768A (en) * | 1991-09-05 | 1993-06-08 | Advanced Dielectric Technologies | Adhesiveless susceptor films and packaging structures |
US5400460A (en) * | 1992-07-02 | 1995-03-28 | Minnesota Mining And Manufacturing Company | Microwaveable adhesive article and method of use |
US6045648A (en) * | 1993-08-06 | 2000-04-04 | Minnesta Mining And Manufacturing Company | Thermoset adhesive having susceptor particles therein |
US5536921A (en) * | 1994-02-15 | 1996-07-16 | International Business Machines Corporation | System for applying microware energy in processing sheet like materials |
US5804801A (en) * | 1994-03-31 | 1998-09-08 | Lambda Technologies, Inc. | Adhesive bonding using variable frequency microwave energy |
US5798395A (en) * | 1994-03-31 | 1998-08-25 | Lambda Technologies Inc. | Adhesive bonding using variable frequency microwave energy |
US5603795A (en) * | 1994-09-01 | 1997-02-18 | Martin Marietta Energy Systems, Inc. | Joining of thermoplastic substrates by microwaves |
US5770296A (en) * | 1996-08-05 | 1998-06-23 | Senco Products, Inc. | Adhesive device |
US6007662A (en) * | 1996-08-05 | 1999-12-28 | Senco Products, Inc. | Method of adhesively adhering rubber components |
US6266836B1 (en) * | 1996-10-04 | 2001-07-31 | Consejo Superior De Investigaciones Cientificas | Process and device for continuous ultrasonic washing of textile |
US5871872A (en) * | 1997-05-30 | 1999-02-16 | Shipley Company, Ll.C. | Dye incorporated pigments and products made from same |
US5916203A (en) * | 1997-11-03 | 1999-06-29 | Kimberly-Clark Worldwide, Inc. | Composite material with elasticized portions and a method of making the same |
US6103812A (en) * | 1997-11-06 | 2000-08-15 | Lambda Technologies, Inc. | Microwave curable adhesive |
US6024822A (en) * | 1998-02-09 | 2000-02-15 | Ato Findley, Inc. | Method of making disposable nonwoven articles with microwave activatable hot melt adhesive |
US6689730B2 (en) * | 1998-02-20 | 2004-02-10 | The Procter & Gamble Company | Garment stain removal product which uses sonic or ultrasonic waves |
US6600142B2 (en) * | 1998-03-17 | 2003-07-29 | Codaco, Inc. | RF active compositions for use in adhesion, bonding and coating |
US6348679B1 (en) * | 1998-03-17 | 2002-02-19 | Ameritherm, Inc. | RF active compositions for use in adhesion, bonding and coating |
US6673178B2 (en) * | 1999-01-15 | 2004-01-06 | Dr. Hielscher Gmbh | Method for the constant maintenance of the mean gap width between a sonotrode of an ultrasonic system and a tool of an ultrasonic cutting device designed as a counter surface |
US20020074380A1 (en) * | 1999-01-15 | 2002-06-20 | Dr. Hielscher Gmbh | Method for the constant maintenance of the mean gap width between a sonotrode of an ultrasonic system and a tool of an ultrasonic cutting device designed as a counter surface |
US6114676A (en) * | 1999-01-19 | 2000-09-05 | Ramut University Authority For Applied Research And Industrial Development Ltd. | Method and device for drilling, cutting, nailing and joining solid non-conductive materials using microwave radiation |
US6117192A (en) * | 1999-05-24 | 2000-09-12 | Tatecraft Industries, Inc. | Dye composition, dyeing apparatus and dyeing method |
US6855760B1 (en) * | 1999-05-26 | 2005-02-15 | Henkel Kommanditgesellschaft Auf Aktien | Detachable adhesive compounds |
US6203151B1 (en) * | 1999-06-08 | 2001-03-20 | Hewlett-Packard Company | Apparatus and method using ultrasonic energy to fix ink to print media |
US6431702B2 (en) * | 1999-06-08 | 2002-08-13 | Hewlett-Packard Company | Apparatus and method using ultrasonic energy to fix ink to print media |
US6649888B2 (en) * | 1999-09-23 | 2003-11-18 | Codaco, Inc. | Radio frequency (RF) heating system |
US6419798B1 (en) * | 2000-12-15 | 2002-07-16 | Kimberly-Clark Worldwide, Inc. | Methods of making disposable products having materials having shape-memory |
US20050202578A1 (en) * | 2001-10-19 | 2005-09-15 | Nano-Proprietary, Inc. | Ink jet application for carbon nanotubes |
US20030119406A1 (en) * | 2001-12-20 | 2003-06-26 | Abuto Francis Paul | Targeted on-line stabilized absorbent structures |
US6846448B2 (en) * | 2001-12-20 | 2005-01-25 | Kimberly-Clark Worldwide, Inc. | Method and apparatus for making on-line stabilized absorbent materials |
US6652602B2 (en) * | 2001-12-21 | 2003-11-25 | N.V. Bekaert S.A. | Color dyeing system for plastic films |
US6901683B2 (en) * | 2002-02-15 | 2005-06-07 | International Business Machines Corporation | Method and apparatus for electromagnetic drying of printed media |
US20050238804A1 (en) * | 2002-06-13 | 2005-10-27 | Arkady Garbar | Nano-powder-based coating and ink compositions |
US6783623B2 (en) * | 2002-10-23 | 2004-08-31 | Sonoco Development, Inc. | Method of making a dry bonded paperboard structure |
US6734409B1 (en) * | 2002-10-31 | 2004-05-11 | Corning Incorporated | Microwave assisted bonding method and joint |
US20050132906A1 (en) * | 2003-12-19 | 2005-06-23 | Sca Hygiene Products Ab | Production Of A Dyed Patterned Web |
US6938683B2 (en) * | 2004-01-07 | 2005-09-06 | Inventec Corporation | Radiator |
US7034266B1 (en) * | 2005-04-27 | 2006-04-25 | Kimberly-Clark Worldwide, Inc. | Tunable microwave apparatus |
US20080155763A1 (en) * | 2006-12-28 | 2008-07-03 | Kimberly-Clark Worldwide, Inc. | Process for dyeing a textile web |
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US20080192568A1 (en) * | 2004-05-24 | 2008-08-14 | Dr. Hielscher Gmbh | Method and Device For Introducing Ultrasound Into a Flowable Medium |
US8235579B2 (en) * | 2004-05-24 | 2012-08-07 | Dr. Hielscher Gmbh | Device for introducing ultrasound into a flowable medium |
US8182552B2 (en) | 2006-12-28 | 2012-05-22 | Kimberly-Clark Worldwide, Inc. | Process for dyeing a textile web |
US7674300B2 (en) | 2006-12-28 | 2010-03-09 | Kimberly-Clark Worldwide, Inc. | Process for dyeing a textile web |
US7740666B2 (en) | 2006-12-28 | 2010-06-22 | Kimberly-Clark Worldwide, Inc. | Process for dyeing a textile web |
US20080157442A1 (en) * | 2006-12-28 | 2008-07-03 | Kimberly-Clark Worldwide, Inc. | Process For Cutting Textile Webs With Improved Microwave Absorbing Compositions |
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US8632613B2 (en) | 2007-12-27 | 2014-01-21 | Kimberly-Clark Worldwide, Inc. | Process for applying one or more treatment agents to a textile web |
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