US20050221230A1 - Plate for digitally-imaged offset printing - Google Patents

Plate for digitally-imaged offset printing Download PDF

Info

Publication number
US20050221230A1
US20050221230A1 US11/110,950 US11095005A US2005221230A1 US 20050221230 A1 US20050221230 A1 US 20050221230A1 US 11095005 A US11095005 A US 11095005A US 2005221230 A1 US2005221230 A1 US 2005221230A1
Authority
US
United States
Prior art keywords
plate
printing plate
coating
substrate
printing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US11/110,950
Inventor
Murray Figov
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to US11/110,950 priority Critical patent/US20050221230A1/en
Publication of US20050221230A1 publication Critical patent/US20050221230A1/en
Abandoned legal-status Critical Current

Links

Images

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/16Coating processes; Apparatus therefor
    • G03F7/18Coating curved surfaces
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/027Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds

Definitions

  • the present invention generally relates to computer-to-plate (CTP) offset lithographic printing, and more particularly, to an inexpensive and simple, offset printing plate which is digitally-imaged using actinic light.
  • CTP computer-to-plate
  • Offset lithographic printing has remained a most popular method of printing for many years. An important reason for this is the relative ease with which offset lithographic printing plates can be produced.
  • the most widely-used method for plate preparation has remained that which utilizes specially-prepared masking films through which pre-sensitized printing blanks are selectively hardened or softened (according to the chemistry of the plate) by exposure to ultra-violet light.
  • the plate then undergoes a development process, during which the more soluble regions of the plate (which may be exposed or the unexposed areas) are washed away.
  • a detailed description of the system and the plates used can be found in Chapter 20 of the book Printing Materials: Science and Technology by Bob Thompson, published by Pira (Leathershead, London, UK), 1998.
  • U.S. Pat. No. 4,486,529 descries the sensitizing of a negative working diazo system to the 450 nm to 530 nm region for imaging with, for example, argon-ion lasers with most of its energy being emitted in the 488 nm to 514.5 nm region.
  • Such systems require a cover layer of, for example, polyvinyl alcohol to protect against oxygen inhibition and may also require a post-image heating stage.
  • Sensitivity of diazo systems which are used in the coatings of pre-sensitized plates is generally in the region of 150 to 600 mJ/cm 2 .
  • U.S. Pat. No. 5,339,737 Lewis et al describes the processless preparation of offset lithographic printing plates, wherein the upper layer or layers of the plate are ablated away.
  • the upper layer is either oleophobic for waterless plates or hydrophilic for conventional wet-process plates.
  • the substrate is oleophilic in both cases.
  • U.S. Pat. No. 5,353,705 Lewis et al is similar to the previous patent, but describes additional layers for secondary partial ablation.
  • U.S. Pat. No. 5,487,338 is similar, but includes reflective layers.
  • UV-Setter ® CTPs produced by basysPrint GmbH of Boizenburg, Germany. These are flatbed image setter based on a Spatial Light Modulator device working in transmission and a non-coherent UV light source.
  • U.S. patent application Ser. No. 09/312763 assigned to Scitex Corporation describes the invention of a digital image-setter utilizing a high-resolution micro-display which can be used inter alia to image pre-sensitized offset lithographic plates which are sensitive to either UV or visible light.
  • imaging-on-press A reason for simplicity of processing can be found in the development of imaging-on-press.
  • imaging-on-press has been described in, for example, U.S. Pat. No. 3,654,864 (Ovshinski), U.S. Pat. No. 3,741,118 (Carley), and U.S. Pat. No. 4,718,340 (Love III)
  • printing presses incorporating this principle such as the GTODI by Heidelberg, have only appeared within the past few years.
  • Such presses utilize waterless plates imaged by infrared ablation where post-imaging processing is by a cleaning method to remove ablated material, rather than by image development.
  • the processing has to be on press, it has to be relatively simple.
  • UV sensitive offset printing plates All present pre-sensitized UV sensitive offset printing plates have a common constraint.
  • the manufactured plates are coated in continuous rolls in a factory where the plates are then cut to size, boxed and sent to the customer. The plate is removed from the box by the customer and placed on a machine for imagine.
  • UV sensitive plates it has been the general rule that they are placed in emulsion-to-emulsion contact with an imaged masking film, imaged by flood UV and then the film is peeled off before processing the plate in a bath of aqueous alkali. It is an obvious constraint of the plate that the surface must be resistant to damage. The plate must also be dry to the touch.
  • the coating formulation is either confined to substances that produce such a dry layer or have added polymers that must be present in quantities that produce the dry layer.
  • Yet a further object of this invention is to provide a plateless process for offset lithographic printing using an inexpensive imaging system and using the surface of a lithographic printing cylinder itself as a plate substrate.
  • a simple and inexpensive offset lithographic printing plate for use in an offset printing system, said plate being produced in accordance with a method comprising the steps of:
  • the present invention seeks to remove such constraints on coatings for offset lithographic plates as are found in the prior art, and utilizes sticky or wet layers as coatings so that little or no binder is present to interfere with the sensitivity or ease of processing.
  • image processes used with this invention are non-contact and do not require contact of a film mask, having a sticky or liquid surface is not a problem.
  • the coating process is done at the customer's location, and not provided to the customer as a finished and packed plate, handling a sticky or liquid surface is not a problem.
  • the plate is provided with a sticky surface, such surface may be protected from sticking by use of a release layer bonded to a cover film, rather like that provided to sticky labels. It has been found that such coatings do not need processing by strong alkalis, but can be processed more simply as will be described in the various embodiments of the invention.
  • FIG. 1 shows three consecutive, enlarged, sectional views from the prior art of a conventional negative printing plate as it undergoes changes while being processed;
  • FIGS. 2A through 2C show consecutive, enlarged sectional views from the prior art of a typical, thermally-ablated plate in various stages of processing;
  • FIGS. 3A through 3D show consecutive, enlarged sectional views of an embodiment of the invention and a preferred method for the use thereof;
  • FIG. 4 shows another embodiment of the invention as used in a plateless, cylinder system
  • FIGS. 5A through 5C show enlarged sectional views of a further embodiment of the invention and a preferred method for the use thereof.
  • FIG. 1 shows, in a series of enlarged sectional views, an example of the widely-used prior art process of platemaking with pre-sensitized plates.
  • Printing plate 10 comprises a grained, anodized aluminum substrate 12 and an emulsion coating 14 , containing a prepolymer, photoinitiator, binder, resin, and dyes or pigments.
  • a film negative 16 acts as a negative mask in emulsion-to-emulsion contact with plate 10 and is flood-exposed with UV light 20 .
  • the path of UV light 20 to the photosensitive, prepolymeric emulsion coating 14 is blocked by deposits of blackened, light-opaque silver 18 .
  • UV light 20 reaches emulsion coating 14 only in transparent area 22 of the negative image.
  • Exposure of emulsion coating 14 under transparent area 22 activates the photoinitiator component of emulsion coating 14 and initiates polymerization.
  • Negative masking film 16 is then removed from plate 10 which is then passed -through a plate processor (not shown) usually providing a strong aqueous alkali for washing away the unexposed portions of emulsion coating 14 .
  • the binder resin contained in emulsion coating 14 is usually a phenol-formaldehyde type known as Novalak.
  • the resin is not photosensitive and its very presence acts as a diluent for the photosensitive material and consequently reduces the sensitivity of emulsion coating 14 to UV radiation 20 .
  • Emulsion coating 14 is an alkali-soluble resin except that in the polymerized areas, such as under transparent area 22 , emulsion coating 14 is no longer alkali-soluble and remains hardened in place after development. Under image areas corresponding to light-opaque areas 18 , however, the alkali dissolves out of the unexposed, unpolymerized areas of emulsion coating 14 , leaving exposed surface 24 which is hydrophilic.
  • Image area 26 of emulsion coating 14 which remains is an oleophilic and hydrophobic surface.
  • plate 10 is first damped with fountain solution which remains only on exposed, hydrophilic surface 24 and is then inked up, the ink remaining solely on image area 26 since it is oleophilic.
  • Multiple impressions are made by the offset lithographic printing process by successively transferring ink from inked image area 26 of plate 10 to an offset press blanket cylinder (not shown) and then onto the required substrate (not shown) which is usually paper.
  • FIG. 2A shows, in an enlarged sectional view, a typical structure for a thermally-ablated, waterless, offset lithographic plate 13 as known in the prior art.
  • Plate 13 comprises, in its simplest form, a substrate 122 , a thermally-ablatable layer 28 , and a silicone rubber top layer 30 .
  • Substrate 122 often is made up of a think, polyester sheet which is bonded to a grained, anodized aluminum base.
  • FIG. 2B shows, in an enlarged sectional view, plate 13 during exposure to infrared radiation 32 .
  • Ablative layer 28 is heated to a high temperature in localized areas 33 in accordance with a digitized image and undergoes physical and/or chemical changes in these areas ablating portions of top layer 30 which lie above said localized areas 33 in ablative layer 28 which are detached together with said localized areas 33 .
  • FIG. 2C in an enlarged sectional view, shows the exposed image areas 36 on substrate 122 .
  • the remaining portions 34 of top layer 30 act as ink-repellant areas and exposed image areas 36 on substrate 122 provide the ink-receptive areas of said plate 13 .
  • plate 13 In order to ensure that exposed image areas 36 are completely free of silicone residue and ready to receive ink, it is necessary to clean plate 13 after ablation, either by dry rubbing or by washing with a liquid. In the course of the waterless offset lithographic process, plate 13 is inked up, the ink remaining solely on the oleophilic substrate image areas 36 . Multiple impressions are made by the offset lithographic printing process by successively transferring ink from the inked image areas 36 of plate 13 to an offset blanket (not shown) and then onto the required printing substrate (not shown) which is usually paper.
  • FIGS. 3A through 3D there are depicted various enlarged sectional representations of a preferred embodiment of the present invention operated in accordance with the principles of the present invention.
  • substrate 222 is coated in proximity to, or at the imaging stage with photosensitive material 40 which is deposited from container 38 .
  • photosensitive material 40 which is deposited from container 38 .
  • This can be used either as CTP or for imaging-on-press, or for a plateless system.
  • Substrate 222 is preferably grained, anodized aluminum, but could be any hydrophilic substrate known to the art.
  • Photosensitive material 40 is held in a liquid state in container 38 which can advantageously serve as an entire coating applicator device by moving across substrate 222 , applying an exact measure of material 40 uniformly over the surface.
  • material 40 is applied by applicator 42 which could be, for instance, a wire-would rod held in contact with substrate 222 so that the thickness of the coating applied to substrate 222 is controlled by the thickness of the wire used on applicator 42 .
  • applicator 42 could be, for instance, a wire-would rod held in contact with substrate 222 so that the thickness of the coating applied to substrate 222 is controlled by the thickness of the wire used on applicator 42 .
  • the combination of devices 38 and 42 results in a method of application of a uniform liquid layer of material 40 of a controlled thickness laid down upon substrate 222 .
  • container 38 (as shown in FIG. 3 a ) may consist of two or more compartments, each holding one component of material 40 which are mixed shortly before being deposited on substrate 222 . This allows the use of materials which may have a limited pot life after mixing.
  • photosensitive layer 216 As shown in FIG. 3B , after substrate 222 is coated with material 40 , it forms a photosensitive layer 216 which is not subject to any drying process as it contains little or no volatile material.
  • layer 216 is exposed to a UV or visible light source 220 , so as to produce polymerized areas 226 in layer 216 , where exposed to the light source, and unpolymerized areas 46 , where layer 216 remains unexposed.
  • FIG. 3C shows exposed plate 48 being washed, preferably with tap water 50 , or with a dilute aqueous solution to remove unpolymerized areas 46 (shown in FIG. 3B ) of photosensitive material 40 and plate 48 is then ready for printing by a known offset lithographic process.
  • FIG. 3D shows a further step whereby plate 48 , after washing, is flood-exposed with UV or visible light to further harden the polymerized areas 226 prior to printing by a known offset lithographic process.
  • the method of the present invention lends itself to application as a technique of CTP,
  • the information to be printed may be provided as a digital signal in combination with a UV or visible light source, producing an image on an offset printing plate which may subsequently be printed.
  • the method can be adapted for imaging-on-press, the coating devices 38 and 42 (shown in FIG. 3A ) replacing the automatic plate feed devices now available on offset printing machines, and the processing may be done by automatic plate cleaning devices (not shown), also currently available.
  • the imaging device is attached to each plate cylinder.
  • FIG. 4 shows yet another embodiment of the present invention, whereby photosensitive coating 40 is applied directly onto surface 54 of cylinder 52 itself instead of using a cylinder as in an offset machine which normally holds a plate.
  • surface 54 of cylinder 52 provides a reusable plate substrate which is cleaned after the completion of each printing job.
  • Applicator 56 coats surface 54 of cylinder 52 with photosensitive material 40 .
  • the prepolymer coating formed is then digitally-imaged with UV or visible light source 220 which polymerizes the image areas 326 . Any unpolymerized material 46 remaining on surface 54 of cylinder 52 is washed away by washing means 62 which contains an aqueous liquid.
  • the imaged and inked cylinder 52 is then printed by applying a fount from a conventional fountain system 64 and inking by means of an ink train 66 .
  • the ink is transferred from cylinder surface 54 to blanket cylinder 68 and thereafter printed in a known offset lithographic process.
  • the entire layer of imaged material 326 is removed, either by abrasion or by means of a non-volatile solvent oil, thus erasing the image.
  • An example of such an oil is ethyl lactate.
  • the cycle can then be repeated by reapplying the photosensitive prepolymer material 40 .
  • a manufactured plate 70 is supplied directly to the customer and comprises substrate 322 , which, in a preferred embodiment, is comprised of grained, anodized aluminum, but generally characterized by a hydrophilic surface and a photosensitive coating 314 , which also contains a small amount of non-light-sensitive binder.
  • substrate 322 which, in a preferred embodiment, is comprised of grained, anodized aluminum, but generally characterized by a hydrophilic surface and a photosensitive coating 314 , which also contains a small amount of non-light-sensitive binder.
  • Such a coating would be sticky to the touch and therefore, film 17 , comprising polypropylene, polyester or the like, with a release coating 316 , such as silicone, is also provided.
  • a sticky layer is applied to the hydrophilic anodized and grained aluminum substrate 322 in the manufacturing process, during which a release film is laminated onto the coating.
  • the imaging can be done with or without the film in place.
  • any film between the masking image intermediate and the sensitive coating of the offset plate could reduce the image quality.
  • CTP imaging without a masking film this not the case.
  • the release film remains, it provides an oxygen barrier and thus enhances the sensitivity of oxygen-inhibited photosensitive coatings.
  • film 17 with release coating 316 is laid upon the sticky surface of coating 314 .
  • Manufacturing is accomplished in on continuous process involving coating substrate 322 with a solution comprising a volatile solvent; evaporating the solvent; and then laminating film 17 with release coating 316 onto plate 70 .
  • the customer receives a box of plates manufactured as described above and shown in FIG. 5A . These are for use in a CTP system in combination with a digitally-controlled UV or visible light source. Film 17 acts as a cover and provides a means of oxygen exclusion as well as giving optimum sensitive and ease of development with aqueous solutions to the processing of plate 70 .
  • photosensitive coating 314 is polymerized in imaged areas 26 after digital exposure to UV light 320 .
  • Film 17 together with its attached release coating 316 , is then peeled away and the unexposed, unpolymerized material of photosensitive coating 314 is washed away with water or water containing minimal additives, leaving polymerized imaged areas 326 on substrate 322 , as shown in FIG. 5C .
  • Plate 70 is then ready for printing by a known offset lithographic process.
  • a minimal amount of non-active binder is beneficial in providing some pre-polymerization bonding to substrate 322 to prevent distortion of layer uniformity caused by pressure from the release film, this is not the case in the embodiment where coating material 40 is supplied separately for application by the user. In this case, use of a non-active binder is not necessary. In both cases, the processing is done by washing in water or by use of a very dilute aqueous solution containing additives to aid washing. The inventor has found that even though the composition used may be insoluble and immiscible with water, nevertheless, they are removed by water washing.
  • part or all of the photopolymer precursors which may be oligomers or monomers are themselves water-soluble or miscible.
  • whatever binder resin is present is water-soluble, while in the case of the embodiment where coating material 40 is applied by the user, water washability is achieved because material 40 is unpolymerized and in the form of a sticky liquid or semi-sold.
  • composition of the layer there is a large range of suitable pre-polymer mixtures that may be used.
  • the mixture may consist of oligomers, monomer and diluents together with photoinitiators and synergists and dye colorants.
  • a small amount of binder should be added.
  • This binder should be soluble in water or may be soluble in a dilute aqueous alkali such as provided by small quantities of sodium carbonate or sodium borate.
  • suitable binders are hydroxypropyl cellulose, poly(2-ethyl-2-oxazoline), polymethylvinyl either alt maleic acid, and styrene maleic anhydride copolymers and derivatives. The total amount of this polymer does not exceed 15% by weight of the solids content of the coating.
  • the coating may comprise volatile solvents or solvent mixtures such a methyl ethyl ketone, ethyl alcohol, toluene, ethyl acetate or butyl acetate.
  • volatile solvents such as a methyl ethyl ketone, ethyl alcohol, toluene, ethyl acetate or butyl acetate.
  • VOC's volatile organic compounds
  • solventless coatings characterized as 100% solids whereby, even though the coating material is a liquid under the conditions of coating, the entire coating is capable of polymerization without any material evaporating into the atmosphere.
  • oligomers and monomers there are a large variety of photopolymerizable oligomers and monomers as well as diluents that have been found to be advantageous for use in the present invention. It is preferable to have water-soluble oligomers, monomers and diluents present because this makes the washing off of the unpolymerized coating extremely easy.
  • water-soluble oligomers, monomers and diluents are polyethylene glycol diacrylates, ethoxylated trimethylol propane acrylate and polyether acrylates.
  • Examples of monomers are 2 hydroxy-3-methylacryloxy propyltrimethylammonium chloride, hydroxyalkyl acrylate and dimethylaminoethyl acrylate.
  • Examples of water-soluble diluents are N-methyl pyrrolidone, 2-amino ethanol, ethyl lactate and mopholine. Not all of the olgomer and monomer content needs to be water-soluble, and materials can also be chosen for their high reactivity and good adhesion to the aluminum base, once polymerized.
  • Examples of oligomers and monomers found useful are tris(2-hydroxyethyl) isocyanurate triacrylate, carboxyl functional multifunctional methacrylate oligomers, and polyurethane acrylates.
  • such materials as amine syergists and surfactants to improve coating properties may also be present.
  • the above-described formulation was mixed and then heated to 50° C. and maintained at that temperature until a clear solution was obtained.
  • the mixture was coated onto a grained, anodized aluminum plate with a wire-wound rod to produce a minimal continuous layer.
  • the layer was selectively exposed to a UV source of 300 nm to 400 nm to an extent of 200 micro-joules/cm 2 .
  • the unexposed material was washed away under running water drawn from a tap.
  • the resulting image was inked up with offset lithographic ink and printed in an offset lithographic process known to the art.

Abstract

A plateless process for offset lithographic printing using an inexpensive imaging system and using the surface of a lithographic printing cylinder itself as a plate substrate. The process enables production of a simple and inexpensive offset lithographic printing plate for use in an offset printing system, with the plate being produced by coating the substrate of the printing plate with a photosensitive liquid coating, and sealing the coated substrate with a release coating, coated on a protective film.

Description

    CROSS-REFERENCE TO RELATED APPLICATIONS
  • The present application is a divisional application of U.S. patent application Ser. No. 10/148,913 filed Jun. 5, 2002.
  • FIELD OF THE INVENTION
  • The present invention generally relates to computer-to-plate (CTP) offset lithographic printing, and more particularly, to an inexpensive and simple, offset printing plate which is digitally-imaged using actinic light.
  • BACKGROUND OF THE INVENTION
  • Offset lithographic printing has remained a most popular method of printing for many years. An important reason for this is the relative ease with which offset lithographic printing plates can be produced. Currently, the most widely-used method for plate preparation has remained that which utilizes specially-prepared masking films through which pre-sensitized printing blanks are selectively hardened or softened (according to the chemistry of the plate) by exposure to ultra-violet light. The plate then undergoes a development process, during which the more soluble regions of the plate (which may be exposed or the unexposed areas) are washed away. A detailed description of the system and the plates used can be found in Chapter 20 of the book Printing Materials: Science and Technology by Bob Thompson, published by Pira (Leathershead, Sussex, UK), 1998.
  • In recent years, various considerations have arisen that point to advantages for modification of hitherto generally-accepted practices. With the advent of computers, information for printing is prepared digitally and it has become preferable to use this digital information as directly as possible in plate preparation. One obvious way would be to eliminate the masking film. Not only are these films a source of expense, but the most widely-used films are based on silver chemistry whereby the exposure and handling of the film must be in a light-excluding environment. In addition, the exposed film must be processed with chemical solutions which are unstable, messy and environmentally problematic.
  • One answer is to be found in computer-to-plate (CTP) systems whereby the offset lithographic plates are directly imaged with a light source which is modulated to correspond to the digital information from the computer. Thus the film intermediate is completely eliminated. It would have been easy and convenient if the UV sensitive pre-sensitized plates previously used for imaging with an intermediate film could have been used for direct digital imaging. However, it has been found necessary to either sensitize plates for imaging with visible light or to develop plates that are sensitive to radiation in the near infrared. The reason for this is that UV lasers are very expensive and difficult to modulate. Visible and infrared lasers are more readily available and less costly and easier to modulate to produce the digital signal necessary for imaging.
  • U.S. Pat. No. 4,486,529 descries the sensitizing of a negative working diazo system to the 450 nm to 530 nm region for imaging with, for example, argon-ion lasers with most of its energy being emitted in the 488 nm to 514.5 nm region. Such systems require a cover layer of, for example, polyvinyl alcohol to protect against oxygen inhibition and may also require a post-image heating stage. Sensitivity of diazo systems which are used in the coatings of pre-sensitized plates is generally in the region of 150 to 600 mJ/cm2. This type of plate, like most pre-sensitized plates, needs processing with a strong alkali, although attempts are being made to develop CTP systems that are processless. The subject of CTP systems can be found in Chapter 21 of the book )Thompson, 1998) cited above.
  • U.S. Pat. No. 5,339,737 Lewis et al describes the processless preparation of offset lithographic printing plates, wherein the upper layer or layers of the plate are ablated away. The upper layer is either oleophobic for waterless plates or hydrophilic for conventional wet-process plates. The substrate is oleophilic in both cases. U.S. Pat. No. 5,353,705 Lewis et al is similar to the previous patent, but describes additional layers for secondary partial ablation. U.S. Pat. No. 5,487,338 is similar, but includes reflective layers.
  • All of these inventions involve multi-layered plates which are expensive to produce. Also, for such multi-coated systems, it is more difficult to maintain a consistent standard of quality from plate to plate. So called processless plates that are imaged by laser ablation either involve a scrubbing stage to remove ablated debris from the surface, or they need extraction systems to remove debris ‘on the fly’ as it is being produced during imagine.
  • Recently, it has been found that there are ways of imaging UV-sensitive plates by digital means, permitting the development of machines for use in CTP systems. Examples of this are the UV-Setter ®, CTPs produced by basysPrint GmbH of Boizenburg, Germany. These are flatbed image setter based on a Spatial Light Modulator device working in transmission and a non-coherent UV light source. U.S. patent application Ser. No. 09/312763 assigned to Scitex Corporation, describes the invention of a digital image-setter utilizing a high-resolution micro-display which can be used inter alia to image pre-sensitized offset lithographic plates which are sensitive to either UV or visible light.
  • With the development of these technologies, there is a need for inexpensive plates highly-sensitive to either UV or visible light. It would also be beneficial to be able to process the plate without recourse to highly-alkaline solutions that, in many countries, is prohibited by law from being disposed of in sewage systems due to environmental hazards.
  • A reason for simplicity of processing can be found in the development of imaging-on-press. Although the concept of imaging-on-press has been described in, for example, U.S. Pat. No. 3,654,864 (Ovshinski), U.S. Pat. No. 3,741,118 (Carley), and U.S. Pat. No. 4,718,340 (Love III), printing presses incorporating this principle, such as the GTODI by Heidelberg, have only appeared within the past few years. Such presses utilize waterless plates imaged by infrared ablation where post-imaging processing is by a cleaning method to remove ablated material, rather than by image development. As the processing has to be on press, it has to be relatively simple.
  • Further developments in plate design have followed the path of elimination of a plate substrate and, in its stead, the press cylinder which traditionally holds the plate becomes a reusable lithographic ‘master’ surface. U.S. Pat. No. 4,718,340 (Love III) describes such a process which, in one embodiment, spreads an oleophilic material onto a hydrophilic surface and then removes oleophilic material from the non-image areas. As is stated in the Abstract of this prior-art patent, no photo-induced chemical reaction or latent imaging development steps are required at any time.
  • All present pre-sensitized UV sensitive offset printing plates have a common constraint. The manufactured plates are coated in continuous rolls in a factory where the plates are then cut to size, boxed and sent to the customer. The plate is removed from the box by the customer and placed on a machine for imagine. In the case of UV sensitive plates, it has been the general rule that they are placed in emulsion-to-emulsion contact with an imaged masking film, imaged by flood UV and then the film is peeled off before processing the plate in a bath of aqueous alkali. It is an obvious constraint of the plate that the surface must be resistant to damage. The plate must also be dry to the touch. Although this latter constraint has been removed if non-contact imaging as used in CTP is involved, it is a constraint that hitherto has not been appreciated as restrictive in certain areas of performance. In order to achieve dry coatings, the coating formulation is either confined to substances that produce such a dry layer or have added polymers that must be present in quantities that produce the dry layer. The presence of such polymers, and limitations of the kind of photosensitive materials used to produce the dry layers, reduces opportunities to optimize coating sensitivity and simplicity of processing.
  • SUMMARY OF THE INVENTION
  • Accordingly, it is a principal object of the present invention to overcome the disadvantages associated with prior art digitally-imaged offset plates by providing an inexpensive and simple offset plate sensitive to UV or visible light that can then be imaged digitally therewith and also processed in a simple manner.
  • It is another object of this invention to provide photopolymer plates with increased sensitivity over previous photopolymer printing plates.
  • It is still a further object of this invention to provide a CTP method that can utilize an inexpensive UV or visible light source.
  • It is still another object of this invention to provide a simple imaging-on-press system that can utilize inexpensive plates as well as an inexpensive imaging system in the UV or visible region.
  • Yet a further object of this invention is to provide a plateless process for offset lithographic printing using an inexpensive imaging system and using the surface of a lithographic printing cylinder itself as a plate substrate.
  • In accordance with a preferred method of the present invention there is provided a simple and inexpensive offset lithographic printing plate for use in an offset printing system, said plate being produced in accordance with a method comprising the steps of:
  • a) coating the substrate of said printing plate with a photosensitive liquid coating; and
  • b) sealing said coated substrate with a release coating, coated on a protective film.
  • The present invention seeks to remove such constraints on coatings for offset lithographic plates as are found in the prior art, and utilizes sticky or wet layers as coatings so that little or no binder is present to interfere with the sensitivity or ease of processing. As the image processes used with this invention are non-contact and do not require contact of a film mask, having a sticky or liquid surface is not a problem.
  • Also, in the preferred embodiments described, since the coating process is done at the customer's location, and not provided to the customer as a finished and packed plate, handling a sticky or liquid surface is not a problem. Where the plate is provided with a sticky surface, such surface may be protected from sticking by use of a release layer bonded to a cover film, rather like that provided to sticky labels. It has been found that such coatings do not need processing by strong alkalis, but can be processed more simply as will be described in the various embodiments of the invention.
  • Other features and advantages of the present invention will become clear from the further detailed description and examples.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • For a better understanding of the invention with regard to the embodiments thereof, reference is made to the accompanying drawings, (shown not to scale), in which like numerals designate corresponding elements or sections throughout, and in which:
  • FIG. 1 shows three consecutive, enlarged, sectional views from the prior art of a conventional negative printing plate as it undergoes changes while being processed;
  • FIGS. 2A through 2C show consecutive, enlarged sectional views from the prior art of a typical, thermally-ablated plate in various stages of processing;
  • FIGS. 3A through 3D show consecutive, enlarged sectional views of an embodiment of the invention and a preferred method for the use thereof;
  • FIG. 4 shows another embodiment of the invention as used in a plateless, cylinder system; and
  • FIGS. 5A through 5C show enlarged sectional views of a further embodiment of the invention and a preferred method for the use thereof.
  • DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
  • Referring now to the drawings, FIG. 1 shows, in a series of enlarged sectional views, an example of the widely-used prior art process of platemaking with pre-sensitized plates. Printing plate 10 comprises a grained, anodized aluminum substrate 12 and an emulsion coating 14, containing a prepolymer, photoinitiator, binder, resin, and dyes or pigments. A film negative 16 acts as a negative mask in emulsion-to-emulsion contact with plate 10 and is flood-exposed with UV light 20. The path of UV light 20 to the photosensitive, prepolymeric emulsion coating 14 is blocked by deposits of blackened, light-opaque silver 18.
  • Thus, UV light 20 reaches emulsion coating 14 only in transparent area 22 of the negative image. Exposure of emulsion coating 14 under transparent area 22 activates the photoinitiator component of emulsion coating 14 and initiates polymerization. Negative masking film 16 is then removed from plate 10 which is then passed -through a plate processor (not shown) usually providing a strong aqueous alkali for washing away the unexposed portions of emulsion coating 14.
  • The binder resin contained in emulsion coating 14 is usually a phenol-formaldehyde type known as Novalak. The resin is not photosensitive and its very presence acts as a diluent for the photosensitive material and consequently reduces the sensitivity of emulsion coating 14 to UV radiation 20. Emulsion coating 14 is an alkali-soluble resin except that in the polymerized areas, such as under transparent area 22, emulsion coating 14 is no longer alkali-soluble and remains hardened in place after development. Under image areas corresponding to light-opaque areas 18, however, the alkali dissolves out of the unexposed, unpolymerized areas of emulsion coating 14, leaving exposed surface 24 which is hydrophilic.
  • Image area 26 of emulsion coating 14 which remains is an oleophilic and hydrophobic surface. In the course of the offset lithographic process, plate 10 is first damped with fountain solution which remains only on exposed, hydrophilic surface 24 and is then inked up, the ink remaining solely on image area 26 since it is oleophilic. Multiple impressions are made by the offset lithographic printing process by successively transferring ink from inked image area 26 of plate 10 to an offset press blanket cylinder (not shown) and then onto the required substrate (not shown) which is usually paper.
  • FIG. 2A shows, in an enlarged sectional view, a typical structure for a thermally-ablated, waterless, offset lithographic plate 13 as known in the prior art. Plate 13 comprises, in its simplest form, a substrate 122, a thermally-ablatable layer 28, and a silicone rubber top layer 30. Substrate 122 often is made up of a think, polyester sheet which is bonded to a grained, anodized aluminum base.
  • FIG. 2B shows, in an enlarged sectional view, plate 13 during exposure to infrared radiation 32. Ablative layer 28 is heated to a high temperature in localized areas 33 in accordance with a digitized image and undergoes physical and/or chemical changes in these areas ablating portions of top layer 30 which lie above said localized areas 33 in ablative layer 28 which are detached together with said localized areas 33.
  • FIG. 2C, in an enlarged sectional view, shows the exposed image areas 36 on substrate 122. The remaining portions 34 of top layer 30 act as ink-repellant areas and exposed image areas 36 on substrate 122 provide the ink-receptive areas of said plate 13.
  • In order to ensure that exposed image areas 36 are completely free of silicone residue and ready to receive ink, it is necessary to clean plate 13 after ablation, either by dry rubbing or by washing with a liquid. In the course of the waterless offset lithographic process, plate 13 is inked up, the ink remaining solely on the oleophilic substrate image areas 36. Multiple impressions are made by the offset lithographic printing process by successively transferring ink from the inked image areas 36 of plate 13 to an offset blanket (not shown) and then onto the required printing substrate (not shown) which is usually paper.
  • Referring now to FIGS. 3A through 3D, there are depicted various enlarged sectional representations of a preferred embodiment of the present invention operated in accordance with the principles of the present invention.
  • As shown in FIG. 3A, substrate 222 is coated in proximity to, or at the imaging stage with photosensitive material 40 which is deposited from container 38. Thus the cost of making a plate becomes relatively low as the customer purchases an uncoated plate plus a photosensitive coating solution. This can be used either as CTP or for imaging-on-press, or for a plateless system.
  • Substrate 222 is preferably grained, anodized aluminum, but could be any hydrophilic substrate known to the art. Photosensitive material 40 is held in a liquid state in container 38 which can advantageously serve as an entire coating applicator device by moving across substrate 222, applying an exact measure of material 40 uniformly over the surface.
  • In yet another embodiment, material 40 is applied by applicator 42 which could be, for instance, a wire-would rod held in contact with substrate 222 so that the thickness of the coating applied to substrate 222 is controlled by the thickness of the wire used on applicator 42. The combination of devices 38 and 42 results in a method of application of a uniform liquid layer of material 40 of a controlled thickness laid down upon substrate 222.
  • In still another embodiment of the present invention (not shown), container 38 (as shown in FIG. 3 a) may consist of two or more compartments, each holding one component of material 40 which are mixed shortly before being deposited on substrate 222. This allows the use of materials which may have a limited pot life after mixing.
  • As shown in FIG. 3B, after substrate 222 is coated with material 40, it forms a photosensitive layer 216 which is not subject to any drying process as it contains little or no volatile material. In accordance with digital-imaging control signals pre-programmed by a user, layer 216 is exposed to a UV or visible light source 220, so as to produce polymerized areas 226 in layer 216, where exposed to the light source, and unpolymerized areas 46, where layer 216 remains unexposed.
  • FIG. 3C shows exposed plate 48 being washed, preferably with tap water 50, or with a dilute aqueous solution to remove unpolymerized areas 46 (shown in FIG. 3B) of photosensitive material 40 and plate 48 is then ready for printing by a known offset lithographic process.
  • FIG. 3D shows a further step whereby plate 48, after washing, is flood-exposed with UV or visible light to further harden the polymerized areas 226 prior to printing by a known offset lithographic process.
  • Although al of the steps are depicted here as flat-bed, either the entire process can be arranged around a cylinder, or the coating can be flat-bed, as shown, and exposure to UV or visible light source can also be done either on a cylinder or a flat-bed.
  • The method of the present invention lends itself to application as a technique of CTP, The information to be printed may be provided as a digital signal in combination with a UV or visible light source, producing an image on an offset printing plate which may subsequently be printed.
  • Alternatively, in a further embodiment (not shown), the method can be adapted for imaging-on-press, the coating devices 38 and 42 (shown in FIG. 3A) replacing the automatic plate feed devices now available on offset printing machines, and the processing may be done by automatic plate cleaning devices (not shown), also currently available. In accordance with this preferred embodiment, the imaging device is attached to each plate cylinder.
  • FIG. 4 shows yet another embodiment of the present invention, whereby photosensitive coating 40 is applied directly onto surface 54 of cylinder 52 itself instead of using a cylinder as in an offset machine which normally holds a plate. Thus, in the plateless process depicted here, surface 54 of cylinder 52 provides a reusable plate substrate which is cleaned after the completion of each printing job. Applicator 56 coats surface 54 of cylinder 52 with photosensitive material 40. The prepolymer coating formed is then digitally-imaged with UV or visible light source 220 which polymerizes the image areas 326. Any unpolymerized material 46 remaining on surface 54 of cylinder 52 is washed away by washing means 62 which contains an aqueous liquid.
  • The imaged and inked cylinder 52 is then printed by applying a fount from a conventional fountain system 64 and inking by means of an ink train 66. The ink is transferred from cylinder surface 54 to blanket cylinder 68 and thereafter printed in a known offset lithographic process. After the required number of copies have been produced, the entire layer of imaged material 326 is removed, either by abrasion or by means of a non-volatile solvent oil, thus erasing the image. An example of such an oil is ethyl lactate. The cycle can then be repeated by reapplying the photosensitive prepolymer material 40.
  • Another preferred embodiment of the present invention is depicted in FIGS. 5A through 5C. A manufactured plate 70 is supplied directly to the customer and comprises substrate 322, which, in a preferred embodiment, is comprised of grained, anodized aluminum, but generally characterized by a hydrophilic surface and a photosensitive coating 314, which also contains a small amount of non-light-sensitive binder. Such a coating would be sticky to the touch and therefore, film 17, comprising polypropylene, polyester or the like, with a release coating 316, such as silicone, is also provided. A sticky layer is applied to the hydrophilic anodized and grained aluminum substrate 322 in the manufacturing process, during which a release film is laminated onto the coating. This permits easy handling of the film during packaging and loading into the CTP system. The imaging can be done with or without the film in place. Generally, for UV imaging, any film between the masking image intermediate and the sensitive coating of the offset plate could reduce the image quality. But for CTP imaging without a masking film, this not the case. Moreover, if the release film remains, it provides an oxygen barrier and thus enhances the sensitivity of oxygen-inhibited photosensitive coatings.
  • During manufacture, film 17 with release coating 316 is laid upon the sticky surface of coating 314. Manufacturing is accomplished in on continuous process involving coating substrate 322 with a solution comprising a volatile solvent; evaporating the solvent; and then laminating film 17 with release coating 316 onto plate 70.
  • The customer receives a box of plates manufactured as described above and shown in FIG. 5A. These are for use in a CTP system in combination with a digitally-controlled UV or visible light source. Film 17 acts as a cover and provides a means of oxygen exclusion as well as giving optimum sensitive and ease of development with aqueous solutions to the processing of plate 70.
  • As shown in FIG. 5B, photosensitive coating 314 is polymerized in imaged areas 26 after digital exposure to UV light 320. Film 17, together with its attached release coating 316, is then peeled away and the unexposed, unpolymerized material of photosensitive coating 314 is washed away with water or water containing minimal additives, leaving polymerized imaged areas 326 on substrate 322, as shown in FIG. 5C. Plate 70 is then ready for printing by a known offset lithographic process.
  • Although in the embodiment provided with a release film, a minimal amount of non-active binder is beneficial in providing some pre-polymerization bonding to substrate 322 to prevent distortion of layer uniformity caused by pressure from the release film, this is not the case in the embodiment where coating material 40 is supplied separately for application by the user. In this case, use of a non-active binder is not necessary. In both cases, the processing is done by washing in water or by use of a very dilute aqueous solution containing additives to aid washing. The inventor has found that even though the composition used may be insoluble and immiscible with water, nevertheless, they are removed by water washing.
  • However, it is preferable that part or all of the photopolymer precursors which may be oligomers or monomers are themselves water-soluble or miscible. In the embodiment providing a manufactured plate, whatever binder resin is present is water-soluble, while in the case of the embodiment where coating material 40 is applied by the user, water washability is achieved because material 40 is unpolymerized and in the form of a sticky liquid or semi-sold.
  • In defining the composition of the layer, there is a large range of suitable pre-polymer mixtures that may be used. The mixture may consist of oligomers, monomer and diluents together with photoinitiators and synergists and dye colorants.
  • Optionally, in the embodiment where the user is provided with an uncoated plate and some coating material, and preferably, in the embodiment providing a manufactured plate, as shown in FIG. 5, a small amount of binder should be added. This binder should be soluble in water or may be soluble in a dilute aqueous alkali such as provided by small quantities of sodium carbonate or sodium borate. Examples of suitable binders are hydroxypropyl cellulose, poly(2-ethyl-2-oxazoline), polymethylvinyl either alt maleic acid, and styrene maleic anhydride copolymers and derivatives. The total amount of this polymer does not exceed 15% by weight of the solids content of the coating.
  • In the case of the embodiment where a finished, manufactured plate is sold to the customer, the coating may comprise volatile solvents or solvent mixtures such a methyl ethyl ketone, ethyl alcohol, toluene, ethyl acetate or butyl acetate. Such solvents are termed VOC's (volatile organic compounds) and are subject to strict control. They are more suitable for use and more manageable in a manufacturing plant where the solvent can be either recovered or incinerated. Where the coating is done in a customer environment, this is less appropriate and where a small amount of volatile solvent (less than 5% of total formulation) may be tolerated, it is most preferable to utilize solventless coatings characterized as 100% solids whereby, even though the coating material is a liquid under the conditions of coating, the entire coating is capable of polymerization without any material evaporating into the atmosphere.
  • There are a large variety of photopolymerizable oligomers and monomers as well as diluents that have been found to be advantageous for use in the present invention. It is preferable to have water-soluble oligomers, monomers and diluents present because this makes the washing off of the unpolymerized coating extremely easy. Examples of such oligomers are polyethylene glycol diacrylates, ethoxylated trimethylol propane acrylate and polyether acrylates.
  • Examples of monomers are 2 hydroxy-3-methylacryloxy propyltrimethylammonium chloride, hydroxyalkyl acrylate and dimethylaminoethyl acrylate. Examples of water-soluble diluents are N-methyl pyrrolidone, 2-amino ethanol, ethyl lactate and mopholine. Not all of the olgomer and monomer content needs to be water-soluble, and materials can also be chosen for their high reactivity and good adhesion to the aluminum base, once polymerized. Examples of oligomers and monomers found useful are tris(2-hydroxyethyl) isocyanurate triacrylate, carboxyl functional multifunctional methacrylate oligomers, and polyurethane acrylates.
  • In addition, such materials as amine syergists and surfactants to improve coating properties may also be present.
  • The following is an example of a formulation suitable for the preferred embodiment (all parts by weight).
    Tris (2-hydroxyethyl) isocyanurate triacrylate 50
    2-methyll-1-[4(methylthio)phenyl]-2-morpholino propan-1-one 4
    2-benzyl-2-N,N-dimethylamino-1-(4-morpholinophenyl)-1- 4.3
    butanone
    Isopropylthioxanthone 5.3
    CN 435 (polyether trifunctional acrylate, sold by Cray Valley 30
    Products of Exton, Pa, USA)
    BYK 306 (silicone surface active agent sold by BYK-Cera, 1
    AM Deventer, Holland)
    Rose Bengal 1.8
    Triisopropanolamine 1.9
  • The above-described formulation was mixed and then heated to 50° C. and maintained at that temperature until a clear solution was obtained. The mixture was coated onto a grained, anodized aluminum plate with a wire-wound rod to produce a minimal continuous layer. The layer was selectively exposed to a UV source of 300 nm to 400 nm to an extent of 200 micro-joules/cm2. The unexposed material was washed away under running water drawn from a tap. The resulting image was inked up with offset lithographic ink and printed in an offset lithographic process known to the art.
  • Having described the present invention with regard to certain specific embodiments thereof, it is to be understood that the description is not meant as a limitation, since further modifications may now suggest themselves to those skilled in the art, and it is intended to cover such modifications as fall within the scope of the appended claims.

Claims (8)

1. An offset lithographic printing plate for use in an offset printing system, said plate being produced in accordance with a method comprising the steps of:
a) coating the substrate of said printing plate with a photosensitive liquid coating; and
b) sealing said coated substrate with a release coating, coated on a protective film.
2. The printing plate of claim 1 wherein said substrate is comprised of a hydrophilic surface.
3. The printing plate of claim 1 wherein said substrate is comprised of grained, anodized aluminum.
4. The printing plate of claim 1 wherein said liquid coating comprises a small amount of non-light-sensitive binder.
5. The printing plate of claim 1, wherein said release coating is comprised of silicone.
6. The printing plate of claim 1 wherein said protective film is comprised of polypropelene.
7. The printing plate of claim 1 wherein said protective film is comprised of polyester.
8. The printing plate of claim 1 wherein, after said coating and sealing steps, said printing plate is readied for printing in an offset lithographic press in the further steps comprising:
a) mounting said printing plate into a CTP imaging system;
b) providing an actinic light source controlled by said CTP imaging system;
c) imaging said printing plate using actinic light from said actinic light source;
d) removing said protective film and said release coating from said printing plate after exposure to said actinic light; and
e) washing said printing plate with an aqueous solution to remove unpolymerized portions of said liquid coating.
US11/110,950 1999-12-07 2005-04-21 Plate for digitally-imaged offset printing Abandoned US20050221230A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US11/110,950 US20050221230A1 (en) 1999-12-07 2005-04-21 Plate for digitally-imaged offset printing

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
IL133355 1999-12-07
IL13335599A IL133355A (en) 1999-12-07 1999-12-07 Method and plate for digitally-imaged offset printing
US10/148,913 US6899998B2 (en) 1999-12-07 2000-12-05 Method and a plate for digitally-imaged offset printing
PCT/IL2000/000818 WO2001042856A2 (en) 1999-12-07 2000-12-05 A method and a plate for digitally-imaged offset printing
WOPCT/IL00/00818 2000-12-05
US11/110,950 US20050221230A1 (en) 1999-12-07 2005-04-21 Plate for digitally-imaged offset printing

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
US10/148,913 Division US6899998B2 (en) 1999-12-07 2000-12-05 Method and a plate for digitally-imaged offset printing

Publications (1)

Publication Number Publication Date
US20050221230A1 true US20050221230A1 (en) 2005-10-06

Family

ID=11073576

Family Applications (2)

Application Number Title Priority Date Filing Date
US10/148,913 Expired - Fee Related US6899998B2 (en) 1999-12-07 2000-12-05 Method and a plate for digitally-imaged offset printing
US11/110,950 Abandoned US20050221230A1 (en) 1999-12-07 2005-04-21 Plate for digitally-imaged offset printing

Family Applications Before (1)

Application Number Title Priority Date Filing Date
US10/148,913 Expired - Fee Related US6899998B2 (en) 1999-12-07 2000-12-05 Method and a plate for digitally-imaged offset printing

Country Status (7)

Country Link
US (2) US6899998B2 (en)
JP (1) JP2003516564A (en)
AU (1) AU1729901A (en)
CA (1) CA2393807A1 (en)
DE (1) DE10085272T1 (en)
IL (1) IL133355A (en)
WO (1) WO2001042856A2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070101883A1 (en) * 2005-11-07 2007-05-10 Xerox Corporation Printing system using shape-changing materials
US20090155994A1 (en) * 2007-12-12 2009-06-18 Hawkins Gilbert A Forming thin film transistors using ablative films with pre-patterned conductors

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6566039B1 (en) 2002-06-04 2003-05-20 Gary Ganghui Teng Variable data lithographic printing device and method
US7005232B2 (en) 2003-06-16 2006-02-28 Napp Systems, Inc. Highly reflective substrates for the digital processing of photopolymer printing plates
US8343707B2 (en) 2005-07-29 2013-01-01 Anocoil Corporation Lithographic printing plate for in-solidus development on press
US8133658B2 (en) * 2005-07-29 2012-03-13 Anocoil Corporation Non-chemical development of printing plates
WO2007016109A2 (en) 2005-07-29 2007-02-08 Anocoil Corporation Imageable printing plate for on-press development
US8137897B2 (en) * 2005-07-29 2012-03-20 Anocoil Corporation Processless development of printing plate
US8377630B2 (en) * 2005-07-29 2013-02-19 Anocoil Corporation On-press plate development without contamination of fountain fluid
US7554566B2 (en) * 2006-07-07 2009-06-30 Hewlett-Packard Development Company, L.P. Image development methods, hard imaging devices, and image members
BR102012016393A2 (en) 2012-07-02 2015-04-07 Rexam Beverage Can South America S A Can printing device, can printing process, printed can and blanket
ES2842224T3 (en) 2013-06-11 2021-07-13 Ball Corp Printing procedure using soft photopolymer plates
US9555616B2 (en) 2013-06-11 2017-01-31 Ball Corporation Variable printing process using soft secondary plates and specialty inks
US10086602B2 (en) 2014-11-10 2018-10-02 Rexam Beverage Can South America Method and apparatus for printing metallic beverage container bodies
ES2734983T3 (en) 2014-12-04 2019-12-13 Ball Beverage Packaging Europe Ltd Printing apparatus
WO2016115640A1 (en) * 2015-01-23 2016-07-28 Li Minggan Methods and apparatus for creation of wrinkles in three-dimensional surfaces, and compositions of matter resulting from same
US10549921B2 (en) 2016-05-19 2020-02-04 Rexam Beverage Can Company Beverage container body decorator inspection apparatus
EP3487706A4 (en) 2016-07-20 2020-04-08 Ball Corporation System and method for aligning an inker of a decorator
US11034145B2 (en) 2016-07-20 2021-06-15 Ball Corporation System and method for monitoring and adjusting a decorator for containers
MX2019001607A (en) 2016-08-10 2019-11-08 Ball Corp Method and apparatus of decorating a metallic container by digital printing to a transfer blanket.
US10739705B2 (en) 2016-08-10 2020-08-11 Ball Corporation Method and apparatus of decorating a metallic container by digital printing to a transfer blanket
MX2020007505A (en) 2018-01-19 2020-09-09 Ball Corp System and method for monitoring and adjusting a decorator for containers.
WO2019157346A2 (en) 2018-02-09 2019-08-15 Ball Corporation Method and apparatus of decorating a metallic container by digital printing to a transfer blanket
WO2020097451A1 (en) 2018-11-09 2020-05-14 Ball Corporation A metering roller for an ink station assembly of a decorator and a method of decorating a container with the decoration
CN110188014A (en) * 2019-05-29 2019-08-30 浙江大学 A kind of anti-interference test method for capacitive touch screen
CN113954502B (en) * 2021-10-26 2023-04-07 浙江康尔达新材料股份有限公司 Photosensitive negative-working lithographic printing plate precursor and method for making lithographic printing plate by using the same

Citations (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3654884A (en) * 1969-12-11 1972-04-11 Thiokol Chemical Corp Tufted pile fabric
US3741118A (en) * 1970-06-17 1973-06-26 A Carley Method for electronic lithography
US4286529A (en) * 1979-04-13 1981-09-01 Geo. P. Reintjes Co., Inc. Combination hanger and expansion plate for electric furnace roof
US4288043A (en) * 1980-04-18 1981-09-08 The Perfect Measuring Tape Company Measuring tape dispenser
US4713340A (en) * 1984-06-13 1987-12-15 Regents Of The University Of Minnesota Biodegradation of pentachlorophenol
US4806450A (en) * 1986-06-06 1989-02-21 Basf Aktiengesellschaft Photosensitive photopolymerizable recording element having a terpolymer binder in the photopolymerizable layer
US5039592A (en) * 1985-12-09 1991-08-13 Nippon Paint Co., Ltd. Photosensitive resin base material for making relief printing plates having a slip layer containing a blue anthroquinone
US5069999A (en) * 1989-11-20 1991-12-03 Fuji Photo Film Co., Ltd. PS plate for making lithographic printing plate requiring no dampening water
US5077175A (en) * 1988-08-30 1991-12-31 E. I. Du Pont De Nemours And Company Plasticized polyvinyl alcohol release layer for a flexographic printing plate
US5339737A (en) * 1992-07-20 1994-08-23 Presstek, Inc. Lithographic printing plates for use with laser-discharge imaging apparatus
US5353705A (en) * 1992-07-20 1994-10-11 Presstek, Inc. Lithographic printing members having secondary ablation layers for use with laser-discharge imaging apparatus
US5487338A (en) * 1992-07-20 1996-01-30 Presstek, Inc. Lithographic printing plates for use with laser-discharge imaging apparatus
US5750315A (en) * 1996-08-13 1998-05-12 Macdermid Imaging Technology, Inc. Compressible printing plates and manufacturing process therefor
US6232038B1 (en) * 1998-10-07 2001-05-15 Mitsubishi Chemical Corporation Photosensitive composition, image-forming material and image-forming method employing it
US6326128B1 (en) * 1997-03-20 2001-12-04 Basf Drucksysteme Gmbh Production of a photosensitive recording material
US6468713B1 (en) * 1999-03-30 2002-10-22 Yamamoto Chemicals, Inc. Phthalocyanine compounds, process for producing the same, and near infrared absorbent comprising the same

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1251232A (en) * 1967-10-12 1971-10-27
CH506099A (en) * 1967-10-17 1971-04-15 Du Pont Photopolymerisable elements for use with long service
US3537853A (en) * 1968-02-21 1970-11-03 Grace W R & Co Process of forming printing plates,including the step of subjecting the mounted transparency to a surface static electricity eliminator
US3654864A (en) * 1970-01-16 1972-04-11 Energy Conversion Devices Inc Printing employing materials with variable volume
US3773514A (en) * 1971-08-12 1973-11-20 Fromson H A Light-sensitive structure
US3836709A (en) * 1972-04-12 1974-09-17 Grace W R & Co Process and apparatus for preparing printing plates using a photocured image
US4486529A (en) * 1976-06-10 1984-12-04 American Hoechst Corporation Dialo printing plate made from laser
US4286043A (en) * 1980-05-21 1981-08-25 E. I. Du Pont De Nemours And Company Negative-working dry peel apart photopolymer element with polyvinylformal binder
US4718340A (en) * 1982-08-09 1988-01-12 Milliken Research Corporation Printing method
DE3447356A1 (en) * 1984-12-24 1986-07-03 Basf Ag, 6700 Ludwigshafen LIGHT SENSITIVE RECORDING ELEMENT
DE3528309A1 (en) * 1985-08-07 1987-02-12 Hoechst Ag LIGHT SENSITIVE MIXTURE AND LIGHT SENSITIVE RECORDING MATERIAL MADE THEREOF
DE3819457A1 (en) * 1988-06-08 1989-12-14 Basf Ag LIGHT-SENSITIVE, NEGATIVE WORKING OFFSET PRINTING PLATES
US5278027A (en) * 1989-03-08 1994-01-11 R. R. Donnelley Method and apparatus for making print imaging media
JPH06297565A (en) * 1993-02-22 1994-10-25 Toray Ind Inc Cover film
WO1998053370A1 (en) 1997-05-19 1998-11-26 Day International, Inc. Printing plate and method of making using digital imaging photopolymerization
DE19732902A1 (en) 1997-07-30 1999-02-04 Sun Chemical Corp A cover layer for photosensitive materials comprising a (1-vinylimidazole) polymer or copolymer

Patent Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3654884A (en) * 1969-12-11 1972-04-11 Thiokol Chemical Corp Tufted pile fabric
US3741118A (en) * 1970-06-17 1973-06-26 A Carley Method for electronic lithography
US4286529A (en) * 1979-04-13 1981-09-01 Geo. P. Reintjes Co., Inc. Combination hanger and expansion plate for electric furnace roof
US4288043A (en) * 1980-04-18 1981-09-08 The Perfect Measuring Tape Company Measuring tape dispenser
US4713340A (en) * 1984-06-13 1987-12-15 Regents Of The University Of Minnesota Biodegradation of pentachlorophenol
US5039592A (en) * 1985-12-09 1991-08-13 Nippon Paint Co., Ltd. Photosensitive resin base material for making relief printing plates having a slip layer containing a blue anthroquinone
US4806450A (en) * 1986-06-06 1989-02-21 Basf Aktiengesellschaft Photosensitive photopolymerizable recording element having a terpolymer binder in the photopolymerizable layer
US5077175A (en) * 1988-08-30 1991-12-31 E. I. Du Pont De Nemours And Company Plasticized polyvinyl alcohol release layer for a flexographic printing plate
US5069999A (en) * 1989-11-20 1991-12-03 Fuji Photo Film Co., Ltd. PS plate for making lithographic printing plate requiring no dampening water
US5339737A (en) * 1992-07-20 1994-08-23 Presstek, Inc. Lithographic printing plates for use with laser-discharge imaging apparatus
US5353705A (en) * 1992-07-20 1994-10-11 Presstek, Inc. Lithographic printing members having secondary ablation layers for use with laser-discharge imaging apparatus
US5487338A (en) * 1992-07-20 1996-01-30 Presstek, Inc. Lithographic printing plates for use with laser-discharge imaging apparatus
US5339737B1 (en) * 1992-07-20 1997-06-10 Presstek Inc Lithographic printing plates for use with laser-discharge imaging apparatus
US5750315A (en) * 1996-08-13 1998-05-12 Macdermid Imaging Technology, Inc. Compressible printing plates and manufacturing process therefor
US6326128B1 (en) * 1997-03-20 2001-12-04 Basf Drucksysteme Gmbh Production of a photosensitive recording material
US6232038B1 (en) * 1998-10-07 2001-05-15 Mitsubishi Chemical Corporation Photosensitive composition, image-forming material and image-forming method employing it
US6468713B1 (en) * 1999-03-30 2002-10-22 Yamamoto Chemicals, Inc. Phthalocyanine compounds, process for producing the same, and near infrared absorbent comprising the same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070101883A1 (en) * 2005-11-07 2007-05-10 Xerox Corporation Printing system using shape-changing materials
US20090155994A1 (en) * 2007-12-12 2009-06-18 Hawkins Gilbert A Forming thin film transistors using ablative films with pre-patterned conductors

Also Published As

Publication number Publication date
DE10085272T1 (en) 2003-01-30
IL133355A0 (en) 2001-04-30
WO2001042856A2 (en) 2001-06-14
JP2003516564A (en) 2003-05-13
IL133355A (en) 2003-10-31
WO2001042856A3 (en) 2002-07-11
US20030134230A1 (en) 2003-07-17
US6899998B2 (en) 2005-05-31
CA2393807A1 (en) 2001-06-14
AU1729901A (en) 2001-06-18

Similar Documents

Publication Publication Date Title
US20050221230A1 (en) Plate for digitally-imaged offset printing
US6245481B1 (en) On-press process of lithographic plates having a laser sensitive mask layer
US6245486B1 (en) Method for imaging a printing plate having a laser ablatable mask layer
US6242156B1 (en) Lithographic plate having a conformal radiation-sensitive layer on a rough substrate
US6387595B1 (en) On-press developable lithographic printing plate having an ultrathin overcoat
US6143470A (en) Digital laser imagable lithographic printing plates
EP1315998A1 (en) On-press development of thermosensitive lithographic plates
CN102483588B (en) Method and apparatus for drying after single-step-processing of lithographic printing plates
US7348132B2 (en) Laser sensitive lithographic printing plate having specific photopolymer composition
AU2001261250B2 (en) Chemical imaging of a lithographic printing plate
US20060251993A1 (en) Method of on-press developing thermosensitive lithographic printing plate
RU2004106537A (en) PHOTO-SENSITIVE FLEXOGRAPHIC ELEMENT AND METHOD FOR PRODUCING FORM PLATES OF FLEXOGRAPHIC PRINT FOR PRINTING NEWSPAPERS
CA2226782A1 (en) Water-less lithographic plates
EP0720053B1 (en) Photosensitive resin composition, photosensitive printing plate and method of manufacturing printing master plate
WO2018082499A1 (en) Heat-sensitive processless planographic printing plate material containing thermosensitive protection layer, and use
CN102460308B (en) Preparing lithographc printing plates with enhanced contrast
CN104704427B (en) Negative working lithographic plate precursor and purposes
US7674571B2 (en) Laser sensitive lithographic printing plate comprising specific acrylate monomer and initiator
US20040038152A1 (en) Method for making printing plate by inkjet deposition on positive-working media
Liu et al. A review of flexographic printing plate development
US5609981A (en) Waterless presensitized printing plate comprising four layers and method of making thereof
TW583508B (en) A radiation sensitive composition and a process for preparing an image
TW584787B (en) A radiation sensitive composition and a process for preparing an image
JPH061088A (en) Printing original plate, manufacture of printing plate using the same, printing method and device using printing plate
JPS5914744B2 (en) Method for manufacturing printing plates that prevent background smearing

Legal Events

Date Code Title Description
STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION