DE102014221061A1 - Auf Terpenlactam basierende Polyamide - Google Patents

Auf Terpenlactam basierende Polyamide Download PDF

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Publication number
DE102014221061A1
DE102014221061A1 DE102014221061.5A DE102014221061A DE102014221061A1 DE 102014221061 A1 DE102014221061 A1 DE 102014221061A1 DE 102014221061 A DE102014221061 A DE 102014221061A DE 102014221061 A1 DE102014221061 A1 DE 102014221061A1
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Germany
Prior art keywords
terpene
lactam
group
polyamide
ring
Prior art date
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DE102014221061.5A
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German (de)
English (en)
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DE102014221061B4 (de
Inventor
Claudia Falcke
Harald Strittmatter
Marion Wölbing
Volker Sieber
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Fraunhofer Gesellschaft zur Forderung der Angewandten Forschung eV
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Fraunhofer Gesellschaft zur Forderung der Angewandten Forschung eV
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Priority to DE102014221061.5A priority Critical patent/DE102014221061B4/de
Priority to CH01493/15A priority patent/CH710304B1/de
Priority to CH01040/19A priority patent/CH715224B1/de
Publication of DE102014221061A1 publication Critical patent/DE102014221061A1/de
Application granted granted Critical
Publication of DE102014221061B4 publication Critical patent/DE102014221061B4/de
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
    • C07C209/48—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of nitriles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
    • C07C209/52—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of imines or imino-ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C221/00—Preparation of compounds containing amino groups and doubly-bound oxygen atoms bound to the same carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C227/22—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton from lactams, cyclic ketones or cyclic oximes, e.g. by reactions involving Beckmann rearrangement
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D223/00—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
    • C07D223/14—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
    • C07D223/32—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom condensed with carbocyclic rings or ring systems containing carbocyclic rings other than six-membered
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C08G69/14—Lactams
    • C08G69/16—Preparatory processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C08G69/14—Lactams
    • C08G69/16—Preparatory processes
    • C08G69/18—Anionic polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C08G69/14—Lactams
    • C08G69/16—Preparatory processes
    • C08G69/18—Anionic polymerisation
    • C08G69/20—Anionic polymerisation characterised by the catalysts used
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/02—Systems containing only non-condensed rings with a three-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/04—Systems containing only non-condensed rings with a four-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/08—Systems containing only non-condensed rings with a five-membered ring the ring being saturated
DE102014221061.5A 2014-10-16 2014-10-16 Auf Terpenlactam basierende Polyamide Active DE102014221061B4 (de)

Priority Applications (3)

Application Number Priority Date Filing Date Title
DE102014221061.5A DE102014221061B4 (de) 2014-10-16 2014-10-16 Auf Terpenlactam basierende Polyamide
CH01493/15A CH710304B1 (de) 2014-10-16 2015-10-15 Auf Terpenlactam basierende Polyamide.
CH01040/19A CH715224B1 (de) 2014-10-16 2015-10-15 Verfahren zur Herstellung eines Terpendiamins.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102014221061.5A DE102014221061B4 (de) 2014-10-16 2014-10-16 Auf Terpenlactam basierende Polyamide

Publications (2)

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DE102014221061A1 true DE102014221061A1 (de) 2016-04-21
DE102014221061B4 DE102014221061B4 (de) 2019-05-29

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CH (2) CH715224B1 (ru)
DE (1) DE102014221061B4 (ru)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102018203631A1 (de) 2018-03-09 2019-09-12 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Isomeren-angereicherte 3-Caranlactame und darauf basierende Polyamide mit hoher optischer Reinheit und einstellbarer Kristallinität für Hochleistungsanwendungen
EP3741790A1 (de) 2019-05-20 2020-11-25 Evonik Operations GmbH Polyamide mit cyclischen terpenoiden substrukturen
EP4067409A1 (en) 2021-04-01 2022-10-05 Ems-Chemie Ag Renewable cycloaliphatic diamines and polymers thereof
RU2801943C2 (ru) * 2018-03-09 2023-08-21 Фраунхофер-Гезелльшафт Цур Фердерунг Дер Ангевандтен Форшунг Е.Ф. Обогащенный изомером 3-каранлактам и полиамид на его основе с высокой оптической чистотой и регулируемой кристалличностью для высокопроизводительных вариантов применения

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6930165B2 (en) * 2000-06-16 2005-08-16 Rhodia Engineering Plastics S.R.L. Modified polyamides, compositions based on same and macromolecular compounds used to obtain them
WO2007128512A1 (de) 2006-05-08 2007-11-15 Combots Product Gmbh Verfahren und vorrichtung zum bereitstellen eines einem dargestellten symbol zugeordneten auswahlmenüs
EP1687356B1 (de) * 2003-11-21 2009-05-27 Lanxess Deutschland GmbH Verfahren zur kontinuierlichen herstellung von polyamiden mit verbesserten fliesseigenschaften
US20140275034A1 (en) * 2013-03-14 2014-09-18 United States of America, as represented by the Secretary of Agriculture Methods and Compositions Utilizing Lactams Derived from Camphor, Verbenone or Cat Thyme Oil for Repelling Blood-Sucking and Biting Insects, Ticks and Mites

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6930165B2 (en) * 2000-06-16 2005-08-16 Rhodia Engineering Plastics S.R.L. Modified polyamides, compositions based on same and macromolecular compounds used to obtain them
EP1687356B1 (de) * 2003-11-21 2009-05-27 Lanxess Deutschland GmbH Verfahren zur kontinuierlichen herstellung von polyamiden mit verbesserten fliesseigenschaften
WO2007128512A1 (de) 2006-05-08 2007-11-15 Combots Product Gmbh Verfahren und vorrichtung zum bereitstellen eines einem dargestellten symbol zugeordneten auswahlmenüs
US20140275034A1 (en) * 2013-03-14 2014-09-18 United States of America, as represented by the Secretary of Agriculture Methods and Compositions Utilizing Lactams Derived from Camphor, Verbenone or Cat Thyme Oil for Repelling Blood-Sucking and Biting Insects, Ticks and Mites

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
B. Tieke, Makromolekulare Chemie, Wiley VCH 2005
Campher und Menthon wurden in der Literatur beschrieben (Kumar, Med. Chem. Res. 2012, Seite 531)
DIN EN ISO 307
Frunze et al., Russian Chemical Review, 1979, 48(10), 991-1005
Lochinski et al. (Tetrahedron: Asymmetry, 2000, 11, 1295)
R. E. Gawley, Org. React. 1988, 35, 1

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102018203631A1 (de) 2018-03-09 2019-09-12 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Isomeren-angereicherte 3-Caranlactame und darauf basierende Polyamide mit hoher optischer Reinheit und einstellbarer Kristallinität für Hochleistungsanwendungen
WO2019170538A1 (de) 2018-03-09 2019-09-12 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Isomeren-angereicherte 3-caranlactame und darauf basierende polyamide mit hoher optischer reinheit und einstellbarer kristallinität für hochleistungsanwendungen
CN111836848A (zh) * 2018-03-09 2020-10-27 弗劳恩霍夫应用研究促进协会 富含异构体的3-蒈烷内酰胺和基于此的具有高光学纯度和可调结晶度的高性能用途用聚酰胺
US20210017332A1 (en) * 2018-03-09 2021-01-21 Fraunhofer-Gesellschaft zür Förderung der angwandten Forschung E.V. Isomer-enriched 3-caranlactams and polyamides based thereon with high optical purity and adjustable crystallinity for high-performance applications
JP2021516279A (ja) * 2018-03-09 2021-07-01 フラウンホファー ゲセルシャフト ツール フェールデルンク ダー アンゲヴァンテン フォルシュンク エー．ファオ． 異性体富化された３−カランラクタム並びに高い光学純度及び高性能用途のために調整可能な結晶性を有する上記ラクタムをベースとするポリアミド
RU2801943C2 (ru) * 2018-03-09 2023-08-21 Фраунхофер-Гезелльшафт Цур Фердерунг Дер Ангевандтен Форшунг Е.Ф. Обогащенный изомером 3-каранлактам и полиамид на его основе с высокой оптической чистотой и регулируемой кристалличностью для высокопроизводительных вариантов применения
CN111836848B (zh) * 2018-03-09 2023-11-07 弗劳恩霍夫应用研究促进协会 富含异构体的3-蒈烷内酰胺和基于此的聚酰胺
JP7438121B2 (ja) 2018-03-09 2024-02-26 フラウンホファー ゲセルシャフト ツール フェールデルンク ダー アンゲヴァンテン フォルシュンク エー．ファオ． 異性体富化された３－カランラクタム並びに高い光学純度及び高性能用途のために調整可能な結晶性を有する上記ラクタムをベースとするポリアミド
EP3741790A1 (de) 2019-05-20 2020-11-25 Evonik Operations GmbH Polyamide mit cyclischen terpenoiden substrukturen
WO2020234289A1 (de) 2019-05-20 2020-11-26 Evonik Operations Gmbh Polyamide mit cyclischen terpenoiden substrukturen
EP4067409A1 (en) 2021-04-01 2022-10-05 Ems-Chemie Ag Renewable cycloaliphatic diamines and polymers thereof

Also Published As

Publication number Publication date
CH710304A2 (de) 2016-04-29
CH710304B1 (de) 2019-08-30
CH715224B1 (de) 2020-01-31
DE102014221061B4 (de) 2019-05-29

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