CN104876586A - Production method of novel ceramic tile - Google Patents

Production method of novel ceramic tile Download PDF

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Publication number
CN104876586A
CN104876586A CN201510184891.5A CN201510184891A CN104876586A CN 104876586 A CN104876586 A CN 104876586A CN 201510184891 A CN201510184891 A CN 201510184891A CN 104876586 A CN104876586 A CN 104876586A
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China
Prior art keywords
ceramic tile
production method
novel ceramic
ball
raw materials
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Pending
Application number
CN201510184891.5A
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Chinese (zh)
Inventor
卢精
邹奇峰
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Fu Luoni Pottery Co Ltd
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Fu Luoni Pottery Co Ltd
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Priority to CN201510184891.5A priority Critical patent/CN104876586A/en
Publication of CN104876586A publication Critical patent/CN104876586A/en
Priority to MYPI2016701442A priority patent/MY191420A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a production method of a novel ceramic tile. The production method comprises the following steps of: adding all kinds of raw materials of the novel ceramic tile into a ball-milling tank to mix according to a certain ratio; adding water with a certain proportion after mixing all kinds of raw materials of the novel ceramic tile, so that all kinds of raw materials are sufficiently ball-milled in the ball-milling tank; adding nano zinc oxide having the catalytic function into the ball-milling tank after ball-milling, and continuously ball-milling; covering the mixed raw materials on the surface of a green blank of the ceramic tile when a ball-milled nano antibacterial glaze is 350 g/200cc in concentration and 200 mesh in fineness, and printing a metallic inorganic compound on the surface of the ceramic tile; and calcining the ceramic tile at 1120-1230 DEG C after forming the green blank of the ceramic tile so as to obtain an antibacterial anion far-infrared ceramic tile. Due to the production method of the novel ceramic tile disclosed by the invention, the living quality is increased; health threatening of chemical residues and bacteria breeding to human bodies is reduced; the water resource is saved; use of daily chemicals is reduced; pollution to water quality is reduced; and the novel ceramic tile has the far-infrared function and is capable of effectively activating water quality.

Description

A kind of production method of novel ceramic tile
Technical field
The present invention relates to a kind of production method of ceramic tile, tool a kind ofly has antibacterium mildew-resistant endurance quality strong and have far-infrared radiation effect and can the production method of anion releasing ceramic tile, belongs to building material field.
Background technology
Bacteriological infection very easily extremely affects the healthy of people, and even crisis is to life.The disease of experiment proof 90 percent is all by bacteriological infection.But bacterium is as the single celled microorganism of a class, wide in distributed in nature, kind is many, and it is very close with the relation of human being's production and life again.Bacterium can cause various diseases, and on the one hand harm people's is healthy, and as on the human skin, when oral cavity neutralizes other position damaged, bacteriological infection can cause suppuration phenomenon, pyaemia septica can occur time serious; On the other hand, microorganism can cause various Industrial materials Disassembling Products, rotten, corrupt, as pollute on Industrial materials and goods thereof the loss that causes, can compared with floods, fire.Therefore, the research of anti-biotic material and goods causes the concern of people, and the demand of antimicrobial prod will form huge market.
Ceramic tile as a kind of extremely conventional material of construction, if having the new breakthrough that antibacterial will be building material field.And be commercially now common ceramic tile function, fire in the common glaze paint of idiosome surface spraying one deck and form, without any function, even may cause new pollution to environment, also there is no sterilizing function.
Summary of the invention
Have problems for above-mentioned prior art, the invention provides a kind of production method of novel ceramic tile, the ceramic tile with antibiotic layer can be produced by the method, this ceramic tile is the ceramic tile of antibacterial anionic far-infrared radiation effect, and environment is not polluted, safety and stability, health care, prevents bacterium from spreading.
For achieving the above object, the technical solution used in the present invention is: a kind of production method of novel ceramic tile, and this production method comprises the steps:
1), the various raw materials of novel ceramic tile are joined according to a certain ratio ball grinder mixing;
2), etc. after the mixing of novel ceramic tile various raw material, add a certain proportion of water, make various raw material abundant ball milling in ball grinder;
3), after ball milling, in ball grinder, add the nano zine oxide with catalysis, continue ball milling;
4), when the nano-antibacterial glaze concentration after ball milling be 350g/200cc, fineness be 200 order time, the raw material of mixing is covered the raw embryo surface of ceramic tile, and stamps the mineral compound of metal on brick surface;
5), after the raw embryogeny of ceramic tile, ceramic tile had antibacterial anionic far infrared rays ceramic tile with the temperature calcination of 1120 degree to 1230 degree one-tenth.
Further, the various raw materials of described novel ceramic tile are: industrial zinc oxide, industrial potassium titanate, potassium felspar sand, zirconium silicate, aluminum oxide powder, whiten stone, kaolin.
Further, the various raw materials of described novel ceramic tile become than being industrial zinc oxide: 3-8; Industrial potassium titanate: 15-30; Potassium felspar sand: 30-50; Zirconium silicate: 20-40; Aluminum oxide powder: 3-10; Whiten stone: 5-15; Kaolin: 5-15; Nano zine oxide: 2--10.
Further, described a certain proportion of water be the 0.6-1.5 of the various raw materials of described novel ceramic tile in proportion doubly.
Further, the diameter of described nano zine oxide is 20 to 25 nanometers.
Further, the mineral compound of described metal be alum, chromium, manganese, iron, cobalt, nickel or copper one or more.
The invention has the beneficial effects as follows: the ceramic tile of the method manufacture has the effect of antibacterial anionic far-infrared radiation, make ceramic tile surface often have effect and keep bright and clean, and produce antibacterium virus function, light wave between releasing far infrared about 6-14 micron, the antiviral property of ceramic tile makes blood flow smooth and easy, human body is warm and reduce neurodynia, myalgia or arthrodynia, improve the symptoms such as brothers are ice-cold simultaneously, wound healing can be helped, promote sleep, promote metabolism, cleaning vivotoxin, strengthen immunity system, neural adjustment, the symptom such as promote health.Negative ion is released in air, can remove the taste such as peculiar smell and formaldehyde, strengthens the metabolism of human body cell and promotes immunity, promote deep sleep and well digest.Negative ion also protects body and mind, escorts the detrimentally affect that hertzian wave in daily life brings.
The ceramic tile that the method is produced has and prevents bacterium, and virus adheres to the anti-microbial effect grown, and via the far-infrared radiation function of ceramic tile surface, normal effect activation pass through the one's share of expenses for a joint undertaking characteristic of material, and promoted the function of this material, reached health-care effect.
This ceramic tile can be avoided or significantly reduce using detergents and cosmetic detergent product, will be that ceramic tile field one great revolution promotes; And greatly can reduce the labour intensity of ceramic tile cleaning.Improve the quality of living, reduce chemical residues and bacteria breed, HUMAN HEALTH is threatened.Saving water resource, reduces household chemicals and uses, reduce water pollution.Product has far-infrared functional, can effective activation water quality.
Accompanying drawing explanation
Fig. 1 is structural representation of the present invention;
In figure: 1, basic unit; 2, antibiotic layer; 3, nano zine oxide.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described.Obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
A production method for novel ceramic tile, this production method comprises the steps:
1), the various raw materials of novel ceramic tile are joined according to a certain ratio ball grinder mixing;
2), etc. after the mixing of novel ceramic tile various raw material, add a certain proportion of water, make various raw material abundant ball milling in ball grinder;
3), after ball milling, in ball grinder, add the nano zine oxide with catalysis, continue ball milling;
4), when the nano-antibacterial glaze concentration after ball milling be 350g/200cc, fineness be 200 order time, the raw material of mixing is covered the raw embryo surface of ceramic tile, and stamps the mineral compound of metal on brick surface;
5), after the raw embryogeny of ceramic tile, ceramic tile had antibacterial anionic far infrared rays ceramic tile with the temperature calcination of 1120 degree to 1230 degree one-tenth.
The various raw materials of described novel ceramic tile are: industrial zinc oxide, industrial potassium titanate, potassium felspar sand, zirconium silicate, aluminum oxide powder, whiten stone, kaolin and nano zine oxide.
The various raw materials of described novel ceramic tile become than being industrial zinc oxide: 3-8; Industrial potassium titanate: 15-30; Potassium felspar sand: 30-50; Zirconium silicate: 20-40; Aluminum oxide powder: 3-10; Whiten stone: 5-15; Kaolin: 5-15; Nano zine oxide: 2-10.
Described a certain proportion of water be the 0.6-1.5 of the various raw materials of described novel ceramic tile in proportion doubly.
The diameter of described nano zine oxide is 20 to 25 nanometers.
The mineral compound of described metal be alum, chromium, manganese, iron, cobalt, nickel or copper one or more.
Embodiment one
Ornamental brick function brick glaze material formula: industrial zinc oxide: 3-8; Industrial potassium titanate: 15-30; Potassium felspar sand: 30-50; Zirconium silicate: 20-40; Aluminum oxide powder: 3-10; Whiten stone: 5-15; Kaolin: 5-15; Nano zine oxide: 2-10.After adding ball grinder mixing together, then add and be equivalent to the 0.6-1.5 doubly abundant ball milling of water in proportion.
Product median size is added again: (nano zine oxide and titanium dioxide are all semiconductor material again to 24nm nano zine oxide, have catalysis after spending 3 hours; Unlike titanium dioxide, UV-light is relied on.) etc. score that to be milled to glaze abrasive lapping solubility be about 350g/200cc, fineness is 200 object nano-antibacterial glaze.(adding formula: nano zine oxide * glaze proportion * per-cent/zinc oxide solid content).
Glaze completed according to this, when practical probation, can be coated on the surface of the raw embryo of ceramic tile or plain embryo, and mineral compound such as vanadium, chromium, manganese, iron, cobalt, nickel and copper that the glaze on brick surface stamps metal is all common pigments etc.Full wafer ceramic tile sinters into the temperature of 1120 degree of-1230 degree has antibacterial anionic far infrared rays ceramic tile.The characteristic of nano-antibacterial glaze is often imitated and is kept the bright and clean of this ceramic surface, attractive in appearance, and generation prevents bacterium, virus adheres to the anti-microbial effect grown, and via the far-infrared radiation function of ceramic tile surface, normal effect activation pass through the one's share of expenses for a joint undertaking characteristic of material, and promoted the function of this material, reached health-care effect.
Embodiment two
By nano zine oxide by 6% solid content add in the idiosome of brick embryo, and carry out the formula rate of adjusting brick according to the temperature of brick.
Be fired into the composition of raw materials in ceramic idiosome: feldspar: 30-50; Porcelain stone: 20-40; Quartz: 3-10; Clay: 20-30; Talcum: 1-5;
1. kaolinite class: such as ball clay, sedimentation type kaolin etc.; 2. illite class: such as porcelain stone, porcelain sand and sedentary product thereof; 3. smectites: such as wilkinite; 4. pyrophyllite class: rear certain plasticity-that some data is included into flint clay class, particularly sericite type, dickite type pyrophyllite, kaolinite type pyrophyllite is levigate.
Conventional flux and mineralizer have: 1. potassium sodium system: potassium felspar sand, albite, potassium albite, porcelain stone, porcelain sand etc.; 2. calcium magnesium system: diopside, the tremolite, attaclay (or claiming talc clay), talcum etc.; 3. composite system: nano zinc oxide material etc.
Manufacturing process programanalysis:
1, raw material: chemical composition, burn after whiteness, supply whether sufficient, whether mineral reserve stable, whether transport convenient, homogenizing, fragmentation, deironing.
2, prepare burden: raw material moisture, batching accuracy.
3, ball milling: slurry fineness, moisture, viscosity.
4, to sieve deironing: organism, cross thick thing, free irony.
5, spraying dry: powder lot humidity, powder grating, powder structure.
6, bin stock: moisture homogenizing, organic matter fermentation, ensures the quality of pressing unfired brick.
7, suppress: press pressure, mould structure, punching press number of times, cloth degree of uniformity.
8, dry: to get rid of moisture, prevent the intensity bursting, ensure dry base substrate.
9, stamp: fixed pattern, design ooze the formula of fancy glaze.
10, penetration-assisting agent is drenched: guarantee depth of penetration.
11, burn till: by series of physical and chemical reaction, make adobe at high temperature form liquid phase, finally form glassy phase, crystalline phase, gas phase, reasonably formula and rational calcining system are the bases ensureing to be formed fine and close hard porcelain brick.
Thus reach and can not absorb water and corrosion-and high-temp-resistant.Surface is fallen again, the antibacterial far infrared polished glazed tile that the eternal function of a slice does not slacken through polishing machine polishing grinding.Can produce and prevent bacterium, virus adheres to the anti-microbial effect that grows, and via the far-infrared radiation function of ceramic tile surface, normal effect activation pass through the one's share of expenses for a joint undertaking characteristic of material, and promoted the function of this material, reached health-care effect.
By nano zine oxide by 30% solid content be dispersed into liquid and mix homogenizing with solid state wax water (major ingredient is silicon-dioxide and silicone oil) again and within about 15 minutes, become antibacterial wax water.Add in the clean bright machine of the excess of imports to operate routinely again and squeeze into polished tile surface, fill the pore on polished tile surface, also can play antifouling and antibiosis, and generation prevents bacterium, virus adheres to the effect of growing.
As shown in Figure 1, a kind of multi-functional glazed ceramic wall tile, is made up of basic unit 1 and antibiotic layer 2, containing catalyst nano zine oxide 3 in antibiotic layer 2.Described nano zine oxide 3 median size is 24nm.
This ceramic tile is verified through product quality supervision and testing institute, ceramic tile normal direction total emissivity 0.87; This ceramic tile anti-microbial property (intestinal bacteria, streptococcus aureus) meets the standard-required of JC/T897-2002 " anti-bacteria ceramic anti-microbial property ".
To those skilled in the art, obviously the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when not deviating from spirit of the present invention or essential characteristic, the present invention can be realized in other specific forms.Therefore, no matter from which point, all should embodiment be regarded as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of above-mentioned explanation, and all changes be therefore intended in the implication of the equivalency by dropping on claim and scope are included in the present invention.Any Reference numeral in claim should be considered as the claim involved by limiting.
The above; be only preferred embodiment of the present invention; not in order to limit the present invention, every above embodiment is done according to technical spirit of the present invention any trickle amendment, equivalently replace and improve, within the protection domain that all should be included in technical solution of the present invention.

Claims (6)

1. a production method for novel ceramic tile, is characterized in that: this production method comprises the steps:
1), the various raw materials of novel ceramic tile are joined according to a certain ratio ball grinder mixing;
2), etc. after the mixing of novel ceramic tile various raw material, add a certain proportion of water, make various raw material abundant ball milling in ball grinder;
3), after ball milling, in ball grinder, add the nano zine oxide with catalysis, continue ball milling;
4), when the nano-antibacterial glaze concentration after ball milling be 350g/200cc, fineness be 200 order time, the raw material of mixing is covered the raw embryo surface of ceramic tile, and stamps the mineral compound of metal on brick surface;
5), after the raw embryogeny of ceramic tile, ceramic tile had antibacterial anionic far infrared rays ceramic tile with the temperature calcination of 1120 degree to 1230 degree one-tenth.
2. the production method of a kind of novel ceramic tile according to claim 1, is characterized in that, the various raw materials of described novel ceramic tile are: industrial zinc oxide, industrial potassium titanate, potassium felspar sand, zirconium silicate, aluminum oxide powder, whiten stone, kaolin.
3. the production method of a kind of novel ceramic tile according to claim 2, is characterized in that, the various raw materials of described novel ceramic tile become than being industrial zinc oxide: 3-8; Industrial potassium titanate: 15-30; Potassium felspar sand: 30-50; Zirconium silicate: 20-40; Aluminum oxide powder: 3-10; Whiten stone: 5-15; Kaolin: 5-15; Nano zine oxide: 2-10.
4. the production method of a kind of novel ceramic tile according to claim 1 or 3, is characterized in that: described a certain proportion of water be the 0.6-1.5 of the various raw materials of described novel ceramic tile in proportion doubly.
5. the production method of a kind of novel ceramic tile according to claim 4, is characterized in that: the diameter of described nano zine oxide is 20 to 25 nanometers.
6. the production method of a kind of novel ceramic tile according to claim 1 or 5, is characterized in that: the mineral compound of described metal be alum, chromium, manganese, iron, cobalt, nickel or copper one or more.
CN201510184891.5A 2015-04-20 2015-04-20 Production method of novel ceramic tile Pending CN104876586A (en)

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CN201510184891.5A CN104876586A (en) 2015-04-20 2015-04-20 Production method of novel ceramic tile
MYPI2016701442A MY191420A (en) 2015-04-20 2016-04-19 A method of ceramic tile production

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105344021A (en) * 2015-11-07 2016-02-24 德化均能手造陶瓷有限公司 Optical wafer for activating blood and dredging collaterals
CN105801175A (en) * 2016-03-04 2016-07-27 浙江根根陶瓷有限公司 Antibacterial ceramic tiles and production method thereof
CN106220139A (en) * 2016-08-05 2016-12-14 佛山市寰田陶瓷有限公司 A kind of antifouling self-purification tile and preparation method thereof
CN107419866A (en) * 2017-06-21 2017-12-01 信益陶瓷(中国)有限公司 A kind of Dali stone ceramic tile with antibacterial functions
CN108658582A (en) * 2018-07-04 2018-10-16 熊静 A kind of preparation method of construction tile
CN109020481A (en) * 2018-09-03 2018-12-18 合肥久新不锈钢厨具有限公司 A kind of high intensity resistant ceramic tile and preparation method thereof
CN110511010A (en) * 2019-08-17 2019-11-29 山东华宇国际控股有限公司 A kind of novel sheen reflection ceramic tile and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101008286A (en) * 2006-01-25 2007-08-01 魏英洲 Flooring Board with health care function
CN101157542A (en) * 2007-09-27 2008-04-09 何乾 Production technique for ceramic title having semitransparent reflecting decorative surface
CN103664193A (en) * 2013-12-16 2014-03-26 酉阳县四达机械厂 Ceramic tile production process

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101008286A (en) * 2006-01-25 2007-08-01 魏英洲 Flooring Board with health care function
CN101157542A (en) * 2007-09-27 2008-04-09 何乾 Production technique for ceramic title having semitransparent reflecting decorative surface
CN103664193A (en) * 2013-12-16 2014-03-26 酉阳县四达机械厂 Ceramic tile production process

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105344021A (en) * 2015-11-07 2016-02-24 德化均能手造陶瓷有限公司 Optical wafer for activating blood and dredging collaterals
CN105801175A (en) * 2016-03-04 2016-07-27 浙江根根陶瓷有限公司 Antibacterial ceramic tiles and production method thereof
CN106220139A (en) * 2016-08-05 2016-12-14 佛山市寰田陶瓷有限公司 A kind of antifouling self-purification tile and preparation method thereof
CN107419866A (en) * 2017-06-21 2017-12-01 信益陶瓷(中国)有限公司 A kind of Dali stone ceramic tile with antibacterial functions
CN108658582A (en) * 2018-07-04 2018-10-16 熊静 A kind of preparation method of construction tile
CN109020481A (en) * 2018-09-03 2018-12-18 合肥久新不锈钢厨具有限公司 A kind of high intensity resistant ceramic tile and preparation method thereof
CN110511010A (en) * 2019-08-17 2019-11-29 山东华宇国际控股有限公司 A kind of novel sheen reflection ceramic tile and preparation method thereof

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