CN103896558B - Preparation method of infrared ceramic vacuum cup and product prepared by same - Google Patents

Preparation method of infrared ceramic vacuum cup and product prepared by same Download PDF

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CN103896558B
CN103896558B CN201410088764.0A CN201410088764A CN103896558B CN 103896558 B CN103896558 B CN 103896558B CN 201410088764 A CN201410088764 A CN 201410088764A CN 103896558 B CN103896558 B CN 103896558B
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glaze
preparation
blank
oxide
mud
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CN103896558A (en
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肖杨
胡飞
谢庚
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Hunan Karpery Industrial Co ltd
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Hunan Karpery Industrial Co ltd
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Abstract

The invention relates to a preparation method of an infrared ceramic vacuum cup and a product prepared by the same. A formula of a blank comprises the raw materials in parts by weight: 10-30% of Longyan cleansing mud, 10-30% of Chenzhou mud, 15-30% of Yunnan sand, 15-30% of potassium feldspar, 5-10% of medical stone, 0.5-5% of titanium oxide, 2-10% of zirconium silicate, 0.5-3% of manganese dioxide and 0.2-1% of yttrium oxide. A formula of glaze comprises the raw materials in parts by weight: 20-40% of potassium feldspar, 5-15% of sodium feldspar, 5-15% of kaolin, 20-40% of quartz, 10-30% of calcite, 1-5% of talc, 1-5% of zinc oxide, 1-5% of titanium oxide, 2-5% of manganese dioxide, 5-15% of zirconium silicate, 1-5% of ferric oxide and 0.2-1% of yttrium oxide. The product with a good health care function is obtained by the steps of preparing the blank and the glaze, forming, drying, biscuiting, glazing and firing glaze and has broad application prospect.

Description

A kind of preparation method of infra-red china thermos cup and obtained product thereof
Technical field
The invention belongs to ceramic (pottery) field, be specifically related to a kind of preparation method of infra-red china thermos cup and obtained product thereof.
Background technology
The vibrational frequency of far infrared rays and human inner cell's molecule is close, the atom of human body cell and the resonance of molecule can be caused, thermal response is formed by frictional heat between resonant absorption molecule, promote that subcutaneous deep temperature rises, and make Marjoram Extract, promote and improve blood circulation, strengthen metabolism, be conducive to removing blood vessel and hoard objectionable impurities in thing and body, improve immune function of human body, there is good human body heath care function.Can emitting far-infrared material be inorganic materials mostly, this be because inorganic materials inside easily forms defect, as doped Ti in the crystalline phase of mullite, trichroite 4+, Mg 2+, Y 3+, Pd 3+, Ni 2+, Fe 3+, Zr 4+, Ti 4+after plasma, molecular vibration is asymmetric and launch far infrared rays.
In CN102070324A, prepare a kind of far-infrared ceramic ball, this Ceramic Balls can give off far infrared rays, kills the harmful microorganisms such as the intestinal bacteria in water.Patent CN1027365C prepares far-infrared ceramic powder, and then adds in various vessel, clothes, comes emitting far-infrared, can play a role in health care by far-infrared ceramic powder.Tourmaline haydite ball joins in the interlayer of thermos cup by Chinese patent CN101849781, but it is more weak that far-infrared functional launched by Tourmaline haydite ball, low to the activity performance of water, but up to the present also far infrared health care technology is not applied to the report in ceramic cup.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind ofly has mobilizing function to water, have good nourishing function, the preparation method of low raw-material cost, production technique simple infra-red china thermos cup and obtained product thereof.
For solving above technical problem, technical scheme of the present invention is: a kind of preparation method of infra-red china thermos cup, and adopt raw mineral materials and industrial chemicals, the weight percent of its blank and glaze formula consists of:
Blank: mud 10 ~ 30%, Chenzhou mud 10 ~ 30%, Yunnan sand 15 ~ 30%, potassium felspar sand 15 ~ 30%, medical stone 5 ~ 10%, titanium oxide 0.5 ~ 5%, zirconium silicate 2 ~ 10%, Manganse Dioxide 0.5 ~ 3%, yttrium oxide 0.2 ~ 1% are washed in Longyan;
Glaze: potassium felspar sand 20 ~ 40%, albite 5 ~ 15%, kaolin 5 ~ 15%, quartz 20 ~ 40%, calcite 10 ~ 30%, talcum 1 ~ 5%, zinc oxide 1 ~ 5%, titanium oxide 1 ~ 5%, Manganse Dioxide 2 ~ 5%, zirconium silicate 5 ~ 15%, ferric oxide 1 ~ 5%, yttrium oxide 0.2 ~ 1%;
Burn through blank and glaze preparation, shaping, dry, base substrate biscuiting, glazing, drying, medium temperature glaze and obtain goods, wherein base substrate biscuiting temperature range is: 700 ~ 1100 DEG C, and medium temperature glaze burning temperature is 1280 DEG C, firing time is 8 ~ 10h.
The preparation technology of described blank is: mix by blank formulation raw materials weighing, add weight percent be 0.1 ~ 0.4% tripoly phosphate sodium STPP and 0.2 ~ 0.8% water glass as thinner, then load ball milling in ball-grinding machine, going out to grind pug proportion is 1.58 ~ 1.65g/cm 3, then make blank through old.
The preparation technology of described glaze is: close evenly by glaze formula raw materials weighing, add weight percent be 0.3 ~ 0.8% carboxymethyl cellulose and 0.2 ~ 0.6% tripoly phosphate sodium STPP as additive, then load ball milling in ball-grinding machine, going out to grind glaze proportion is 1.55 ~ 1.65g/cm 3.
Described zinc oxide, aluminum oxide, talcum need first through pre-burning before using, and calcining temperature is 1200 DEG C.
The mass percent of described glaze chemical composition is as follows: Al 2o 36 ~ 10%, SiO 264 ~ 68%, K 2o 0.5 ~ 5%, Na 2o 0.2 ~ 3%, MgO 0.1 ~ 2%, CaO 0.4 ~ 15%, ZrO 20.1 ~ 8%, ZnO 0.05 ~ 5%, TiO 21 ~ 5%, Mn0 22 ~ 5%, Y 2o 30.2 ~ 1%.
The infra-red china thermos cup product that above-mentioned preparation method obtains, is characterized in that: the normal direction whole radiation rate of described product is 0.90 ~ 0.95.
The present invention's a kind of far-infrared ceramic thermos cup that adopted natural mineral raw and industrial pure material to prepare, this infra-red china thermos cup not only can activate the water in thermos cup, microcirculation in human body can be improved again simultaneously, strengthen metabolism, improve human immunological competence, there is good nourishing function, therefore there are wide market outlook.
Embodiment
Implementation column one:
A kind of far-infrared ceramic thermos cup, takes blank: mud 15% is washed in Longyan, Chenzhou mud 17% by mass percentage, Yunnan sand 25%, potassium felspar sand 20%, medical stone 8%, titanium oxide 5%, zirconium silicate 8%, Manganse Dioxide 1.2%, yttrium oxide 0.8%, adds the tripoly phosphate sodium STPP of 0.2% and the water glass of 0.5% in blank raw material, mixing and ball milling, adjustment mud balance is 1.60g/cm 3, after mud is old, casting obtains base substrate, and this base substrate is in advance through biscuiting, and biscuiting temperature is 1000 DEG C;
Take glaze by mass percentage: potassium felspar sand 20%, albite 8%, kaolin 5%, quartz 27.5%, calcite 15%, talcum 3%, zinc oxide 1%, titanium oxide 5%, manganese oxide 5%, zirconium silicate 8%, ferric oxide 1.5%, yttrium oxide 1%, the mass percent of its chemical composition is: Al 2o 38.6%, SiO 265%, K 2o 2.5%, Na 2o 1%, MgO 1%, CaO 9%, ZrO 25%, ZnO 1%, TiO 22%, Mn0 24%, Y 2o 30.9%, in glaze, add the carboxymethyl cellulose of 0.5% and the tripoly phosphate sodium STPP of 0.3%, mixing and ball milling, adjustment glaze proportion is 1.58g/cm 3, then in the glazing of thermal-insulation ceramic cup capable ectonexine, the drying of biscuiting, burn till at 1280 DEG C, firing time is 9h.
The sample prepared is carried out far infrared transmission performance test, and normal direction whole radiation rate is 0.91.
Implementation column two:
A kind of far-infrared ceramic thermos cup, take blank by mass percentage: mud 13%, Chenzhou mud 16%, Yunnan sand 23%, potassium felspar sand 25%, medical stone 10%, titanium oxide 5%, zirconium silicate 6%, Manganse Dioxide 1.3%, yttrium oxide 0.7% are washed in Longyan, in blank raw material, add the tripoly phosphate sodium STPP of 0.1% and the water glass of 0.4%.Mixing and ball milling, adjustment mud balance is 1.62g/cm 3, after mud is old, casting obtains base substrate, and this base substrate is in advance through biscuiting, and biscuiting temperature is 1000 DEG C;
Take glaze by mass percentage: potassium felspar sand 35%, albite 5%, kaolin 9%, quartz 20%, calcite 10%, talcum 2%, zinc oxide 3%, titanium oxide 4%, manganese oxide 3%, zirconium silicate 7%, ferric oxide 1.2%, yttrium oxide 0.8%, the mass percent of its chemical composition is: Al 2o 37.68%, SiO 266%, K 2o 2.5%, Na 2o 1.2%, MgO 0.9%, CaO 6%, ZrO 25%, ZnO 3%, TiO 24%, Mn0 23%, Y 2o 30.72%, in glaze, add the carboxymethyl cellulose of 0.4% and the tripoly phosphate sodium STPP of 0.3%.Mixing and ball milling, adjustment glaze proportion is at 1.60g/cm 3, then in the glazing of thermal-insulation ceramic cup capable ectonexine, the drying of biscuiting, burn till at 1280 DEG C, firing time is 8h.
The sample prepared is carried out far infrared transmission performance test, and normal direction whole radiation rate is 0.92.
Implementation column three:
A kind of far-infrared ceramic thermos cup, take blank by mass percentage: mud 30%, Chenzhou mud 11%, Yunnan sand 17%, potassium felspar sand 28%, medical stone 6%, titanium oxide 2%, zirconium silicate 3%, Manganse Dioxide 2.3%, yttrium oxide 0.7% are washed in Longyan, in blank raw material, add the tripoly phosphate sodium STPP of 0.2% and the water glass of 0.7%.Mixing and ball milling, adjustment mud balance is 1.64g/cm 3, after mud is old, casting obtains base substrate, and this base substrate is in advance through biscuiting, and biscuiting temperature is 1000 DEG C;
Take glaze by mass percentage: potassium felspar sand 20%, albite 5%, kaolin 13%, quartz 20%, calcite 15.7%, talcum 3%, zinc oxide 4%, titanium oxide 2%, manganese oxide 2%, zirconium silicate 12%, ferric oxide 3%, yttrium oxide 0.3%, the mass percent of its chemical composition is: Al 2o 39%, SiO 268%, K 2o 2.5%, Na 2o 2.2%, MgO 1.9%, CaO 6%, ZrO 21.68%, ZnO 1%, TiO 24%, Mn0 23.5%, Y 2o 30.22%, in glaze, add the carboxymethyl cellulose of 0.4% and the tripoly phosphate sodium STPP of 0.3%.Mixing and ball milling, adjustment glaze proportion is at 1.64g/cm 3, then in the glazing of thermal-insulation ceramic cup capable ectonexine, the drying of biscuiting, burn till at 1280 DEG C, firing time is 8h.
The sample prepared is carried out far infrared transmission performance test, and normal direction whole radiation rate is 0.95.

Claims (2)

1. a preparation method for infra-red china thermos cup, adopt raw mineral materials and industrial chemicals, the weight percent of its blank and glaze formula consists of:
Blank: mud 10 ~ 30%, Chenzhou mud 10 ~ 30%, Yunnan sand 15 ~ 30%, potassium felspar sand 15 ~ 30%, medical stone 5 ~ 10%, titanium oxide 0.5 ~ 5%, zirconium silicate 2 ~ 10%, Manganse Dioxide 0.5 ~ 3%, yttrium oxide 0.2 ~ 1% are washed in Longyan;
Glaze: potassium felspar sand 20 ~ 40%, albite 5 ~ 15%, kaolin 5 ~ 15%, quartz 20 ~ 40%, calcite 10 ~ 30%, talcum 1 ~ 5%, zinc oxide 1 ~ 5%, titanium oxide 1 ~ 5%, Manganse Dioxide 2 ~ 5%, zirconium silicate 5 ~ 15%, ferric oxide 1 ~ 5%, yttrium oxide 0.2 ~ 1%;
Burn through blank and glaze preparation, shaping, dry, base substrate biscuiting, glazing, drying, medium temperature glaze and obtain goods, wherein base substrate biscuiting temperature range is: 700 ~ 1100 DEG C, and medium temperature glaze burning temperature is 1280 DEG C, firing time is 8 ~ 10h.
2. preparation method according to claim 1, it is characterized in that: the preparation technology of described blank is: mix by blank formulation raw materials weighing, add weight percent be 0.1 ~ 0.4% tripoly phosphate sodium STPP and 0.2 ~ 0.8% water glass as thinner, then load ball milling in ball-grinding machine, going out to grind pug proportion is 1.58 ~ 1.65g/cm 3, then make blank through old.
3 .preparation method according to claim 1, it is characterized in that: the preparation technology of described glaze is: close evenly by glaze formula raw materials weighing, add weight percent be 0.3 ~ 0.8% carboxymethyl cellulose and 0.2 ~ 0.6% tripoly phosphate sodium STPP as additive, then load ball milling in ball-grinding machine, going out to grind glaze proportion is 1.55 ~ 1.65g/cm 3.
4 .preparation method according to claim 1, is characterized in that: described zinc oxide, talcum need first through pre-burning before using, and calcining temperature is 1200 DEG C.
5 .preparation method according to claim 1, is characterized in that: the mass percent of described glaze chemical composition is as follows: Al 2o 36 ~ 10%, SiO 264 ~ 68%, K 2o 0.5 ~ 5%, Na 2o 0.2 ~ 3%, MgO 0.1 ~ 2%, CaO 0.4 ~ 15%, ZrO 20.1 ~ 8%, ZnO 0.05 ~ 5%, TiO 21 ~ 5%, MnO 22 ~ 5%, Y 2o 30.2 ~ 1%.
6 .according to the infra-red china thermos cup product that the arbitrary described preparation method of claim 1-5 obtains, it is characterized in that: the normal direction whole radiation rate of described product is 0.90 ~ 0.95.
CN201410088764.0A 2014-03-12 2014-03-12 Preparation method of infrared ceramic vacuum cup and product prepared by same Active CN103896558B (en)

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CN106277788B (en) * 2016-08-23 2018-11-30 宜兴市方卫明均陶艺术研究所 A kind of enamel glaze and preparation method thereof
CN107056263B (en) * 2017-04-27 2020-07-31 湖南港鹏实业有限公司 Preparation method of medium-temperature feldspar bone porcelain
CN110204205A (en) * 2019-05-23 2019-09-06 醴陵陶润实业发展有限公司 Crude pottery and preparation method thereof
CN110655382A (en) * 2019-08-02 2020-01-07 景德镇御腾瓷器有限公司 Preparation method of health-care ball with high far infrared radiance
CN111548010A (en) * 2020-05-06 2020-08-18 佛山科学技术学院 Antibacterial aromatic ceramic glaze
CN111333430B (en) * 2020-05-19 2020-11-13 佛山市东鹏陶瓷发展有限公司 Deodorizing glaze and preparation method of glazed tile using same
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CN113061055B (en) * 2021-03-25 2022-11-22 景德镇陶瓷大学 Antibacterial ceramic product and preparation method and application thereof
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CN103467134A (en) * 2012-06-06 2013-12-25 湖南泰鑫瓷业有限公司 Preparation method of beige high brightness metal glaze
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