CN103408328A - Ceramic glaze and preparation method thereof - Google Patents
Ceramic glaze and preparation method thereof Download PDFInfo
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- CN103408328A CN103408328A CN2013103305401A CN201310330540A CN103408328A CN 103408328 A CN103408328 A CN 103408328A CN 2013103305401 A CN2013103305401 A CN 2013103305401A CN 201310330540 A CN201310330540 A CN 201310330540A CN 103408328 A CN103408328 A CN 103408328A
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Abstract
The invention provides ceramic glaze. The ceramic glaze comprises the following components by weight percent: 34.8-35.3% of feldspar minerals, 5.5-6.5% of kaolin, 16.5-18.2% of quartz, 10.6-12.2% of dolomite, 5-6.3% of zinc oxide, 6.8-7.8% of titanium dioxide, 11.8-12.4% of calcium hydrophosphate, 4.4-4.7% of ferric oxide and 8.3-9.8% of fruit tree ashes. According to the ceramic glaze, natural mineral materials, which are used as solvents in the prior art, are replaced with the fruit tree ashes or reduced, so that the suspension property of the ceramic glaze can be improved, the function of presenting a crystal effect can be achieved, and the ceramic glaze is environment-friendly, and can be recycled. Besides, the invention further discloses a preparation method of the ceramic glaze.
Description
Technical field
The present invention relates to chemical field, refer to especially a kind of ceramic glaze, the invention still further relates to a kind of preparation method of ceramic glaze.
Background technology
In existing ceramic sintering process, the formula of ceramic glaze usually adopts the powder of the natural mineral matters such as feldspar, quartz, Wingdale, calcium carbonate, lead to be used as solvent or increases the suspension of glaze, generally in the formula of glaze, add and do not wait in 3% to 70% ratio, but adopt traditional natural crystal that the multiple long-term scientific development that the disadvantageous factor existence of long-run development is contrary to industry is arranged, such as, natural mineral belongs to Nonrenewable resources, long-term a large amount of exploitation, be unfavorable for the development of being longer than; Simultaneously, natural mineral throughout the country distribution and quality all level is uneven, the development of extensive style also can damage physical environment; If the mineral of above-mentioned use directly use generally need to be milled to the fineness that can cross 250 to 350 eye mesh screen density, the larger price of fineness of using is also higher, and be that the technique of finished product is loaded down with trivial details from digging up mine to ball milling, and manufacturer's extensive style ball-milling technology also generally needs the Ball-milling Time of 20 to 30 hours, its machine cost and time cost be quite high and waste also; Above-mentioned or similar natural mineral purity after processing is all higher, for art with the modulation of ceramic glaze and the exploitation, it lacks wider possibility, glaze is fired to effect and cause certain limitation etc., and, being fired into because being to be in state of saturation after the crystalline material melting in glaze in the product sintering process of more famous and crystalline glaze that range of application is wider in traditional ceramics technique, utilize the control of annealing process produced to crystallization, thereby separate out the crystallization of various decorative patterns.Generally to adopt zinc oxide, plumbous, the mineral such as lithium type oxide add the material proportion in glaze formula by increase or in sintering procedure, adopt the steep temperature rise of local temperature section or the processing method of cooling to obtain effect, but these traditional techniques need higher material cost or the state of the art of firing the master worker and the experience of firing are had to higher requirement, but because the art pottery is teaching privately between master and apprentice among the people in development since ancient times, cause the utilization to material never to obtain too large change, and domestic training for sintering technology and education also are in the stage comparatively fallen behind, so can grasp preferably master worker indivedual crowds that also majority is older and quantity is few of these sintering technology, above these are all not meet now society to the demand for development of industry and actual demand.
Summary of the invention
The present invention proposes a kind of ceramic glaze and preparation method thereof, has solved or has alleviated the above-mentioned problem of mentioning.
Technical scheme of the present invention is achieved in that a kind of ceramic glaze, comprises each component of following weight part:
The mineral 34.8-35.3% of feldspar family, kaolin 5.5-6.5%,
Quartzy 16.5-18.2%, rhombspar 10.6-12.2%,
Zinc oxide 5-6.3%, titanium dioxide 6.8-7.8%,
Secondary calcium phosphate 11.8-12.4%, ferric oxide 4.4-4.7%,
Fruit tree ash 8.3-9.8%.
Preferably, adopt each component of following weight part:
Feldspar family mineral 35.1%, kaolin 5.9%,
Quartz 17.6%, rhombspar 11.7%,
Zinc oxide 5.9%, titanium dioxide 7.5%,
Secondary calcium phosphate 11.7%, ferric oxide 4.6%,
Fruit tree ash 9%.
Preferably, described feldspar family mineral adopt any in potassium felspar sand, albite and nepheline syenite.
Preferably, described fruit tree ash adopts the litchi wood ash.
Further, described fruit tree ash adopts following technique to make:
(1) gather lichee fruit tree and branches and leaves and sort;
(2) fruit tree and branches and leaves impact cutting are become to fritter and be positioned in clean water basin, wetting fruit tree also carries out the secondary sorting;
(3) soak after 1-2 days fruit tree and branches and leaves are picked up and be placed in gas furnace with the temperature baking 10-15 hour of 100-180 ℃, or be placed under the sun 4-5 days that is exposed to the sun;
(4) fruit tree after drying and branches and leaves are put into fiery pit in batches and are burnt, and when to burning, producing the wood ash volume and reach the 80-85% of fiery pit volume, stop putting into fruit tree and branches and leaves;
While (5) in fiery pit, there is no naked light, namely with the iron sand net of 60-80 order density, fiery pit is built to smoldering 8-10 hour;
(6) after the wood ash in fiery pit is cooling, its taking-up is placed in to container, and adds clear water to obtain wood ash water, the ratio of wood ash and clear water is 1:1.5, standing 10-15 hour after fully stirring;
(7) by the wood ash water after standing with standing 2-3 hour again after the screen filtration of 60 order density 2-3 time, water is poured out;
The wood ash that (8) will be left takes out and air-dryly at 2-5%, gets final product to water content.
The preparation method of described ceramic glaze comprises the following steps:
I, except the fruit tree ash, other material ratio in the desired amount in glaze formula is added in the abrading-ball of ball mill, adding weight is the clear water ball milling 30-40 minute of material 1/2nd ratios;
II, in proportion required fruit tree ash is held with container, adding weight is the hot water of fruit tree ash 1/3rd, and the hot water temperature is between 50 ℃ to 90 ℃, and stirs;
III, the fruit tree buck after stirring are poured in abrading-ball, then ball milling 10-20 minute just can pour all material into splendid attire in clean container;
The clear water that IV, the glaze Material Addition that ball milling is good are applicable to the glazing deal namely completes.
Beneficial effect of the present invention is:
Ceramic glaze described in the present invention utilizes described fruit tree ash to replace or reduces in traditional technology and adopt natural minerals in ceramic glaze, to make solvent, increase the suspension of glaze or present the effect of crystallization effect;
Drawing materials of described fruit tree ash is very convenient, environmental protection, is a kind of resource of reusable edible.Its manufacture craft also compares, and the making of traditional mineral material is simple, flow process is few, yield rate is high, the measured characteristics of matter;
The preparation method's of described ceramic glaze disclosed by the invention applied range and easy to understand, to the reduction of production cost and technician's training is all played to goodish effect;
Adopt described fruit tree ash that the present invention makes in the modulation of ceramic glaze, to the demand of other material, can reduce, and the fineness of material is required to reduce at least 40% to 55%;
The interpolation of described fruit tree ash in ceramic glaze of adopting the present invention to make, can enlarge the possibility to the glaze formula exploitation, and can reduce human cost and the material cost of exploitation.
Embodiment
Below in conjunction with following examples, technical scheme of the present invention is clearly and completely described, obviously, described embodiment is only the present invention's part embodiment, rather than whole embodiment.Based on the embodiment in the present invention, those of ordinary skills, not making under the creative work prerequisite the every other embodiment obtained, belong to the scope of protection of the invention.
Embodiment 1
Adopt content disclosed by the invention, proceed as follows, at first, preparation litchi wood ash:
(1) gather lichee fruit tree and branches and leaves and sort, wherein the weight ratio of fruit tree and branches and leaves is 9:1;
(2) fruit tree and branches and leaves impact cutting are become to fritter and be positioned in clean water basin, the density principle of wetting fruit tree different substances is carried out the secondary sorting;
(3) soak after 2 days fruit tree and branches and leaves are picked up and be placed in gas furnace with the temperature baking of 160 ℃ 13 hours, avoid the naked light of coal gas firelock directly to burn the fruit tree branch, certainly, also can according to actual situation, be placed under the sun 4-5 days that is exposed to the sun;
(4) fruit tree after drying and branches and leaves are put into fiery pit in batches and are burnt, this fiery pit can be that watt brick is built folded square fiery pit of leaving equably ventilation opening in the place of ventilation and no-sundries, can be also in direct mud ground nearby, to dig the mud pit of a 300-500ml, particular case determines according to the residing situation of reality, to burning produce the wood ash volume reach the fiery pit volume 85% the time, stop putting into fruit tree and branches and leaves;
While (5) in fiery pit, there is no naked light, namely with the iron sand net of 80 order density, fiery pit is built to smoldering 10 hours;
(6) after the wood ash in fiery pit is cooling, its taking-up is placed in to container, and adds clear water to obtain wood ash water, the ratio of wood ash and clear water is 1:1.5, fully stirs latter standing 13 hours;
(7) by the wood ash water after standing with after the screen filtration of 60 order density 3 times standing 2.5 hours again, water is poured out;
(8) remaining wood ash taken out and air-dryly 3%, namely obtain required litchi wood ash to water content, we therefrom take 9Kg, standby rear use.
Preparation method according to ceramic glaze disclosed by the invention proceeds as follows:
I, except the fruit tree ash, by other material in glaze formula: potassium felspar sand 35.1Kg, kaolin 5.9Kg, quartzy 17.6Kg, rhombspar 7.5Kg, zinc oxide 5.9Kg, titanium dioxide 4.6Kg, secondary calcium phosphate 11.7Kg, ferric oxide 4.6Kg is added in the abrading-ball of ball mill, and adding weight is the clear water ball milling 40 minutes of material 1/2nd ratios;
II, in proportion 9Kg fruit tree ash is held with container, adding weight is 80 ℃ of hot water of fruit tree ash 1/3rd, and stirs;
III, the fruit tree buck after stirring are poured in abrading-ball, then ball milling just can be poured all material into splendid attire in clean container in 15 minutes;
The clear water that IV, the glaze Material Addition that ball milling is good are applicable to the glazing deal namely completes, in the present embodiment, the clear water that is applicable to the glazing deal is 32Kg, difference according to formula, the adjustment one that this ratio also can adapt to meets the requirement of fully dissolving, and the weight of general clear water is that the glaze material weight is than being 30-40:100.
Finally, fire after invention sprays the ceramic glaze obtained, its sintering procedure is:
In electrical kiln, in 8.5 hours, be warming up to 1240 ℃, and maintain 20min, cooling getting final product gradually then, and in electrical kiln, free oxygen level is 1.1-1.23%, carbon monoxide content is 0.6-0.9%.
Also can in the gas kiln, fire, process is for to be warming up to gradually 1240 ℃ in 11.5 hours, and maintains 30min, and then cooling get final product gradually, and the oxygen level of dissociating in the gas kiln is 4.1-4.3%, and carbon monoxide content is 0.2-0.73%.
Ceramic glaze of the present invention utilize the plant ashes replace traditional natural mineral in ceramic glaze addition or reduce its interpolation, to reach the crystalline glaze effect of firing before not replacing, even can burn out the special glazing effect of " glaze is double-colored ", its also alternative traditional mineral material in ceramic glaze, serve as the functions such as suspension agent and solvent, the plant ashes that adopt in the present invention are the litchi wood ash, certain vegetation characteristics according to various places, also can adopt other plant ashes, whole technique and fill a prescription basically identical.
The foregoing is only preferred embodiment of the present invention, in order to limit the present invention, within the spirit and principles in the present invention not all, any modification of doing, be equal to replacement, improvement etc., within all should being included in protection scope of the present invention.
Claims (6)
1. a ceramic glaze, is characterized in that, comprises each component of following weight part:
The mineral 34.8-35.3% of feldspar family, kaolin 5.5-6.5%,
Quartzy 16.5-18.2%, rhombspar 10.6-12.2%,
Zinc oxide 5-6.3%, titanium dioxide 6.8-7.8%,
Secondary calcium phosphate 11.8-12.4%, ferric oxide 4.4-4.7%,
Fruit tree ash 8.3-9.8%.
2. ceramic glaze described in claim 1, is characterized in that, comprises each component of following weight part:
Feldspar family mineral 35.1%, kaolin 5.9%,
Quartz 17.6%, rhombspar 11.7%,
Zinc oxide 5.9%, titanium dioxide 7.5%,
Secondary calcium phosphate 11.7%, ferric oxide 4.6%,
Fruit tree ash 9%.
3. as ceramic glaze as described in arbitrary in claim 1 or 2, it is characterized in that: described feldspar family mineral are any in potassium felspar sand, albite and nepheline syenite.
4. as ceramic glaze as described in arbitrary in claim 1 or 2, it is characterized in that: described fruit tree ash is the litchi wood ash.
5. ceramic glaze described in claim 4 is characterized in that: described fruit tree ash adopts following technique to make:
(1) gather lichee fruit tree and branches and leaves and sort;
(2) fruit tree and branches and leaves impact cutting are become to fritter and be positioned in clean water basin, wetting fruit tree also carries out the secondary sorting;
(3) soak after 1-2 days fruit tree and branches and leaves are picked up and be placed in gas furnace with the temperature baking 10-15 hour of 100-180 ℃, or be placed under the sun 4-5 days that is exposed to the sun;
(4) fruit tree after drying and branches and leaves are put into fiery pit in batches and are burnt, and when to burning, producing the wood ash volume and reach the 80-85% of fiery pit volume, stop putting into fruit tree and branches and leaves;
While (5) in fiery pit, there is no naked light, namely with the iron sand net of 60-80 order density, fiery pit is built to smoldering 8-10 hour;
(6) after the wood ash in fiery pit is cooling, its taking-up is placed in to container, and adds clear water to obtain wood ash water, the ratio of wood ash and clear water is 1:1.5, standing 10-15 hour after fully stirring;
(7) by the wood ash water after standing with standing 2-3 hour again after the screen filtration of 60 order density 2-3 time, water is poured out;
The wood ash that (8) will be left takes out and air-dryly at 2-5%, gets final product to water content.
6. as the preparation method of ceramic glaze as described in arbitrary in claim 1-5, it is characterized in that, comprise the following steps:
I, except the fruit tree ash, other material ratio in the desired amount in glaze formula is added in the abrading-ball of ball mill, adding weight is the clear water ball milling 30-40 minute of material 1/2nd ratios;
II, in proportion required fruit tree ash is held with container, adding weight is the hot water of fruit tree ash 1/3rd, and the hot water temperature is between 50 ℃ to 90 ℃, and stirs;
III, the fruit tree buck after stirring are poured in abrading-ball, then ball milling 10-20 minute just can pour all material into splendid attire in clean container;
The clear water that IV, the glaze Material Addition that ball milling is good are applicable to the glazing deal namely completes.
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| CN201310330540.1A CN103408328B (en) | 2013-07-31 | 2013-07-31 | Ceramic glaze and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103896558A (en) * | 2014-03-12 | 2014-07-02 | 湖南港鹏实业有限公司 | Preparation method of infrared ceramic vacuum cup and product prepared by same |
| CN104829268A (en) * | 2015-05-07 | 2015-08-12 | 东莞市唯美陶瓷工业园有限公司 | Glaze for fast-fired crystal glaze ceramic tile, and preparation method and applications of ceramic tile |
| CN105859138A (en) * | 2016-04-06 | 2016-08-17 | 温州任和教育科技有限责任公司 | High-strength high-fire-resistance ceramic glaze and preparation method thereof |
| CN111892299A (en) * | 2020-07-29 | 2020-11-06 | 王混正 | Jiulongshan mountain natural ore transmutation glaze and preparation method thereof |
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| CN101659566A (en) * | 2008-10-21 | 2010-03-03 | 东莞市莲子村陶品有限公司 | Suboptical black grinding glaze material |
| CN101747089A (en) * | 2008-12-16 | 2010-06-23 | 郭秀贞 | Ru agate glaze and processing method and application thereof |
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| CN101659566A (en) * | 2008-10-21 | 2010-03-03 | 东莞市莲子村陶品有限公司 | Suboptical black grinding glaze material |
| CN101747089A (en) * | 2008-12-16 | 2010-06-23 | 郭秀贞 | Ru agate glaze and processing method and application thereof |
| CN102557584A (en) * | 2012-02-20 | 2012-07-11 | 范晨雨 | Jade-like Ru porcelain and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103896558A (en) * | 2014-03-12 | 2014-07-02 | 湖南港鹏实业有限公司 | Preparation method of infrared ceramic vacuum cup and product prepared by same |
| CN103896558B (en) * | 2014-03-12 | 2015-03-25 | 湖南港鹏实业有限公司 | Preparation method of infrared ceramic vacuum cup and product prepared by same |
| CN104829268A (en) * | 2015-05-07 | 2015-08-12 | 东莞市唯美陶瓷工业园有限公司 | Glaze for fast-fired crystal glaze ceramic tile, and preparation method and applications of ceramic tile |
| CN104829268B (en) * | 2015-05-07 | 2017-09-26 | 东莞市唯美陶瓷工业园有限公司 | Preparation method and the application of a kind of fast sinter glaze Ceramic Tiles glaze and Ceramic Tiles |
| CN105859138A (en) * | 2016-04-06 | 2016-08-17 | 温州任和教育科技有限责任公司 | High-strength high-fire-resistance ceramic glaze and preparation method thereof |
| CN105859138B (en) * | 2016-04-06 | 2018-08-31 | 伟业陶瓷有限公司 | A kind of ceramic glaze and preparation method thereof that the high fire resistance of intensity is good |
| CN111892299A (en) * | 2020-07-29 | 2020-11-06 | 王混正 | Jiulongshan mountain natural ore transmutation glaze and preparation method thereof |
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| CN103408328B (en) | 2015-01-21 |
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Effective date of registration: 20191212 Address after: Chengdong Industrial Zone of Dehua County of Quanzhou City, Fujian province 362500 in Jiujiang Town Patentee after: Quanzhou Dehua Jiaoli Crafts Co., Ltd. Address before: 528010, No. 5, No. six, 22, Jihua Road, Chancheng District, Guangdong, Foshan, 512 Patentee before: Cai Huanyi |