CN102718471A - Green body of red soil ceramic and formula of transmutation glaze of red soil ceramic - Google Patents
Green body of red soil ceramic and formula of transmutation glaze of red soil ceramic Download PDFInfo
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- CN102718471A CN102718471A CN2012101744151A CN201210174415A CN102718471A CN 102718471 A CN102718471 A CN 102718471A CN 2012101744151 A CN2012101744151 A CN 2012101744151A CN 201210174415 A CN201210174415 A CN 201210174415A CN 102718471 A CN102718471 A CN 102718471A
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- red soil
- glaze
- green body
- parts
- ceramic
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- 239000002689 soil Substances 0.000 title claims abstract description 34
- 238000009377 nuclear transmutation Methods 0.000 title claims abstract description 18
- 239000000919 ceramic Substances 0.000 title abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 30
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 29
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 238000010304 firing Methods 0.000 claims abstract description 18
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 16
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000292 calcium oxide Substances 0.000 claims abstract description 15
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 15
- 239000010453 quartz Substances 0.000 claims abstract description 10
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 8
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims abstract description 8
- 239000000454 talc Substances 0.000 claims abstract description 8
- 229910052623 talc Inorganic materials 0.000 claims abstract description 8
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000011787 zinc oxide Substances 0.000 claims abstract description 8
- 229910052656 albite Inorganic materials 0.000 claims abstract description 3
- 239000000758 substrate Substances 0.000 claims description 27
- 229910052700 potassium Inorganic materials 0.000 claims description 16
- 235000012255 calcium oxide Nutrition 0.000 claims description 14
- 229910001710 laterite Inorganic materials 0.000 claims description 13
- 239000011504 laterite Substances 0.000 claims description 13
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 9
- 239000011734 sodium Substances 0.000 claims description 9
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 239000011591 potassium Substances 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims description 7
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- 235000012222 talc Nutrition 0.000 claims description 7
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 7
- 239000004576 sand Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 abstract description 5
- 230000009931 harmful effect Effects 0.000 abstract description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000011707 mineral Substances 0.000 abstract description 3
- 235000019738 Limestone Nutrition 0.000 abstract 1
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 abstract 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 abstract 1
- 239000003086 colorant Substances 0.000 abstract 1
- 239000010459 dolomite Substances 0.000 abstract 1
- 229910000514 dolomite Inorganic materials 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 239000000446 fuel Substances 0.000 abstract 1
- 239000006028 limestone Substances 0.000 abstract 1
- 230000036314 physical performance Effects 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- -1 silicate compound Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000002915 spent fuel radioactive waste Substances 0.000 description 1
Abstract
The invention relates to a green body of red soil ceramic. The green body of the red soil ceramic is prepared from the following raw materials: red soil, quartz, talc, limestone and dolomite; the transmutation glaze of the red soil ceramic is prepared from the following raw materials: potassium feldspar, albite, calcium oxide, barium oxide, kaolin, quartz powder, sodium tripolyphosphate, titanium oxide, rutile, zinc oxide and a coloring agent. By addition of other mineral raw materials, chemical raw materials and the like, the physical performance and the chemical performance of the green body are changed and the technical problems that the green body glaze of the red soil product is difficult to combine and the product is loose and fragile are solved; the firing temperature of the glaze is reduced from 1,310 DEG C to 1,230 DEG C, so thatthe firing temperature is reduced by 80 DEG C, the using amount of the fuel and the discharge quantity of harmful gas are reduced, environmental protection is contributed and production cost is greatly saved; and by development of the lead-free transmutation glaze, the lead-free transmutation glaze is suitable for being combined with the green body of the red soil ceramic, so that the problem of pollution to the ceramic decorative environment is solved fundamentally.
Description
Technical field
The present invention relates to the prescription of a kind of ceramic body and cover-coat enamel thereof, be meant a kind of base substrate of red soil pottery and the prescription of transmutation glaze thereof especially.
Background technology
The main raw material laterite aboundresources of laterite base substrate, the good and easy-formation of plasticity, firing range is wide, can be from 1000 ℃ to 1250 ℃, but most of laterite is because of the directly glazing of reason of its coefficient of expansion, and the Chemical Composition of laterite is mainly 52.78% SiO
2, 33.57% Al
2O
3, 10.43% Fe
20
3, 3.16% K
2O, 0.06% Na
2O.Only be the raw material of preparation base substrate with laterite, its SiO
2Content is on the low side, Al
2O
3, Fe
2O
3Content is higher, is unfavorable for the formation of silicate compound; K
2O, Na
2O content mainly influences the biscuiting temperature of base substrate, and too high levels can make the base substrate firing temperature reduce and is unfavorable for the formation of cristobalite; Can reduce the base substrate coefficient of expansion; Influence that the base glaze combines and produce glaze and split defective, quartz, potassium felspar sand, mullite are arranged, glassy phase and pore etc. in the mineral composition because of base substrate; Wherein glassy phase is few, so the base substrate porous.
In addition, because the chemical constitution difference of the glaze that existing red soil is made pottery is bigger, the coefficient of expansion of glaze is higher, and the firing temperature of glaze also reaches 1310 ℃ height, very easily produces early stage glaze and splits, and spent fuel is also bigger, and production cost is higher; For this reason; Glaze is usually to contain lead solution as solvent; And on red soil greenwave body, apply the bigger lead of elasticity one boron glaze; This can offset the harmful effect that the thermal expansion of base glaze is caused within the specific limits, but this also makes product have the excessive shortcoming of lead release, causes product on domestic ceramics, not use.
Summary of the invention
The present invention provides a kind of base substrate of red soil pottery and the prescription of transmutation glaze thereof; Be not easy glazing, be prone to produce that glaze splits, the base substrate porous with what overcome that base substrate that existing red soil makes pottery exists, and the firing temperature that red soil bristol glaze material exists is high, problems such as early stage glaze splits, the product lead release big, can not on domestic ceramics, use very easily take place.
The present invention adopts following technical scheme:
Red soil greenwave body, the preparation of this base substrate comprises following raw material: laterite, quartz, talcum, Wingdale, rhombspar; More particularly, the preparation raw material of this base substrate comprises following component: 49.3% SiO
2, 26.3% Al
2O
3, 2.1% Fe
20
3, 1.6% K
2O, 1.9% MgO, 18.8% CaO.
Red soil pottery transmutation glaze, the preparation of this glaze comprises following raw material: potassium felspar sand 35-40 part, albite 22-25 part, quicklime 8-15 part, barium oxide 15-20 part, Longyan kaolin 8-15 part, silica powder 6-12 part, tripoly phosphate sodium STPP 0.2-0.4 part, titanium oxide 10-20 part, rutile 2-10 part, zinc oxide 3-10 part; The preparation raw material of this glaze also comprises the tinting material of 3-25 part.
The firing temperature of this glaze is 1210 ℃～1250 ℃; More specifically, the firing temperature of this glaze is 1230 ℃.
Can know by the above-mentioned description of this invention; Compare with prior art; The present invention has following advantage: through adding other mineral raw material and industrial chemicals etc., changed the physical and chemical performance of base substrate, solution laterite product base glaze combines to be difficult to and the frangible technical barrier of the uncommon pine of product quality; The firing temperature of glaze is reduced to 1230 ℃ by 1310 ℃, and firing temperature has reduced by 80 ℃, has reduced and has burnt till energy consumption; Reduced the quantity discharged of firing rate and harmful body; Both help environment protection, also practiced thrift a large amount of production costs, also improved the class and the share of market of product; Low temperature frit glaze formula to traditional is reformed, and introduces novel material, replaces plumbous oxide, develops unleaded transmutation glaze, makes it to be suitable for red soil greenwave body, fundamentally solves the ceramic decoration problem of environmental pollution.
Embodiment
Embodiment one
This embodiment is a preferred implementation.
Red soil greenwave body, the preparation of this base substrate comprises following raw material: laterite, quartz, talcum, Wingdale, rhombspar; More particularly, the preparation raw material of this base substrate comprises following component: 49.3% SiO
2, 26.3% Al
2O
3, 2.1% Fe
20
3, 1.6% K
2O, 1.9% MgO, 18.8% CaO.
Red soil pottery transmutation glaze, the preparation of this glaze comprises following raw material: 37 parts of potassium felspar sands, 23 parts of albites, 12 parts in quicklime, 18 parts in barium oxide, 12 parts of Longyan kaolin, 9 parts of silica powders, 0.3 part of tripoly phosphate sodium STPP, 15 parts of titanium oxide, 6 parts of rutile, 8 parts in zinc oxide, 14 parts of tinting materials; The firing temperature of this glaze is 1230 ℃.
Embodiment two
Red soil greenwave body, the preparation of this base substrate comprises following raw material: laterite, quartz, talcum, Wingdale, rhombspar; More particularly, the preparation raw material of this base substrate comprises following component: 49.3% SiO
2, 26.3% Al
2O
3, 2.1% Fe
20
3, 1.6% K
2O, 1.9% MgO, 18.8% CaO.
Red soil pottery transmutation glaze, the preparation of this glaze comprises following raw material: 35 parts of potassium felspar sands, 25 parts of albites, 8 parts in quicklime, 15 parts in barium oxide, 15 parts of Longyan kaolin, 6 parts of silica powders, 0.4 part of tripoly phosphate sodium STPP, 20 parts of titanium oxide, 2 parts of rutile, 10 parts in zinc oxide; The firing temperature of this glaze is 1210 ℃.
Embodiment three
Red soil greenwave body, the preparation of this base substrate comprises following raw material: laterite, quartz, talcum, Wingdale, rhombspar; More particularly, the preparation raw material of this base substrate comprises following component: 49.3% SiO
2, 26.3% Al
2O
3, 2.1% Fe
20
3, 1.6% K
2O, 1.9% MgO, 18.8% CaO.
Red soil pottery transmutation glaze, the preparation of this glaze comprises following raw material: 40 parts of potassium felspar sands, 22 parts of albites, 15 parts in quicklime, 20 parts in barium oxide, 8 parts of Longyan kaolin, 12 parts of silica powders, 0.2 part of tripoly phosphate sodium STPP, 10 parts of titanium oxide, 10 parts of rutile, 3 parts in zinc oxide, 25 parts of tinting materials; The firing temperature of this glaze is 1250 ℃.
Embodiment four
Red soil greenwave body, the preparation of this base substrate comprises following raw material: laterite, quartz, talcum, Wingdale, rhombspar; More particularly, the preparation raw material of this base substrate comprises following component: 49.3% SiO
2, 26.3% Al
2O
3, 2.1% Fe
20
3, 1.6% K
2O, 1.9% MgO, 18.8% CaO.
Red soil pottery transmutation glaze, the preparation of this glaze comprises following raw material: 38 parts of potassium felspar sands, 24 parts of albites, 10 parts in quicklime, 16 parts in barium oxide, 13 parts of Longyan kaolin, 8 parts of silica powders, 0.3 part of tripoly phosphate sodium STPP, 12 parts of titanium oxide, 4 parts of rutile, 5 parts in zinc oxide, 14 parts of tinting materials; The firing temperature of this glaze is 1230 ℃.
Embodiment five
Red soil greenwave body, the preparation of this base substrate comprises following raw material: laterite, quartz, talcum, Wingdale, rhombspar; More particularly, the preparation raw material of this base substrate comprises following component: 49.3% SiO
2, 26.3% Al
2O
3, 2.1% Fe
20
3, 1.6% K
2O, 1.9% MgO, 18.8% CaO.
Red soil pottery transmutation glaze, the preparation of this glaze comprises following raw material: 36 parts of potassium felspar sands, 25 parts of albites, 13 parts in quicklime, 19 parts in barium oxide, 10 parts of Longyan kaolin, 10 parts of silica powders, 0.3 part of tripoly phosphate sodium STPP, 18 parts of titanium oxide, 8 parts of rutile, 9 parts in zinc oxide, 3 parts of tinting materials; The firing temperature of this glaze is 1230 ℃.
Above-mentionedly be merely embodiment of the present invention, but design concept of the present invention is not limited thereto, allly utilizes this design that the present invention is carried out the change of unsubstantiality, all should belong to the behavior of invading protection domain of the present invention.
Claims (6)
1. red soil greenwave body is characterized in that, the preparation of this base substrate comprises following raw material: laterite, quartz, talcum, Wingdale, rhombspar.
2. red soil greenwave body as claimed in claim 1 is characterized in that the preparation raw material of said base substrate comprises following component: 49.3% SiO
2, 26.3% Al
2O
3, 2.1% Fe
20
3, 1.6% K
2O, 1.9% MgO, 18.8% CaO.
3. red soil pottery transmutation glaze; It is characterized in that the preparation of this glaze comprises following raw material: potassium felspar sand 35-40 part, albite 22-25 part, quicklime 8-15 part, barium oxide 15-20 part, kaolin 8-15 part, silica powder 6-12 part, tripoly phosphate sodium STPP 0.2-0.4 part, titanium oxide 10-20 part, rutile 2-10 part, zinc oxide 3-10 part.
4. red soil pottery transmutation glaze as claimed in claim 3, it is characterized in that: the preparation raw material of this glaze comprises the tinting material of 3-25 part.
5. red soil pottery transmutation glaze as claimed in claim 3 is characterized in that: the firing temperature of this glaze is 1210 ℃～1250 ℃.
6. red soil pottery transmutation glaze as claimed in claim 5, it is characterized in that: the firing temperature of this glaze is 1230 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210174415 CN102718471B (en) | 2012-05-31 | 2012-05-31 | Green body of red soil ceramic and formula of transmutation glaze of red soil ceramic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210174415 CN102718471B (en) | 2012-05-31 | 2012-05-31 | Green body of red soil ceramic and formula of transmutation glaze of red soil ceramic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102718471A true CN102718471A (en) | 2012-10-10 |
| CN102718471B CN102718471B (en) | 2013-06-12 |
Family
ID=46944378
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201210174415 Active CN102718471B (en) | 2012-05-31 | 2012-05-31 | Green body of red soil ceramic and formula of transmutation glaze of red soil ceramic |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102718471B (en) |
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| CN102976795A (en) * | 2012-12-04 | 2013-03-20 | 福建省德化县科力陶瓷厂 | Medium-temperature color glaze formula and sintering process thereof |
| CN103232221A (en) * | 2013-04-28 | 2013-08-07 | 福建德化新耀华瓷业有限公司 | Red pottery and preparation process thereof |
| CN103396093A (en) * | 2013-08-07 | 2013-11-20 | 陈永定 | Red soil earthenware and manufacturing method thereof |
| CN104058790A (en) * | 2014-06-26 | 2014-09-24 | 德化恒忆陶瓷艺术股份有限公司 | Furnace transmutation glaze and application method thereof |
| CN104058789A (en) * | 2014-04-30 | 2014-09-24 | 福建省嘉顺艺品股份有限公司 | Starlight enamel glaze material and application technique thereof |
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