CN101041269A - Tube shaped memory complex with expended space and the preparing method thereof - Google Patents
Tube shaped memory complex with expended space and the preparing method thereof Download PDFInfo
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- CN101041269A CN101041269A CN 200710071897 CN200710071897A CN101041269A CN 101041269 A CN101041269 A CN 101041269A CN 200710071897 CN200710071897 CN 200710071897 CN 200710071897 A CN200710071897 A CN 200710071897A CN 101041269 A CN101041269 A CN 101041269A
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Abstract
The invention relates to a space big-expansion tube shape memory composite and the preparing method for solving problems that the weight of expansion structure of conventional shape memory material is big, the expansion is unstable and the reversible process of curling and expanding is operated difficultly. Two ends of each segment of axial looping shape memory alloy are connected with one end of a segment of shape memory polymer composite respectively. The invention comprises that resin is coated on fiber cloth face uniformly; the axial looping shape memory alloy is buried in one side of fiber cloth; the solidification is carried out; tube figure and polymer composite are formed. The shape memory composite in invention is provided with light weight, small occupied cubage, low strain inner energy, high modulus ratio, good shape memory characteristic, big expanding radius, stable expanding structure and easy operation for the reversible process of curling and expanding. The preparing method is provided with simple operation.
Description
Technical field
It relates to a kind of tube shaped memory complex with expended space and preparation method thereof.
Background technology
Therefore shape-memory polymer has been subjected to increasing attention owing to can be used for fields such as medical science, Aero-Space, Based Intelligent Control.Shape memory polymer material all has two phase structure: promptly by the fixedly phase of shape memory with vary with temperature the reversible phase composition that can reversibly solidify and soften.Fixing being generally the mutually unformed area with cross-linked structure fixingly is called the thermoplasticity shape-memory polymer for the physical crosslinking structure mutually; Fixing have the chemical crosslinking structure mutually be called the thermoset shape memory polymer.Reversible varying with temperature mutually can reversibly be solidified and soften, and has the physical crosslinking structure.
Shape-memory polymer has the essential characteristic of polymer when transition temperature is following; When transition temperature is above very big distortion can be arranged, strain can reach percent hundreds of, and such distortion can recover fully; Its polymeric material has excellent mechanical properties such as high specific strength that the resin-based polymeric material has, high specific stiffness.The research of shape-memory polymer is ripe relatively, shape memory polyurethane, shape memory polyester, shape memory epoxy resin, shape memory cyanate, shape memory styrene, shape memory SB, shape memory using trans-polyisoprene, shape memory polynorbornene and pla-pcl thermosetting and thermoplasticity shape memory polymer material have occurred.Because the plurality of advantages and the wide application prospect in the space development field thereof of shape memory polymer composite material, and traditional deployed configuration exists that weight is big, deployment diameter is little, the deployed configuration strength and stiffness are low, the deployed configuration internal stress big, take when curling that volume is big, deployed configuration is unstable and the problems such as difficult operability of curling expansion reversible process, and the research in this field and Related product thereof just are being subjected to countries in the world scientist's attention.
Summary of the invention
For solve conventional shape-memory material space deployed configuration weight big, take when curling volume big, launch that radius is little, deployed configuration is unstable and the problem of the difficult operability of curling expansion reversible process, the invention provides a kind of tube shaped memory complex with expended space and preparation method thereof.
Tube shaped memory complex with expended space of the present invention is made up of multistage shape memory polymer composite material and the axial articulating marmem of multistage, and the two ends of described every section axial articulating marmem connect an end of one section shape memory polymer composite material respectively; One end one-shot forming of one end of every section axial articulating marmem and one section shape memory polymer composite material, the other end then are connected by binding material with an end of another section shape memory polymer composite material.
The preparation method of tube shaped memory complex with expended space of the present invention is finished by the following step:
A, selection fiber weaving cloth;
B, resin is evenly coated on the surface of fiber cloth;
C, marmem is embedded in an end of fiber cloth; Be placed in the vacuum bag then;
D, the fiber cloth after previous step is finished suddenly is crimped onto on the tubular die then, solidifies again;
Slough vacuum bag after E, the curing, make tubular form memory polymer material and the axially contact jaw one-shot forming of articulating marmem;
The other end of F, axial articulating marmem and an end of another shape memory polymer composite material cohere, and form tubular form memory complex;
G, tubular form is remembered complex be heated to and make it become writing board shape more than the transition temperature, writing board shape is remembered complex be crimped onto on the bobbin type heater, form shape memory complex with space development tubular structure from another direction.
That tube shaped memory complex with expended space of the present invention has is in light weight, take that volume is little, launch cost is low, can be low in the strain, modular ratio is high, shape memory characteristic good, launch that radius is big, deployed configuration stable and curl to launch the easy-operating advantage of reversible process, the preparation method of tube shaped memory complex with expended space of the present invention has advantage simple to operate.
Description of drawings
Fig. 1 is a structural representation of the present invention, and the structural representation of Fig. 2 specific embodiment one, Fig. 3 are that the vertical direction spatial of tube shaped memory complex with expended space launches schematic diagram.
The specific embodiment
The specific embodiment one: specify present embodiment below in conjunction with Fig. 1 and Fig. 2, present embodiment is made up of multistage shape memory polymer composite material 1 and the axial articulating marmem 2 of multistage, and the two ends of described every section axial articulating marmem 2 connect an end of one section shape memory polymer composite material 1 respectively; One end one-shot forming of one end of every section axial articulating marmem 2 and one section shape memory polymer composite material 1, the other end then are connected by binding material with an end of another section shape memory polymer composite material 1.Shape memory polymer composite material hop count in the general structure is 5～10.Binding material is for cohering shape memory resin, employing be the epoxy type shape memory resin, with the resin of formed shape memory polymer composite can be a kind of, can not be a kind of also, mainly be according to viscosity and go up hardening time and accept or reject.Sheet composition is connected into a longer sheet composition by marmem, and length dimension can reach nearly 10m, then it is not had heating under the external force effect, and such long slab composite just can revert back to the original state of tubulose.Can prove that the structure after the connection has the shape memory characteristic of shape memory polymer composite material equally.
The specific embodiment two: the following present embodiment that specifies, every section shape memory polymer composite material 1 is curled into tubulose in the present embodiment, described every section axial articulating marmem 2 is curled into ring-type, and other composition and annexation are with the specific embodiment one.
The specific embodiment three: the following present embodiment that specifies, every section shape memory polymer composite material 1 is made up of shape memory polymer material and fibre reinforced materials in the present embodiment; The volume percent content of described shape memory polymer material in every section shape memory polymer composite material 1 is 60～99%, the volume percent content of described fibre reinforced materials in every section shape memory polymer composite material 1 is 1～40%, and other composition and annexation are with the specific embodiment two.Fibre reinforced materials adopts the fabric wild phase, be of a size of 0.90m * 0.90m, the volume fraction of fiber reinforcement phase is 0.4, low fiber content can guarantee to meet material curl and expansion process in have good shape memory characteristic and morphotropism, be unlikely to because destroying appears in deformation process in the rigidity of composite excessive causing easily.So fiber volume fraction will be limited in below 40%, be generally the requirement of strength that guarantees composite, selecting the content range of fiber is 30-40%.
The specific embodiment four: the following present embodiment that specifies, shape memory polymer material is shape memory styrene, shape memory epoxy resin, styrene-butadiene, using trans-polyisoprene, shape memory isocyanates, shape memory polyurethane, shape memory polyester or polynorbornene in the present embodiment, and other composition and annexation are with the specific embodiment three.
The specific embodiment five: the following present embodiment that specifies; fibre reinforced materials is the chopped strand of carbon fiber, glass fibre, boron fibre, Kevlar fiber or above fabric or above fiber in the present embodiment; and micron order carbon dust, carbon nano-particle or CNT, other composition and annexation are with the specific embodiment four.
The specific embodiment six: the following present embodiment that specifies, the two ends of every section axial articulating marmem 2 are sinusoidal dentation in the present embodiment, such shaped design can increase the connectivity between alloy and the composite material of shape memory.Other composition and annexation are with the specific embodiment five.
The specific embodiment seven: the following present embodiment that specifies, the space development length of space tube shaped memory complex with expended can reach more than the 10m in the present embodiment, and other composition and annexation are with the specific embodiment six.
The specific embodiment eight: the following present embodiment that specifies, present embodiment is finished by the following step
A, selection fiber weaving cloth;
B, resin is evenly coated on the surface of fiber cloth;
C, marmem is embedded in an end of fiber cloth; Be placed in the vacuum bag then;
D, the fiber cloth after previous step is finished suddenly is crimped onto on the tubular die then, solidifies again;
Slough vacuum bag after E, the curing, make tubular form memory polymer material and the axially contact jaw one-shot forming of articulating marmem;
The other end of F, axial articulating marmem and an end of another shape memory polymer composite material cohere, and form tubular form memory complex;
G, tubular form is remembered complex be heated to and make it become writing board shape more than the transition temperature, writing board shape is remembered complex be crimped onto on the bobbin type heater, form shape memory complex with space development tubular structure from another direction.
The specific embodiment nine: the following present embodiment that specifies, the bobbin type heater 3 in the present embodiment step F is that other step is with the specific embodiment eight by computer-controlled resistor-type or radial pattern heater.
Marmem is embedded in an end of fiber weaving cloth, gets up with resin-coating equally and solidify together.What axially the articulating marmem adopted is that thickness is the marmem of 0.13mm.Axially the articulating marmem is of a size of 0.9m * 0.04m * 0.13mm, and the surface is the sinusoidal tooth of rule, and the size of a complete tooth is: tooth depth h=3.2mm, radius of curvature r=0.8mm, facewidth b=6.4mm.Shape state with cylinder is placed in the autoclave, and setting solidification temperature in early stage is 50 ℃, and heating rate is 2 ℃/min; Be 6～24 hours hardening time; Curing environment humidity is less than 30RH (relative humidity).After solidifying 24 hours early stage, place at ambient temperature, ambient humidity is less than 30RH, and temperature is 20 ℃, carries out later stage curing in not demoulding condition, and be 24～48 hours hardening time.It is more complete that such post processing gets material cured, promptly fully solidifies.The demoulding is carried out fining-off to complex, comprises the unhairing limit, finishing, polishing.After handling like this has been exactly the shape memory complex of a deployed configuration.The original shape of such shape memory complex is cylindrical.Heating makes it be deformed into tabular the connection, and the transition temperature of shape memory complex is 60 ℃～150 ℃.The moulding process of shape memory complex mainly comprises hand paste method, vacuum bag pressure method and wet method winding method.Resin is stuck with paste the even scrubbing brush of technology on fiber weaving cloth by hand, and make fiber cloth all wetting.Because the viscosity ratio of epoxy resin is bigger, so do not adopt mould in moulding process; Material is placed in the vacuum bag, vacuumizes (promptly adopting vacuum bag pressure method), vacuum pressure is controlled between 5MPa～20MPa.Vacuum bag is crimped onto on the cylinder type metal die, solidifies the planarization on the surface of back complex, cover whole moulds with the broadband adhesive plaster and fix for assurance.The complex that adds once more after the thermally coupled becomes tabular, on the bobbin heater that to be crimped onto heating-up temperature then and to be 100 ℃ of length be 1m.Bobbin type heater is by computer-controlled resistor-type or radial pattern heater.The effect of heater is to launch drive unit, is a kind of of resistance-type heater.After being crimped onto diameter and being on the 10cm bobbin type heater, the large scale structure just be curled into diameter less than 50cm, length is the little structure of the column type of 1m, the volume that occupies is less than 5% of deployed configuration.Preparation technology for the long fibre reinforced composite adopts winding process, and the axle of the wrapping machine that uses in winding process is chosen as diameter 7cm, and the diameter of winding material is 7.5～9.0cm.The two ends of the axial articulating marmem of the complex by twining preparation all are connected by cohering with composite.Composite after twining is placed in the autoclave solidifies.The later processing and the process that experimental results show that are consistent with step C and subsequent step thereof.
The shape memory polymer material that adopts in the above-mentioned embodiment all has two phase structure: promptly by the fixedly phase of shape memory with vary with temperature the reversible phase composition that can reversibly solidify and soften.Fixing being generally the mutually unformed area with cross-linked structure fixingly is called the thermoplasticity shape-memory polymer for the physical crosslinking structure mutually; Fixing have the chemical crosslinking structure mutually be called the thermoset shape memory polymer.Reversiblely vary with temperature curing that can be reversible and softening mutually, have the physical crosslinking structure.
The elementary heat of the shape-memory polymer that adopts in the above-mentioned embodiment-mechanically deform process is: at transfer of shapes temperature (T
r) more than, can apply external force and make its distortion; Keeping making it be cooled to T under the constant prerequisite of external constraint
rFollowing uniform temperature removes external constraint, the deformation energy of composing by being kept for a long time; When being heated to transition temperature once more when above, shape-memory polymer can automatically revert to the most original shape.Wherein transition temperature comprises glass transition temperature and melting transition temperature.
Adopting the main feature of shape-memory polymer in the above-mentioned embodiment is but that recovery strain is bigger, generally can reach more than 100%.But major defect is that mechanical properties such as the rigidity, intensity of material are relatively poor, and rigidity is lower in the shape memory Recovery Process, deformation-recovery power is less, kinetic stability and reliability are relatively poor.And composite material of shape memory can overcome above-mentioned defective preferably, and its rigidity, intensity in the shape memory Recovery Process are higher, and deformation-recovery power is bigger, and kinetic stability and reliability are higher, and the shape hold facility is better.
The application of shape memory complex in deployed configuration of above-mentioned embodiment made full use of the shape memory characteristic of shape-memory material, but the shortcoming of the shape memory characteristic of composite material of shape memory is the one-way of shape memory characteristic, realized that by the connection effect of axial articulating marmem in structure deployed configuration has the amphicheirality, really realized the reversible of expansion and curly course, and the driving energy that consumes is also much little than traditional structure by structural design.
Tube shaped memory complex with expended space described in the above-mentioned embodiment is verified its invertibity curling and deployed configuration, as shown in Figure 3, end in coiled structure passes through fixed pulley 4 fixed traction moving heavy objects 5, make shape memory complex vertical expansion, after heater began heating, the shape memory complex upwards launched under the effect of tractive force.
Claims (9)
1, tube shaped memory complex with expended space, it is characterized in that it is made up of multistage shape memory polymer composite material (1) and the axial articulating marmem of multistage (2), the two ends of described every section axial articulating marmem (2) connect an end of one section shape memory polymer composite material (1) respectively; One end one-shot forming of one end of every section axial articulating marmem (2) and one section shape memory polymer composite material (1), the other end then are connected by binding material with an end of another section shape memory polymer composite material (1).
2, tube shaped memory complex with expended space according to claim 1 is characterized in that described every section shape memory polymer composite material (1) is curled into tubulose, and described every section axial articulating marmem (2) is curled into ring-type.
3, tube shaped memory complex with expended space according to claim 1 is characterized in that described every section shape memory polymer composite material (1) is made up of shape memory polymer material and fibre reinforced materials; The volume percent content of described shape memory polymer material in every section shape memory polymer composite material (1) is 60～99%, and the volume percent content of described fibre reinforced materials in every section shape memory polymer composite material (1) is 1～40%.
4, tube shaped memory complex with expended space according to claim 1 is characterized in that described shape memory polymer material is shape memory styrene, shape memory epoxy resin, styrene-butadiene, using trans-polyisoprene, shape memory isocyanates, shape memory polyurethane, shape memory polyester or polynorbornene.
5, tube shaped memory complex with expended space according to claim 1; it is characterized in that described fibre reinforced materials is the chopped strand of carbon fiber, glass fibre, boron fibre, Kevlar fiber or above fabric or above fiber, and micron order carbon dust, carbon nano-particle or CNT.
6, tube shaped memory complex with expended space according to claim 1, the two ends that it is characterized in that described every section axial articulating marmem (2) are sinusoidal dentation.
7, tube shaped memory complex with expended space according to claim 1 is characterized in that the length of run of tube shaped memory complex with expended space can reach more than the 10m.
8, the preparation method of tube shaped memory complex with expended space is characterized in that it is finished by the following step
A, selection fiber weaving cloth;
B, resin is evenly coated on the surface of fiber cloth;
C, marmem is embedded in an end of fiber cloth; Be placed in the vacuum bag then;
D, the fiber cloth after previous step is finished suddenly is crimped onto on the tubular die then, solidifies again;
Slough vacuum bag after E, the curing, make tubular form memory polymer material and the axially contact jaw one-shot forming of articulating marmem;
The other end of F, axial articulating marmem and an end of another shape memory polymer composite material cohere, and form tubular form memory complex;
G, tubular form is remembered complex be heated to and make it become writing board shape more than the transition temperature, writing board shape is remembered complex be crimped onto on the bobbin type heater, form shape memory complex with space development tubular structure from another direction.
9, the preparation method of tube shaped memory complex with expended space according to claim 8 is characterized in that the bobbin type heater (3) in the step F is by computer-controlled resistor-type or radial pattern heater.
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| CN 200710071897 CN101041269A (en) | 2007-03-16 | 2007-03-16 | Tube shaped memory complex with expended space and the preparing method thereof |
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| CN101781427A (en) * | 2010-02-11 | 2010-07-21 | 冷劲松 | Shape memory polymer stretchable displayer substrate and methods for preparing same |
| CN101913270A (en) * | 2010-07-23 | 2010-12-15 | 哈尔滨工业大学 | Foldable-expandable shape memory supporting pipe and preparation method thereof |
| US8608890B2 (en) | 2010-11-11 | 2013-12-17 | Spirit Aerosystems, Inc. | Reconfigurable shape memory polymer tooling supports |
| US8734703B2 (en) | 2010-11-11 | 2014-05-27 | Spirit Aerosystems, Inc. | Methods and systems for fabricating composite parts using a SMP apparatus as a rigid lay-up tool and bladder |
| US8815145B2 (en) | 2010-11-11 | 2014-08-26 | Spirit Aerosystems, Inc. | Methods and systems for fabricating composite stiffeners with a rigid/malleable SMP apparatus |
| CN104004118A (en) * | 2014-06-12 | 2014-08-27 | 哈尔滨工业大学 | Multi-section stimulating restoring shape memory polystyrene materials and preparing method thereof |
| US8877114B2 (en) | 2010-11-11 | 2014-11-04 | Spirit Aerosystems, Inc. | Method for removing a SMP apparatus from a cured composite part |
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| CN109467929A (en) * | 2018-12-11 | 2019-03-15 | 哈尔滨工业大学 | Shape memory cyanate ester resin material of resistance to radiated by gamma-ray and preparation method thereof |
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| CN113530933A (en) * | 2021-07-09 | 2021-10-22 | 北京航空航天大学 | Shape memory composite material connecting device |
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| CN101781427A (en) * | 2010-02-11 | 2010-07-21 | 冷劲松 | Shape memory polymer stretchable displayer substrate and methods for preparing same |
| CN101913270A (en) * | 2010-07-23 | 2010-12-15 | 哈尔滨工业大学 | Foldable-expandable shape memory supporting pipe and preparation method thereof |
| CN101913270B (en) * | 2010-07-23 | 2012-11-21 | 哈尔滨工业大学 | Foldable-expandable shape memory supporting pipe and preparation method thereof |
| US8974217B2 (en) | 2010-11-11 | 2015-03-10 | Spirit Aerosystems, Inc. | Reconfigurable shape memory polymer tooling supports |
| US8608890B2 (en) | 2010-11-11 | 2013-12-17 | Spirit Aerosystems, Inc. | Reconfigurable shape memory polymer tooling supports |
| US8734703B2 (en) | 2010-11-11 | 2014-05-27 | Spirit Aerosystems, Inc. | Methods and systems for fabricating composite parts using a SMP apparatus as a rigid lay-up tool and bladder |
| US8815145B2 (en) | 2010-11-11 | 2014-08-26 | Spirit Aerosystems, Inc. | Methods and systems for fabricating composite stiffeners with a rigid/malleable SMP apparatus |
| US9073240B2 (en) | 2010-11-11 | 2015-07-07 | Spirit Aerosystems, Inc. | Reconfigurable shape memory polymer tooling supports |
| US8877114B2 (en) | 2010-11-11 | 2014-11-04 | Spirit Aerosystems, Inc. | Method for removing a SMP apparatus from a cured composite part |
| US8945455B2 (en) | 2010-11-11 | 2015-02-03 | Spirit Aerosystems, Inc. | Reconfigurable shape memory polymer support tooling |
| US8945325B2 (en) | 2010-11-11 | 2015-02-03 | Spirit AreoSystems, Inc. | Methods and systems for forming integral composite parts with a SMP apparatus |
| US8951375B2 (en) | 2010-11-11 | 2015-02-10 | Spirit Aerosystems, Inc. | Methods and systems for co-bonding or co-curing composite parts using a rigid/malleable SMP apparatus |
| CN104325652A (en) * | 2013-10-11 | 2015-02-04 | 哈尔滨工程大学 | Polyurethane composite material doped by nickel-titanium memory alloy and carbon nanotube and preparation method thereof |
| CN104325652B (en) * | 2013-10-11 | 2016-06-29 | 哈尔滨工程大学 | Ultimum Ti and the composite mixed compound polyurethane material of CNT and preparation method |
| CN104004118A (en) * | 2014-06-12 | 2014-08-27 | 哈尔滨工业大学 | Multi-section stimulating restoring shape memory polystyrene materials and preparing method thereof |
| CN104004118B (en) * | 2014-06-12 | 2016-08-31 | 哈尔滨工业大学 | Multistage stimulates shape memory polystyrene material of reply and preparation method thereof |
| CN108638123A (en) * | 2018-05-18 | 2018-10-12 | 东莞华南设计创新院 | A kind of manufacture craft of mechanical arm |
| CN109203436A (en) * | 2018-07-27 | 2019-01-15 | 河海大学 | The design method of high polymer autofolding is realized in a kind of macro-scale |
| CN109467929A (en) * | 2018-12-11 | 2019-03-15 | 哈尔滨工业大学 | Shape memory cyanate ester resin material of resistance to radiated by gamma-ray and preparation method thereof |
| CN109467929B (en) * | 2018-12-11 | 2021-07-30 | 哈尔滨工业大学 | Gamma ray irradiation resistant shape memory cyanate ester resin material and preparation method thereof |
| CN113276440A (en) * | 2021-05-24 | 2021-08-20 | 哈尔滨工业大学 | Preparation method and unfolding and recycling method of thin-wall column shell structure |
| CN113276440B (en) * | 2021-05-24 | 2022-03-01 | 哈尔滨工业大学 | Preparation method and unfolding and recycling method of thin-wall column shell structure |
| CN113530933A (en) * | 2021-07-09 | 2021-10-22 | 北京航空航天大学 | Shape memory composite material connecting device |
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