CA2111925A1 - Thermoplastic polyurethanes modified by siloxane block copolymers - Google Patents

Thermoplastic polyurethanes modified by siloxane block copolymers

Info

Publication number
CA2111925A1
CA2111925A1 CA002111925A CA2111925A CA2111925A1 CA 2111925 A1 CA2111925 A1 CA 2111925A1 CA 002111925 A CA002111925 A CA 002111925A CA 2111925 A CA2111925 A CA 2111925A CA 2111925 A1 CA2111925 A1 CA 2111925A1
Authority
CA
Canada
Prior art keywords
block copolymers
thermoplastic polyurethanes
siloxane block
polyurethanes modified
modified
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002111925A
Other languages
French (fr)
Other versions
CA2111925C (en
Inventor
Heinz Pudleiner
Herbert Hugl
Rolf Dhein
Hanns-Peter Muller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2111925A1 publication Critical patent/CA2111925A1/en
Application granted granted Critical
Publication of CA2111925C publication Critical patent/CA2111925C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42Block-or graft-polymers containing polysiloxane sequences
    • C08G77/458Block-or graft-polymers containing polysiloxane sequences containing polyurethane sequences
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/4009Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/61Polysiloxanes

Abstract

The invention relates to thermoplastic polyurethanes modified with segmented siloxane block copolymers which are based on relatively high molecular weight dihydroxy compounds, diisocyanates, and difunctional chain extenders. The application also relates to their use in the medical field, and particularly as a catheter material.
CA002111925A 1992-12-23 1993-12-20 Thermoplastic polyurethanes modified by siloxane block copolymers Expired - Fee Related CA2111925C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4243799A DE4243799A1 (en) 1992-12-23 1992-12-23 Siloxane block copolymer modified thermoplastic polyurethanes
DEP4243799.7 1992-12-23

Publications (2)

Publication Number Publication Date
CA2111925A1 true CA2111925A1 (en) 1994-06-24
CA2111925C CA2111925C (en) 2004-09-14

Family

ID=6476357

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002111925A Expired - Fee Related CA2111925C (en) 1992-12-23 1993-12-20 Thermoplastic polyurethanes modified by siloxane block copolymers

Country Status (4)

Country Link
US (1) US5430121A (en)
EP (1) EP0603679B1 (en)
CA (1) CA2111925C (en)
DE (2) DE4243799A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114891184A (en) * 2022-06-09 2022-08-12 福建汇得新材料有限公司 Organic silicon modified polyurethane elastomer and preparation method and application thereof

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US5674277A (en) * 1994-12-23 1997-10-07 Willy Rusch Ag Stent for placement in a body tube
DE19524653A1 (en) * 1994-12-23 1996-06-27 Ruesch Willy Ag Placeholder for placement in a body tube
DE4447101A1 (en) * 1994-12-29 1996-07-04 Freiburghaus Andreas U Bodies for tube-like passageways e.g. veins and arteries
DE69623647T2 (en) * 1995-12-22 2003-05-28 Novartis Ag POLYURETHANE MADE OF POLYSILOXANE-POLYOL MACROMER
US6521164B1 (en) 1996-02-06 2003-02-18 Parker-Hannifin Corporation Injection-moldable thermoplastic polyurethane elastomer
AUPO251096A0 (en) * 1996-09-23 1996-10-17 Cardiac Crc Nominees Pty Limited Polysiloxane-containing polyurethane elastomeric compositions
US6846893B1 (en) * 1996-10-23 2005-01-25 Minnesota Mining And Manufacturing Company Polymer mixtures containing polydiorganosiloxane urea-containing components
US6221997B1 (en) 1997-04-28 2001-04-24 Kimberly Ann Woodhouse Biodegradable polyurethanes
AUPO700297A0 (en) * 1997-05-26 1997-06-19 Cardiac Crc Nominees Pty Limited Silicon-based polycarbonates
AUPQ170799A0 (en) * 1999-07-20 1999-08-12 Cardiac Crc Nominees Pty Limited Shape memory polyurethane or polyurethane-urea polymers
DE10113980A1 (en) * 2001-03-22 2002-10-02 Consortium Elektrochem Ind Silane-terminated polydiorganosiloxane-urethane copolymer
GB0122393D0 (en) * 2001-09-17 2001-11-07 Polybiomed Ltd Treating metal surfaces to enhance bio-compatibility
DE10243965A1 (en) * 2002-09-20 2004-04-01 Adiam Life Science Ag Process for the production of biocompatible polyurethanes
US8870814B2 (en) * 2003-07-31 2014-10-28 Boston Scientific Scimed, Inc. Implantable or insertable medical devices containing silicone copolymer for controlled delivery of therapeutic agent
GB0401202D0 (en) * 2004-01-20 2004-02-25 Ucl Biomedica Plc Polymer for use in conduits and medical devices
US7638091B2 (en) * 2004-07-02 2009-12-29 Sabic Innovative Plastics Ip B. V. Methods of sterilizing polycarbonate articles and methods of manufacture
US7494665B1 (en) * 2004-07-30 2009-02-24 Advanced Cardiovascular Systems, Inc. Polymers containing siloxane monomers
US20060142486A1 (en) * 2004-12-23 2006-06-29 Derudder James L Thermoplastic polycarbonate compositions, articles made therefrom and method of manufacture
US7432327B2 (en) * 2004-12-30 2008-10-07 Sabic Innovative Plastics Ip B.V. Transparent polymeric compositions comprising polysiloxane-polycarbonate copolymer, articles made therefrom and methods of making same
US7498401B2 (en) * 2005-03-03 2009-03-03 Sabic Innovative Plastics Ip B.V. Thermoplastic polycarbonate compositions, articles made therefrom and method of manufacture
KR100878883B1 (en) 2006-03-16 2009-01-15 호성케멕스 주식회사 Moisture-permeable and waterproof thermoplastic polyurethane for extrusion molding
US20120150131A1 (en) * 2010-12-09 2012-06-14 Teleflex Medical Incorporated Polymer for Controlling Delivery of Bioactive Agents and Method of Use
PL2859044T3 (en) 2012-06-12 2018-05-30 Basf Se Thermoplastic polyurethane composition
KR20170109902A (en) * 2016-03-22 2017-10-10 현대자동차주식회사 Thermoplastic polyurethane resin composition enhanced texture and durability and producing method thereof
US11746181B2 (en) * 2017-11-17 2023-09-05 Piper Access, Llc Alcohol-resistant siliconized polycarbonate polyurethanes and medical devices incorporating the same
CN114206968A (en) * 2019-08-05 2022-03-18 路博润先进材料公司 Thermoplastic polyurethanes and process for preparing thermoplastic polyurethanes and components thereof
KR102553303B1 (en) * 2020-07-08 2023-07-07 주식회사 아이센스 Functionalized thermoplastic polyurethane, method for preparing the same, method for preparing high performance composite in medical application and medical device comprising the same
CN115368531A (en) * 2022-07-09 2022-11-22 苏州净涵新材料科技有限公司 Self-lubricating stain-resistant thermoplastic polyurethane elastomer and preparation method thereof
WO2024016270A1 (en) * 2022-07-21 2024-01-25 Dow Global Technologies Llc Polyurethane composition

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US3562352A (en) * 1968-09-06 1971-02-09 Avco Corp Polysiloxane-polyurethane block copolymers
US3975350A (en) * 1972-08-02 1976-08-17 Princeton Polymer Laboratories, Incorporated Hydrophilic or hydrogel carrier systems such as coatings, body implants and other articles
DE2817457A1 (en) * 1978-04-21 1979-10-31 Bayer Ag THERMOPLASTIC POLYURETHANE FOR PROCESSING IN EXTRUDERS AND / AND ON CALENDARS
GB2140438B (en) * 1980-02-29 1985-06-05 Thoratec Lab Corp Blood compatible polymer mixture
US4675361A (en) * 1980-02-29 1987-06-23 Thoratec Laboratories Corp. Polymer systems suitable for blood-contacting surfaces of a biomedical device, and methods for forming
US4454309A (en) * 1980-11-12 1984-06-12 Tyndale Plains-Hunter, Ltd. Polyurethane polyene compositions
EP0068385B1 (en) * 1981-06-22 1986-09-24 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Thermoplastic elastomers for medical use as moulded articles brought into direct contact with blood
FR2513644B1 (en) * 1981-09-30 1985-06-21 Rhone Poulenc Spec Chim POLYSILOXANIC AND POLYURETHANIC SEQUENCE COPOLYMERS USED IN PARTICULAR AS THERMOPLASTIC ELASTOMERS
JPS5978236A (en) * 1982-10-28 1984-05-07 Toagosei Chem Ind Co Ltd Production of vinyl-polymerizable high-molecular straight-chain silicone monomer
JPS60252617A (en) * 1984-05-28 1985-12-13 Daicel Chem Ind Ltd Thermoplastic and antithrombotic elastomer
JPH0793944B2 (en) * 1984-09-21 1995-10-11 メンロ・ケアー、インコーポレイテッド Body inserts comprising a multi-phase polymer composition
ATE124072T1 (en) * 1985-01-04 1995-07-15 Thoratec Lab Corp METHOD FOR PRODUCING A MOLDED PART WITH SHAPE MEMORY PROPERTIES AND SOME OF THESE MOLDED PARTS OBTAINED.
US4647643A (en) * 1985-11-08 1987-03-03 Becton, Dickinson And Company Soft non-blocking polyurethanes
JP2819410B2 (en) * 1987-01-22 1998-10-30 大日本インキ化学工業株式会社 Method for producing thermoplastic polyurethane resin for moisture-permeable and waterproof material
US4939007A (en) * 1988-03-07 1990-07-03 Becton, Dickinson And Company Article having a hemocompatible surface

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114891184A (en) * 2022-06-09 2022-08-12 福建汇得新材料有限公司 Organic silicon modified polyurethane elastomer and preparation method and application thereof
CN114891184B (en) * 2022-06-09 2024-01-26 福建汇得新材料有限公司 Organosilicon modified polyurethane elastomer and preparation method and application thereof

Also Published As

Publication number Publication date
US5430121A (en) 1995-07-04
EP0603679A2 (en) 1994-06-29
DE59308779D1 (en) 1998-08-20
DE4243799A1 (en) 1994-06-30
EP0603679B1 (en) 1998-07-15
EP0603679A3 (en) 1995-08-02
CA2111925C (en) 2004-09-14

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